Startseite Low-dimensional compounds containing cyanido groups. XXVII. Two forms of nitrosodicyanomethanide in Fe(II) complexes
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Low-dimensional compounds containing cyanido groups. XXVII. Two forms of nitrosodicyanomethanide in Fe(II) complexes

  • Ivan Potočňák EMAIL logo und Lucia Váhovská
Veröffentlicht/Copyright: 5. August 2014

Abstract

Two new ionic [Fe(bpy)3](ONC(CN)2)2·2HONC(CN)2 (1) and [Fe(phen)3](ONC(CN)2)2 (2) complexes have been synthesized (bpy is 2,2′-bipyridine, phen is 1,10-phenanthroline). X-ray structural analysis ((1): P21/n, a=11.7294(5), b=22.0774(11), c=16.2415(8) Å, β=98.910(5)°; (2): P21/c, a=9.4951(3), b=21.6640(9), c=17.3365(6) Å, β=92.483(3)°) revealed that their structures consist of one [Fe(bpy)3]2+ or [Fe(phen)3]2+ complex cation and two uncoordinated nitrosodicyanomethanide, ONC(CN)2- counteranions; two molecules of unique nitrosodicyanomethanide acid HONC(CN)2 were found in (1), too. In the cations, the Fe(II) atom is coordinated by six nitrogen atoms of chelate coordinated neutral ligands forming a distorted octahedron coordination geometry. Both structures are stabilized by π-π interactions and hydrogen bonds, which are very strong in (1).


Corresponding author: Ivan Potočňák, Department of Inorganic Chemistry, Institute of Chemistry, P.J. Šafárik University, Moyzesova 11, SK-041 54 Košice, Slovakia, Tel.: +421 55 234 2335, Fax: +421 55 62 221 24, E-mail:

Acknowledgments

This work was supported by Slovak Research and Development Agency under the contracts No. APVV–0014–11 and APVV–0132–11 and by the grant VEGA 1/0598/14.

References

[1] P. Gamez, J. S. Cost, M. Quesada, G. Aromí, Iron Spin-Crossover compounds: from fundamental studies to practical applications. Dalton Trans.2009, 7845.10.1039/b908208eSuche in Google Scholar

[2] K. Madeja, E. König, Zur frage der bindungsverhältnise in komplexverbindungen des eisen(II) mit 1,10-phenanthrolin. J. Inorg. Nucl. Chem.1963, 25, 377.Suche in Google Scholar

[3] E. König, K. Madeja, 5T2-1A1 Equilibriums in some iron(II)-bis(1,10-phenanthroline) complexes. Inorg. Chem. 1967, 6, 48.Suche in Google Scholar

[4] P. Gütlich, H. A. Goodwin, Spin crossover in transition metal compounds I. Top. Curr. Chem.2004, 233, 341.Suche in Google Scholar

[5] P. Gütlich, H. A. Goodwin, Spin crossover in transition metal compounds II. Top. Curr. Chem.2004, 234, 295.Suche in Google Scholar

[6] P. Gütlich, H. A. Goodwin, Spin crossover in transition metal compounds III. Top. Curr. Chem. 2004, 235, 268.Suche in Google Scholar

[7] L. Váhovská, I. Potočňák, Low-dimensional compounds containing cyanido groups. XXIII. Synthesis and crystal structures of three ionic iron(II) complexes. Z. Kristallogr.2013, 228, 304.Suche in Google Scholar

[8] I. Potočňák, L. Váhovská, P. Herich, Low-dimensional compounds containing cyanide groups. XXV. Synthesis, spectroscopic properties and crystal structures of two ionic iron(II) complexes with tricyanomethanide: tris(1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide) and tris(2,2′-bipyridine-κ2N,N′)iron(II) bis(tricyanomethanide) sesquihydrate. Acta Cryst.2014, C70, 432.Suche in Google Scholar

