Phase behavior of the sodium lauryl glutamate: effects of the temperature and concentration
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Qianjie Zhang
Qianjie Zhang: Worked as an associate professor and postgraduate tutor in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. Her research areas include the formulation of dermatocosmetic emulsion systems and the study of cosmetic rheology.
Chenghao He: Currently studying at Shanghai Institute of Technology. Department of Fragrance, Fragrance and Cosmetics, majoring in Fragrance and Fragrance Technology and Engineering. His research areas include the study of surfactant phase behavior and the development of cosmetic formulations.
Dongmei Zhang: lecturer in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. She holds a PhD in Chemical Engineering and Technology. Her research areas include efficacy evaluation of cosmetics and research on skin cell aging.
Wen Jiang is a lecturer in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. He holds a PhD in Chemical Engineering and Technology. His research areas include botanical extraction and the application of botanical extracts in cosmetics.
Huiwen Zhang: Currently working in Shanghai Kangyue Chemical Technology Co., Ltd. He is a senior engineer. His research areas include the synthesis and application of surfactants.
Wanping Zhang: Served as a professor and postgraduate tutor in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. Her research areas include formulation of dermatocosmetic emulsion systems and research on colloids and surfactants.
Abstract
The physical and chemical properties of sodium lauryl glutamate were systematically investigated in this work. To determine the critical micelle concentration (CMC) of sodium lauryl glutamate, the surface tension was measured using the Wilhelmy plate method. The Krafft point was determined using the ultraviolet/visible spectrophotometer. The effect of pH on the solute in the solution was studied using potentiometric titration. The critical packing parameter (CPP) and Gibbs free energy (ΔG) of micelle formation were calculated using the corresponding parameters. The temperature-concentration phase diagram of sodium lauryl glutamate was constructed using the dynamic light scattering system (DLS) and polarised optical microscopy (POM). The calculated theoretical data were combined with the actual observed data from the phase diagram. Finally, the phase behaviour of sodium lauryl glutamate was determined.
About the authors
Qianjie Zhang: Worked as an associate professor and postgraduate tutor in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. Her research areas include the formulation of dermatocosmetic emulsion systems and the study of cosmetic rheology.
Chenghao He: Currently studying at Shanghai Institute of Technology. Department of Fragrance, Fragrance and Cosmetics, majoring in Fragrance and Fragrance Technology and Engineering. His research areas include the study of surfactant phase behavior and the development of cosmetic formulations.
Dongmei Zhang: lecturer in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. She holds a PhD in Chemical Engineering and Technology. Her research areas include efficacy evaluation of cosmetics and research on skin cell aging.
Wen Jiang is a lecturer in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. He holds a PhD in Chemical Engineering and Technology. His research areas include botanical extraction and the application of botanical extracts in cosmetics.
Huiwen Zhang: Currently working in Shanghai Kangyue Chemical Technology Co., Ltd. He is a senior engineer. His research areas include the synthesis and application of surfactants.
