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Preparation and X-ray structures of selected aminium thiosulfates

  • Agnieszka Dąbrowska and Jarosław Chojnacki EMAIL logo
Published/Copyright: June 25, 2014
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 229 Issue 8

Abstract

Various types of aminium thiosulfates (1–6), including hydrates and mixed salts, have been obtained by the reaction of ammonium thiosulfate with amines. Tert-butylamine, cyclo-hexylamine and 1,6-diaminohexane gave crystals of (t-BuNH3)2S2O3·H2O (1), (c-C6H11NH3)2S2O3 (3) and {(NH4)2(H3NC6H12NH3)(S2O3)2} (6), respectively, which were investigated by X-ray structural analysis. Extensive hydrogen bonding of the N-H…O and N-H…S type is responsible for formation of alternating hydrophilic and hydrophobic layers in the solid-state. In the case of (1), the layers are separated by strata of weak van der Waals interactions, while (3) consists of hydrogen-bonding stabilized rods along the b direction. The structure of (6) contains 3D covalent bonding plus hydrogen bonding networks with no separable substructures. Solubility and thermal decomposition are also briefly discussed.

Keywords: ammonium salts; crystal structure analysis; hydrogen bonding; thiosulfate; X-ray diffraction
Corresponding author: Jarosław Chojnacki, Department of Inorganic Chemistry, Gdansk University of Technology, G. Narutowicza St. 11/12, 80-233 Gdańsk, Poland, Phone: +48 58 3472776, Fax: +48 58 3472694, E-mail:

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Supplemental Material

The online version of this article (DOI 10.1515/zkri-2014-1727) offers supplementary material, available to authorized users.

Received: 2014-1-17
Accepted: 2014-5-25
Published Online: 2014-6-25
Published in Print: 2014-8-1

©2014 by De Gruyter

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Review Article
  4. Partially amorphous (metamict) titanite: a silicate mineral in a natural radiation induced non-equilibrium phase
  5. Inorganic Crystal Structures
  6. 29Si MAS NMR spectroscopy and synchrotron XRD study of metamict Cardiff titanite
  7. Organic and Metalorganic Crystal Structures
  8. Preparation and X-ray structures of selected aminium thiosulfates
  9. One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol
  10. Synthesis and characterization of cyclo-tetrakis(μ-oxo-dimethylaminoethanolato-κN:κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide
  11. Low-dimensional compounds containing cyanido groups. XXVII. Two forms of nitrosodicyanomethanide in Fe(II) complexes
  12. Crystal structures of (E)-2-(2-benzylidenehydrazinyl)quinoxalines: persistent N–H···N intermolecular hydrogen bonds but variable π···π interactions
https://doi.org/10.1515/zkri-2014-1727
Keywords for this article
ammonium salts; crystal structure analysis; hydrogen bonding; thiosulfate; X-ray diffraction

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Review Article
  4. Partially amorphous (metamict) titanite: a silicate mineral in a natural radiation induced non-equilibrium phase
  5. Inorganic Crystal Structures
  6. 29Si MAS NMR spectroscopy and synchrotron XRD study of metamict Cardiff titanite
  7. Organic and Metalorganic Crystal Structures
  8. Preparation and X-ray structures of selected aminium thiosulfates
  9. One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol
  10. Synthesis and characterization of cyclo-tetrakis(μ-oxo-dimethylaminoethanolato-κN:κO)tetrakis(iodozinc) toluene solvate and Bis(dimethylaminoethanol)cadmium(II)iodide
  11. Low-dimensional compounds containing cyanido groups. XXVII. Two forms of nitrosodicyanomethanide in Fe(II) complexes
  12. Crystal structures of (E)-2-(2-benzylidenehydrazinyl)quinoxalines: persistent N–H···N intermolecular hydrogen bonds but variable π···π interactions
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