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Halide-sodalites: thermal expansion, decomposition and the Lindemann criterion

  • Marius Wolpmann , Lars Robben EMAIL logo und Thorsten M. Gesing
Veröffentlicht/Copyright: 7. Februar 2022
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 237 Heft 1-3

Abstract

Twelve cubic sodalites |Na8X2|[T1T2O4]6 (T1 = Al3+, Ga3+; T2 = Si4+, Ge4+; X = Cl−, Br−, I−) were examined using high-temperature (HT) X-ray diffraction experiments and TGA-DSC measurements. Temperature-dependent structure data was obtained by Rietveld refinements. Decomposition temperatures were determined using TGA-DSC data for all compounds. The temperature-dependent volume expansion was used to determine Debye and Einstein temperatures using DEA fits. Distinct relations between thermal expansion, bond lengths and the decomposition temperature could not be found. Determination of Lindemann constants of all compounds enables a classification of the sodalites in three groups.

Keywords: DEA-fit; Lindemann-criterion; sodalites; thermal expansion
Corresponding author: Lars Robben, Institute of Inorganic Chemistry and Crystallography, University of Bremen, Leobener Straße 7, D-28359 Bremen, Germany; and MAPEX Center for Materials and Processes, University of Bremen, Bibliotheksstraße 1, D-28359 Bremen, Germany, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2022-0004).

Received: 2022-01-18
Accepted: 2022-01-19
Published Online: 2022-02-07
Published in Print: 2022-03-28

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Micro Review
  4. Structural diversity among multinary pnictide oxides: a minireview focused on semiconducting and superconducting heteroanionic materials
  5. Inorganic Crystal Structures (Original Paper)
  6. The orthorhombic-to-monoclinic phase transition in NbCrP – Peierls distortion of the chromium chain
  7. Halide-sodalites: thermal expansion, decomposition and the Lindemann criterion
  8. RE3Rh2Sn4 (RE = Y, Gd–Tm, Lu) – first stannides with Lu3Co2In4 type structure
  9. Scandium–copper–indides deriving from the ZrNiAl and MnCu2Al type structures
  10. Syntheses, crystallographic characterization, and structural relations of Rb[SCN]
  11. Organic and Metalorganic Crystal Structures (Original Paper)
  12. Unique supramolecular assembly of a synthetic achiral α, γ-hybrid tripeptide
https://doi.org/10.1515/zkri-2022-0004
Schlagwörter für diesen Artikel
DEA-fit; Lindemann-criterion; sodalites; thermal expansion

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Micro Review
  4. Structural diversity among multinary pnictide oxides: a minireview focused on semiconducting and superconducting heteroanionic materials
  5. Inorganic Crystal Structures (Original Paper)
  6. The orthorhombic-to-monoclinic phase transition in NbCrP – Peierls distortion of the chromium chain
  7. Halide-sodalites: thermal expansion, decomposition and the Lindemann criterion
  8. RE3Rh2Sn4 (RE = Y, Gd–Tm, Lu) – first stannides with Lu3Co2In4 type structure
  9. Scandium–copper–indides deriving from the ZrNiAl and MnCu2Al type structures
  10. Syntheses, crystallographic characterization, and structural relations of Rb[SCN]
  11. Organic and Metalorganic Crystal Structures (Original Paper)
  12. Unique supramolecular assembly of a synthetic achiral α, γ-hybrid tripeptide
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