Wanping Zhang: Served as a professor and postgraduate tutor in the Department of Fragrance, Flavor and Cosmetics, Shanghai Institute of Technology. Her research areas include formulation of dermatocosmetic emulsion systems and research on colloids and surfactants.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: The research was supported in part by the Shanghai Local Capacity Building Projects (19090503600) and was sponsored by Collaborative Innovation Center of Fragrance Flavour and Cosmetics.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Chang, Z., Chen, X., Peng, Y. The adsorption behavior of surfactants on mineral surfaces in the presence of electrolytes–a critical review. Miner. Eng. 2018, 121, 66–76; https://doi.org/10.1016/j.mineng.2018.03.002.Suche in Google Scholar
2. Lajtar, L., Narkiewicz-Michalek, J., Rudzinski, W., Partyka, S. A new theoretical approach to adsorption of ionic surfactants at water/oxide interfaces: studies of the mechanism of cationic surfactant adsorption. Langmuir 1994, 10, 3754–3764; https://doi.org/10.1021/la00022a060.Suche in Google Scholar
3. Tadros, T. F. An Introduction to Surfactants; Walter de Gruyter: Berlin/Boston, 2014; pp. 42–45; https://doi.org/10.1515/9783110312133.Suche in Google Scholar
4. Rhein, L. D., Simion, A., Hill, R. L., Cagan, R. H., Mattai, J., Maibach, H. I. Human cutaneous response to a mixed surfactant system: role of solution phenomena in controlling surfactant irritation. Dermatology 1990, 180, 18–23; https://doi.org/10.1159/000247979.Suche in Google Scholar
5. Sheldon, R. A. The E factor 25 years on: the rise of green chemistry and sustainability. Green Chem. 2017, 19, 18–43; https://doi.org/10.1039/c6gc02157c.Suche in Google Scholar
6. Kanicky, J., Poniatowski, A., Mehta, N., Shah, D. Cooperativity among molecules at interfaces in relation to various technological processes: effect of chain length on the pKa of fatty acid salt solutions. Langmuir 2000, 16, 172–177; https://doi.org/10.1021/la990719o.Suche in Google Scholar
7. Sun, Y., Li, Y., Li, C., Zhang, D., Cao, X., Song, X., Wang, Q., Li, Y. Molecular array behavior and synergistic effect of sodium alcohol ether sulphate and carboxyl betaine/sulfobetaine in foam film under high salt conditions. Colloids Surf. A Physicochem. Eng. Asp. 2015, 480, 138–148; https://doi.org/10.1016/J.COLSURFA.2015.02.042.Suche in Google Scholar
8. Imokawa, G., Tsutsumi, H., Kurosaki, T. Surface activity and cutaneous effects of monoalkyl phosphate surfactants. J. Am. Oil Chem. Soc. 1978, 55, 839–843; https://doi.org/10.1007/BF02682659.Suche in Google Scholar
9. Arakawa, J., Pethica, B. A. Micellization in aqueous solutions of monoalkyl phosphate salts. J. Colloid Interface Sci. 1980, 75, 441–450; https://doi.org/10.1016/0021-9797(80)90469-5.Suche in Google Scholar
10. Bordes, R., Holmberg, K. Amino acid-based surfactants–do they deserve more attention? Adv. Colloid Interface Sci. 2015, 222, 79–91; https://doi.org/10.1016/j.cis.2014.10.013.Suche in Google Scholar PubMed
11. Sreenu, M., Nayak, R. R., Prasad, R. B. N., Sreedhar, B. Synthesis, surface and micellar properties of sodium N-oleoyl amino acids. Colloids Surf. A Physicochem. Eng. Asp. 2014, 449, 74–81; https://doi.org/10.1016/j.colsurfa.2014.02.037.Suche in Google Scholar
12. Bordes, R., Tropsch, J., Holmberg, K. Role of an amide bond for self-assembly of surfactants. Langmuir 2009, 26, 3077–3083; https://doi.org/10.1021/la902979m.Suche in Google Scholar PubMed
13. Sun, H., Cheng, R., Deng, C., Meng, F., Dias, A. A., Hendriks, M., Feijen, J., Zhong, Z. Enzymatically and reductively degradable α-amino acid-based poly (ester amide) s: synthesis, cell compatibility, and intracellular anticancer drug delivery. Biomacromolecules 2015, 16, 597–605; https://doi.org/10.1021/bm501652d.Suche in Google Scholar PubMed