[9] M. Dunaj-Jurčo, I. Potočňák, D. Mikloš, R. Klement, Complexes with new chelate anionic ligands formed by nucleophilic addition in copper(II) coordination sphere. III. The crystal structures of (2,2’-bipyridine N,N’)(cyanato-N)[methyl(2-cyano-2-imidoxy ethaneimidate-N,N’)]copper(II) and (2,2’-bipyridine-N,N’)(2-cyano-2-imidoxy ethaneimidate-N,N’)copper(II). Collect. Czech. Chem. Commun. 1999, 64, 600.Suche in Google Scholar

[10] M. R. Razali, A. Urbatsch, G. B. Deacon, S. R. Batten, Coordination polymers of transition metals derived from the in situ nucleophilic addition of alcohols to dicyanonitrosomethanide [C(CN)2(NO)]-. Inorg. Chim. Acta2013, 403, 120.10.1016/j.ica.2013.03.022Suche in Google Scholar

[11] A. S. R. Chesman, D. R. Turner, B. Moubaraki, K. S. Murray, G. B. Deacon, S. R. Batten, Nucleophilic addition of water and alcohols to dicyanonitrosomethanide: ligands with diverse bonding modes in magnetically coupled d-block complexes. Eur. J. Inorg. Chem.2010, 59.10.1002/ejic.200900779Suche in Google Scholar

[12] L. Palatinus, G. J. Chapuis, SUPERFLIP-a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions. Appl. Crystallogr. 2007, 40, 786.Suche in Google Scholar

[13] G. M. Sheldrick, A short history of SHELX. Acta Cryst.2008, A64, 112.Suche in Google Scholar

[14] A. L. Spek, Structure validation in chemical crystallography. Acta Cryst.2009, D65, 148.Suche in Google Scholar

[15] L. J. Farrugia, WinGX and ORTEP for Windows: an update. J. Appl. Cryst.2012, 45, 849.Suche in Google Scholar

[16] K. Brandenburg, DIAMOND (Release 2.1e) Bonn, Germany, Crystal Impact GbR, D-53002, 2001.Suche in Google Scholar

[17] E. König, K. Madeja, Infra-red spectra at the 5T2-1A1 cross-over in iron (II) complexes. Spectrochim. Acta1967, 23A, 43.10.1016/0584-8539(67)80206-XSuche in Google Scholar

[18] J. S. Strukl, J. L. Walter, Infrared and Raman spectra of heterocyclic compounds-IV: The infrared studies and normal vibrations of some 1:1 transition metal complexes of 2,2′-bipyridine. Spectrochim. Acta1971, 27A, 223.Suche in Google Scholar

[19] A. Kolbe, H. Köhler, Zum IR-Spektrum des Nitrosodicyanmethanid-Ions [ONC(CN)2]-. Zeitschrift Anorg. Allg. Chem.1970, 373, 230.Suche in Google Scholar

[20] A. M. Golub, H. Köhler, V. V. Skopenko, Chemistry of pseudohalides. Elsevier, Amsterdam, 1986.Suche in Google Scholar

[21] K. S. Low, J. M. Cole, X. Zhou, N. Yufa, Rationalizing the molecular origins of Ru- and Fe-based dyes for dye-sensitized solar cells. Acta Cryst.2012, B68, 137.Suche in Google Scholar

[22] W. T. Eckenhoff, A. B. Biernesser, T. Pintauer, Structural characterization and investigation of iron(III) complexes with nitrogen and phosphorus based ligands in atom transfer radical addition (ATRA). Inorg. Chim. Acta2012, 382, 84.10.1016/j.ica.2011.10.016Suche in Google Scholar

[23] P. Antal, J. Tatiersky, P. Schwendt, Z. Žák, R. Gyepes, Supramolecular interactions between chiral ions: Synthesis and characterization of [MII(bpy)3][VO(O2)(ox)(bpy)]·7H2 O (M=Fe and Ni). J. Mol. Struct.2013, 1032, 240.Suche in Google Scholar

[24] J. Xie, R. Gilbert-Wilson, B. Moubaraki, K. S. Murray, A. G. Wedd, A Fe(bipy)2 unit fused to a keggin polyoxotungstate anion. Aust. J. Chem. 2010, 63, 252.Suche in Google Scholar

