Twinned olivenite from Cap Garonne, Mine du Pradet – structure and magnetic behavior
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Jutta Kösters
Abstract
Systematically twinned olivenite (Cu2(AsO4)OH) single crystals from Cap Garonne, Mine du Pradet, France, were studied by X-ray diffraction: P 21/n, a = 822.69(6) pm, b = 861.88(9) pm, c = 594.06(9) pm, β = 90.000(6)°, wR = 0.0224, 1621 F2 values, 79 variables and a domain ratio of 0.501(1)/0.499(1). The temperature dependence of the magnetic susceptibility was well reproduced with a square-spin cluster model and an antiferromagnetic spin-exchange parameter of J/kB = 157(3) K.
Acknowledgements
We thank Jérôme Gibert, Agent du Patrimoine du Musée de la Mine de Cap Garonne for support.
References
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©2020 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Graphical Synopsis
- Inorganic Crystal Structures
- The polymorphs of the Na+ ion conductor Na3PS4 viewed from the perspective of a group-subgroup scheme
- Twinned olivenite from Cap Garonne, Mine du Pradet – structure and magnetic behavior
- Crystal-structure of active layers of small molecule organic photovoltaics before and after solvent vapor annealing
- Group-subgroup schemes for MoNi4, Nb4N5, KxFe2−ySe2, Nd10Au3As8O10 and CsInCl3: i5 superstructures of I 4/m allowing atom, charge or vacancy ordering
- Centrosymmetric LaRh2Ga2
- Organic and Metalorganic Crystal Structures
- Fibril formation through self-assembly of a simple glycine derivative and X-ray diffraction study
Artikel in diesem Heft
- Frontmatter
- Graphical Synopsis
- Inorganic Crystal Structures
- The polymorphs of the Na+ ion conductor Na3PS4 viewed from the perspective of a group-subgroup scheme
- Twinned olivenite from Cap Garonne, Mine du Pradet – structure and magnetic behavior
- Crystal-structure of active layers of small molecule organic photovoltaics before and after solvent vapor annealing
- Group-subgroup schemes for MoNi4, Nb4N5, KxFe2−ySe2, Nd10Au3As8O10 and CsInCl3: i5 superstructures of I 4/m allowing atom, charge or vacancy ordering
- Centrosymmetric LaRh2Ga2
- Organic and Metalorganic Crystal Structures
- Fibril formation through self-assembly of a simple glycine derivative and X-ray diffraction study
