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Hydroformylation of branched olefins catalyzed by Co2(CO)8 for synthesis of branched alcohol ethoxylates and their surfactant properties

  • Jiawei Zhai

    Jiawei Zhai is an M.D. student at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

         , Zexiang Bi

    Zexiang Bi is a Ph.D. student at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

         , Geng Chen

    Geng Chen is an M.D. student at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

         , Xu Li

    Xu Li is a lecturer at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

     EMAIL logo     and Jinxiang Dong

    Jinxiang Dong is a professor at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology at Taiyuan University of Technology. He won the National Science Fund for Distinguished Young Scholars. His research involves daily washings.

     EMAIL logo
Published/Copyright: August 7, 2024
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 61 Issue 5

Abstract

Branched-chain surfactants have lower equilibrium surface tension, superior wettability and emulsifying performance, making them suitable for exclusive applications. Linear α-olefins are rich in coal-based Fischer–Tropsch synthesized liquid products and are promising building blocks for the synthesis of branched-chain surfactants via dimerization and subsequent C=C bond functionalization. Herein, a new series of branched ethoxylate non-ionic surfactants (MDC6E n ) were prepared using 2-butyl-1-octene (1-hexene dimer, DC6), obtained by the dimerization of coal-based Fischer-Tropsch synthesized 1-hexene, as the hydrophobe via hydroxylation and ethoxylation. In particular, the hydroxylation of DC6 was carried out in a one-pot tandem hydroformylation and hydrogenation over unmodified Co2(CO)8 under mild conditions (140 °C and 4–8 MPa, CO:H2 = 1:1). A thorough investigation of their surfactant properties was carried out, including equilibrium surface tension, dynamic surface tension, foaming properties, wetting power, and emulsifying power. The results indicate that MDC6E9 performs comparably to a commercially available branched-chain surfactants, the iso-tridecyl alcohol ethoxylates (MULTISO 1390). This research provides a new direction for the synthesis of branched nonionic surfactants using Fischer–Tropsch synthesized products, further promoting the development of coal-based fine chemicals.

Keywords: branched alcohol ethoxylates; surfactant properties; Fischer–Tropsch synthesis; hydroformylation; unmodified Co2(CO)8
Corresponding authors: Jinxiang Dong and Xu Li, College of Chemical Engineering and Technology, Shanxi Key Laboratory of Chemical Product Engineering, Taiyuan University of Technology, Taiyuan, 030024, Shanxi, China, E-mail: (J. Dong), (X. Li)

Funding source: The National Natural Science Foundation of China

Award Identifier / Grant number: U21A20315, 22078219, and 22378290

About the authors

Jiawei Zhai

Jiawei Zhai is an M.D. student at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

Zexiang Bi

Zexiang Bi is a Ph.D. student at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

Geng Chen

Geng Chen is an M.D. student at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

Xu Li

Xu Li is a lecturer at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology, Taiyuan University of Technology, and his research involves the synthesis and application of fine chemicals.

Jinxiang Dong

Jinxiang Dong is a professor at the Shanxi Key Laboratory of Chemical Product Engineering, College of Chemical Engineering and Technology at Taiyuan University of Technology. He won the National Science Fund for Distinguished Young Scholars. His research involves daily washings.

Acknowledgments

The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: The National Natural Science Foundation of China (Grant numbers: U21A20315, 22078219, and 22378290) and the Fund for Shanxi “1,331” Project.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/tsd-2024-2598).

Received: 2024-04-13
Accepted: 2024-07-11
Published Online: 2024-08-07
Published in Print: 2024-09-25

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Short Communication
  3. Removal of indomethacin from water using covalent organic polymers
  4. EU CLP Regulation
  5. The EU Detergent Industry Network ‘DetNet’ – an industry approach for the EU CLP classification of detergent and cleaning products for skin and eye effects
  6. Dishwashing
  7. Short and sweet: balancing energy savings and cleaning performance to identify efficient short-cycles for domestic dishwashers
  8. Saving resources without sacrificing results: an empirical investigation of the dishwashing reality of British consumers in an international comparison
  9. Synthesis
  10. Synthesis and emulsification properties of polyglyceryl estolides prepared from fatty acids
  11. Hydroformylation of branched olefins catalyzed by Co2(CO)8 for synthesis of branched alcohol ethoxylates and their surfactant properties
  12. Physical Chemistry
  13. Rheological characterization on novel viscoelastic tetrameric polyhydroxy cationic surfactant/sodium chloride micelle solutions
  14. Dynamic light scattering study on quercetin/surfactant/solvent system
  15. Comparative studies on physicochemical properties of cadmium and neodymium soaps in solid-state
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https://doi.org/10.1515/tsd-2024-2598
Keywords for this article
branched alcohol ethoxylates; surfactant properties; Fischer–Tropsch synthesis; hydroformylation; unmodified Co2(CO)8

Articles in the same Issue

  1. Frontmatter
  2. Short Communication
  3. Removal of indomethacin from water using covalent organic polymers
  4. EU CLP Regulation
  5. The EU Detergent Industry Network ‘DetNet’ – an industry approach for the EU CLP classification of detergent and cleaning products for skin and eye effects
  6. Dishwashing
  7. Short and sweet: balancing energy savings and cleaning performance to identify efficient short-cycles for domestic dishwashers
  8. Saving resources without sacrificing results: an empirical investigation of the dishwashing reality of British consumers in an international comparison
  9. Synthesis
  10. Synthesis and emulsification properties of polyglyceryl estolides prepared from fatty acids
  11. Hydroformylation of branched olefins catalyzed by Co2(CO)8 for synthesis of branched alcohol ethoxylates and their surfactant properties
  12. Physical Chemistry
  13. Rheological characterization on novel viscoelastic tetrameric polyhydroxy cationic surfactant/sodium chloride micelle solutions
  14. Dynamic light scattering study on quercetin/surfactant/solvent system
  15. Comparative studies on physicochemical properties of cadmium and neodymium soaps in solid-state
  16. Enhanced removal of toxic Disperse Blue 35 dye through cloud point extraction: influence of parameters and solvent regeneration
  17. Review Article
  18. Cationic Gemini surfactants: a review on synthesis and their applications
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