[25] K.-L. Zhong, Tris(1,10-phenanthroline-κ2N,N′)iron(II) bis(2,4,5-tricarboxybenzoate) monohydrate and tris(2,2′-bipyridine-κ2N,N′)iron(II) 2,5-dicarboxybenzene-1,4-dicarboxylate–benzene-1,2,4,5-tetracarboxylic acid–water (1/1/2). Acta Cryst.2012, C68, m259.Suche in Google Scholar

[26] P. Gütlich, A. B. Gaspar, Y. Garcia, Spin state switching in iron coordination compounds. Beilstein J. Org. Chem.2013, 9, 342.Suche in Google Scholar

[27] W. M. Singh, B. R. Jali, J. B. Baruah, Iron(II) and Manganese(II) Complexes of 2-{2-(3-Carboxypyridin-2-yl)disulfanyl}pyridine-3-carboxylic acid Through C–S Bond Cleavage. J. Chem. Crystallogr. 2012, 42, 775.Suche in Google Scholar

[28] A. M. Goforth, M. A. Tershansy, M. D. Smith, L. Peterson, J. G. Kelley, W. J. I. DeBenedetti, H. Z. C. Loye, Structural diversity and thermochromic properties of iodobismuthate materials containing d-metal coordination cations: Observation of a high symmetry [Bi3 I11]2– Anion and of Isolated I Anions. J. Am. Chem. Soc.2011, 133, 603.Suche in Google Scholar

[29] D. Jia, J. Zhao, Y. Pan, W. Tang, B. Wu, Y. Zhang, Solvothermal synthesis and characterization of polyselenidoarsenate salts of transition metal complex cations. Inorg. Chem.2011, 50, 7195.Suche in Google Scholar

[30] A. Eichhofer, G. Buth, F. Dolci, K. Fink, R. A. Mole, P. T. Wood, Homoleptic 1-D iron selenolate complexes-synthesis, structure, magnetic and thermal behaviour of 1[Fe(SeR)2] (R = Ph, Mes). Dalton Trans.2011, 40, 7022.Suche in Google Scholar

[31] J. S. Ovens, A. R. Geisheimer, A. A. Bokov, Z. G. Ye, D. B. Leznoff, The use of polarizable [AuX2(CN)2] (X = Br, I) building blocks toward the formation of birefringent coordination polymers. Inorg. Chem. 2010, 49, 9609.Suche in Google Scholar

[32] W. L. Jolly, Modern inorganic chemistry. McGraw-Hill, Inc., New York, 1991.Suche in Google Scholar

[33] I. Potočňák, M. Vavra, L. Jäger, P. Baran, C. Wagner, Low-dimensional compounds containing cyano groups. XV. Preparation, crystal structure and spectral properties of three copper(II) nitrosodicyanomethanide complexes. Trans. Met. Chem.2008, 33, 1.Suche in Google Scholar

[34] J. Honzíček, J. Vinklárek, I. Císařová, M. Erben, Synthesis and structural investigation of vanadocene(IV) complexes of non-linear pseudohalides. Inorg. Chim. Acta2009, 362, 83.10.1016/j.ica.2008.03.019Suche in Google Scholar

[35] G. Glover, N. Gerasimchuk, R. Biagioni, K. V. Domasevitch, Monovalent K, Cs, Tl, and Ag nitrosodicyanomethanides: Completely different 3D networks with useful properties of luminescent materials and nonelectric sensors for gates. Inorg. Chem.2009, 48, 2371.Suche in Google Scholar

[36] C. J. Janiak, A critical account on π-π stacking in metal complexes with aromatic nitrogen-containing ligands. J. Chem. Soc., Dalton Trans. 2000, 3885.10.1039/b003010oSuche in Google Scholar

Received: 2014-5-13
Accepted: 2014-7-1
Published Online: 2014-8-5
Published in Print: 2014-8-1

©2014 by De Gruyter

Heruntergeladen am 9.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/zkri-2014-1770/pdf
Button zum nach oben scrollen