Startseite The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) Na2RE3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu)
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The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) Na2RE3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu)

  • Stefan Greiner , Sabine Zitzer , Sabine Strobel , Peter S. Berdonosov und Thomas Schleid EMAIL logo
Veröffentlicht/Copyright: 2. September 2020
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 235 Heft 8-9

Abstract

The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) with the composition Na2RE3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu) has been synthesized via solid-state reactions. For these conversions mixtures of the respective rare-earth metal(III) oxides, tellurium dioxide and sodium chloride as flux and reactant were prepared, intimately ground and heated for 5 days at 1225 K. The almost colorless single crystals were characterized via single-crystal X-ray diffractometry. In the monoclinic crystal structure of these compounds two crystallographically different rare-earth metal(III), but only one sodium cation sites occur. [REO8]13− polyhedra around both RE3+ positions as well as sodium-centered polyhedra [NaO4Cl4]8− form layers via different connectivity modes. These layers spread out parallel to the (001) plane and arrange alternatingly resulting in the three-dimensional network of the Na2RE3Cl3[TeO3]4 structure, where the Te4+ lone-pair cations at two different sites work as linkers by forming isolated ψ1-tetrahedra [TeO3]2−. Some of these compounds were represented before in different settings of space group C2/c. Now the complete series of the Na2RE3Cl3[TeO3]4 representatives with RE = Y, La–Nd, Sm–Lu is described consistently for a better comparison and understanding. Additionally, a single crystal of Na2Pr3Cl3[TeO3]4 was measured via energy dispersive X-ray analysis to verify the included elements, powder samples of Na2Nd3Cl3[TeO3]4 were characterized by X-ray diffractometer data for a phase-purity check and a single-crystal Raman spectrum of Na2Yb3Cl3[TeO3]4 served for proving the signature of discrete [TeO3]2− anions.

Keywords: chloride; crystal structure; oxotellurates(IV); rare-earth metals; sodium

Dedicated to Professor Dr. Ulrich Müller on the occasion of his 80th birthday.

Corresponding author: Thomas Schleid, Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569Stuttgart, Germany, E-mail:

Acknowledgments

We thank Dr. Falk Lissner and Dr. Ingo Hartenbach for the single-crystal X-ray diffraction measurements. Furthermore, we are indebted to Felix C. Goerigk (M.Sc.) for the energy dispersive X-ray analyses (EDXS), Kevin U. Bareiß (M.Sc.) for recording the single-crystal Raman spectra, and Philip L. Russ (M.Sc.) for carrying out powder X-ray diffractometry (PXRD). In addition, we are grateful for the financial support of our research by the Federal State of Baden-Württemberg (Stuttgart).

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary material

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2020-0051).

Received: 2020-04-28
Accepted: 2020-07-01
Published Online: 2020-09-02
Published in Print: 2020-09-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Original papers
  4. Ulrich Müller zum 80. Geburtstag gewidmet
  5. Laboratory synthesis and characterization of Knasibfite K3Na4[SiF6]3[BF4] and the homologous Ge compound K3Na4[GeF6]3[BF4]
  6. The crystal structures of α-Rb7Sb3Br16, α- and β-Tl7Bi3Br16 and their relationship to close packings of spheres
  7. Beryllium triflates: synthesis and structure of BeL2(OTf)2 (L=H2O, THF, nBu2O)
  8. Synthesis and crystal structures of two layered Cu(I) and Ag(I) iodidometalates
  9. New mixed-valent alkali chain sulfido ferrates A1+x[FeS2] (A = K, Rb, Cs; x = 0.333–0.787)
  10. Structure solution of incommensurately modulated La6MnSb15
  11. Polymorphs of VO(PO3)2: synthesis and crystal structure refinement revisited
  12. On tungstates of divalent cations (III) – Pb5O2[WO6]
  13. Hydrogen order in hydrides of Laves phases
  14. High-pressure synthesis of SmGe3
  15. The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) Na2RE3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu)
  16. Structural diversity of salts of terpyridine derivatives with europium(III) located in both, cation and anion, in comparison to molecular complexes
  17. Elucidating structure–property relationships in imidazolium-based halide ionic liquids: crystal structures and thermal behavior
  18. Syntheses and crystal structures of the manganese hydroxide halides Mn5(OH)6Cl4, Mn5(OH)7I3, and Mn7(OH)10I4
  19. Site-preferential copper substitution for silicon leads to Cu-chains in the new ternary silicide Ir4−xCuSi2
  20. Syntheses and crystal structures of solvate complexes of alkaline earth and lanthanoid metal iodides with N,N-dimethylformamide
https://doi.org/10.1515/zkri-2020-0051
Schlagwörter für diesen Artikel
chloride; crystal structure; oxotellurates(IV); rare-earth metals; sodium

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Original papers
  4. Ulrich Müller zum 80. Geburtstag gewidmet
  5. Laboratory synthesis and characterization of Knasibfite K3Na4[SiF6]3[BF4] and the homologous Ge compound K3Na4[GeF6]3[BF4]
  6. The crystal structures of α-Rb7Sb3Br16, α- and β-Tl7Bi3Br16 and their relationship to close packings of spheres
  7. Beryllium triflates: synthesis and structure of BeL2(OTf)2 (L=H2O, THF, nBu2O)
  8. Synthesis and crystal structures of two layered Cu(I) and Ag(I) iodidometalates
  9. New mixed-valent alkali chain sulfido ferrates A1+x[FeS2] (A = K, Rb, Cs; x = 0.333–0.787)
  10. Structure solution of incommensurately modulated La6MnSb15
  11. Polymorphs of VO(PO3)2: synthesis and crystal structure refinement revisited
  12. On tungstates of divalent cations (III) – Pb5O2[WO6]
  13. Hydrogen order in hydrides of Laves phases
  14. High-pressure synthesis of SmGe3
  15. The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) Na2RE3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu)
  16. Structural diversity of salts of terpyridine derivatives with europium(III) located in both, cation and anion, in comparison to molecular complexes
  17. Elucidating structure–property relationships in imidazolium-based halide ionic liquids: crystal structures and thermal behavior
  18. Syntheses and crystal structures of the manganese hydroxide halides Mn5(OH)6Cl4, Mn5(OH)7I3, and Mn7(OH)10I4
  19. Site-preferential copper substitution for silicon leads to Cu-chains in the new ternary silicide Ir4−xCuSi2
  20. Syntheses and crystal structures of solvate complexes of alkaline earth and lanthanoid metal iodides with N,N-dimethylformamide
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