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Synthesis and characterization of cyclo-tetrakis(μ-oxo-dimethylaminoethanolato-κN:κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide

  • Naveed Alam , Muhammad Shahid EMAIL logo , Muhammad Mazhar , Muhammad Khawar Rauf , Kieran C. Molloy and Rohama Gill
Published/Copyright: July 18, 2014
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 229 Issue 8

Abstract

Two new metal(II) complexes formulated as [ZnI(dmae)]4·2(C7H8) 1 and CdI2(Hdmae)22 have been synthesized by using N,N-dimethylaminoethanol, a N,O donor ligand and characterized by melting point, elemental analysis, FT-IR spectroscopy, mass spectrometry and single crystal X-ray diffraction analysis. Complex 1 crystallizes in tetragonal I4(1)/a space group with μ2–O bridge between zinc atoms. The zinc atom is four coordinated with Zn–O 1.9315(13) and 1.9606(14) Å. The complex 2 is mononuclear with distorted octahedral geometry around the Cd(II) and contains two bidentate chelating Hdmae ligands and two iodine atoms, with Cd–O and Cd–N distances of 2.498(2) and 2.400(2) Å, respectively, and the weak O–H···I hydrogen bonds like interactions link the molecules to generate a 1D supramolecular structure.

Keywords: Cadmium; N,N-dimethylaminoethanol; X-ray crystal structure determination; Zinc
Corresponding author: Muhammad Shahid, Department of Chemistry, Quaid-I-Azam University, Islamabad 45320, Pakistan, Phone: +92 322 5111064, E-mail:

Acknowledgments

N.A. and M.S. would like to thank “Higher Education Commission”, Islamabad, Pakistan for financial support through the “Indigenous 5000 Ph.D. Scholarship Scheme”.

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Supplemental Material

The online version of this article (DOI 10.1515/zkri-2013-1721) offers supplementary material, available to authorized users.

Received: 2013-12-19
Accepted: 2014-6-17
Published Online: 2014-7-18
Published in Print: 2014-8-1

©2014 by De Gruyter

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Review Article
  4. Partially amorphous (metamict) titanite: a silicate mineral in a natural radiation induced non-equilibrium phase
  5. Inorganic Crystal Structures
  6. 29Si MAS NMR spectroscopy and synchrotron XRD study of metamict Cardiff titanite
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  8. Preparation and X-ray structures of selected aminium thiosulfates
  9. One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol
  10. Synthesis and characterization of cyclo-tetrakis(μ-oxo-dimethylaminoethanolato-κN:κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide
  11. Low-dimensional compounds containing cyanido groups. XXVII. Two forms of nitrosodicyanomethanide in Fe(II) complexes
  12. Crystal structures of (E)-2-(2-benzylidenehydrazinyl)quinoxalines: persistent N–H···N intermolecular hydrogen bonds but variable π···π interactions
https://doi.org/10.1515/zkri-2013-1721
Keywords for this article
Cadmium; N,N-dimethylaminoethanol; X-ray crystal structure determination; Zinc

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Review Article
  4. Partially amorphous (metamict) titanite: a silicate mineral in a natural radiation induced non-equilibrium phase
  5. Inorganic Crystal Structures
  6. 29Si MAS NMR spectroscopy and synchrotron XRD study of metamict Cardiff titanite
  7. Organic and Metalorganic Crystal Structures
  8. Preparation and X-ray structures of selected aminium thiosulfates
  9. One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol
  10. Synthesis and characterization of cyclo-tetrakis(μ-oxo-dimethylaminoethanolato-κN:κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide
  11. Low-dimensional compounds containing cyanido groups. XXVII. Two forms of nitrosodicyanomethanide in Fe(II) complexes
  12. Crystal structures of (E)-2-(2-benzylidenehydrazinyl)quinoxalines: persistent N–H···N intermolecular hydrogen bonds but variable π···π interactions
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