14. Perinelli, D. R., Casettari, L., Cespi, M., Fini, F., Man, D. K., Giorgioni, G., Canala, S., Lam, J. K., Bonacucina, G., Palmieri, G. F. Chemical–physical properties and cytotoxicity of N-decanoyl amino acid-based surfactants: effect of polar heads. Colloids Surf. A Physicochem. Eng. Asp. 2016, 492, 38–46; https://doi.org/10.1016/J.COLSURFA.2015.12.009.Suche in Google Scholar
15. Morán, M. C., Pinazo, A., Pérez, L., Clapés, P., Angelet, M., García, M. T., Vinardell, M. P., Infante, M. R. “Green” amino acid-based surfactants. Green Chem. 2004, 6, 233–240; https://doi.org/10.1039/B400293H.Suche in Google Scholar
16. Zhang, D., Sun, Y., Deng, Q., Qi, X., Sun, H., Li, Y. Study of the environmental responsiveness of amino acid-based surfactant sodium lauroylglutamate and its foam characteristics. Colloids Surf. A Physicochem. Eng. Asp. 2016, 504, 384–392; https://doi.org/10.1016/J.COLSURFA.2016.05.097.Suche in Google Scholar
17. Chandra, N., Tyagi, V. Synthesis, properties, and applications of amino acids based surfactants: a review. J. Dispersion Sci. Technol. 2013, 34, 800–808; https://doi.org/10.1080/01932691.2012.695967.Suche in Google Scholar
18. Pinazo, A., Manresa, M., Marques, A. M., Bustelo, M., Espuny, M. J., Perez, L. Amino acid–based surfactants: new antimicrobial agents. Adv. Colloid Interface Sci. 2016, 228, 17–39; https://doi.org/10.1016/j.cis.2015.11.007.Suche in Google Scholar PubMed
19. Bordes, R., Holmberg, K. Physical chemical characteristics of dicarboxylic amino acid-based surfactants. Colloids Surf. A Physicochem. Eng. Asp. 2011, 391, 32–41; https://doi.org/10.1016/j.colsurfa.2011.03.023.Suche in Google Scholar
20. Fujii, M., Inoue, M., Fukami, T. Novel amino acid-based surfactant for silicone emulsification and its application in hair care products: a promising alternative to quaternary ammonium cationic surfactants. Int. J. Cosmet. Sci. 2017, 39, 556–563; https://doi.org/10.1111/ics.12414.Suche in Google Scholar PubMed
21. Van Roosmalen, M., Woerlee, G., Witkamp, G. Amino acid based surfactants for dry-cleaning with high-pressure carbon dioxide. J. Supercrit. Fluids 2004, 32, 243–254; https://doi.org/10.1016/j.supflu.2004.01.005.Suche in Google Scholar
22. Cornwell, P. A review of shampoo surfactant technology: consumer benefits, raw materials and recent developments. Int. J. Cosmet. Sci. 2018, 40, 16–30; https://doi.org/10.1111/ics.12439.Suche in Google Scholar
23. Müller, P., Weber, E., Helbig, C., Baldauf, H. Tethering of long-chain amino acids to a rigid aromatic core—a new type of preorganized surfactants acting as flotative agents. J. Surfactants Deterg. 2001, 4, 407–414; https://doi.org/10.1007/S11743-001-0195-Z.Suche in Google Scholar
24. Wu, R., Qiu, X., Shi, Y., Deng, M. Molecular dynamics simulation of the atomistic monolayer structures of N-acyl amino acid-based surfactants. Mol. Simulat. 2017, 43, 491–501; https://doi.org/10.1080/08927022.2016.1261289.Suche in Google Scholar
25. Bonini, M., Gabbani, A., Del Buffa, S., Ridi, F., Baglioni, P., Bordes, R., Holmberg, K. Adsorption of amino acids and glutamic acid-based surfactants on imogolite clays. Langmuir 2017, 33, 2411–2419; https://doi.org/10.1021/acs.langmuir.6b04414.Suche in Google Scholar
26. Ghosh, S., Dey, J. Interaction of bovine serum albumin with N-acyl amino acid based anionic surfactants: effect of head-group hydrophobicity. J. Collolid Interface Sci. 2015, 458, 284–292; https://doi.org/10.1016/j.jcis.2015.07.064.Suche in Google Scholar
27. Darapureddi, P. R., Nayak, R. R. Synthesis surface properties and effect of an amino acid head group of 11-(2-Methoxy-4-vinylphenoxy) undecanoicacid-based anionic surfactants. J. Surfactants Deterg. 2016, 19, 1133–1142; https://doi.org/10.1007/S11743-016-1869-9.Suche in Google Scholar
28. Tah, B., Pal, P., Mahato, M., Talapatra, G. Aggregation behavior of SDS/CTAB catanionic surfactant mixture in aqueous solution and at the air/water interface. J. Phys. Chem. B 2011, 115, 8493–8499; https://doi.org/10.1021/jp202578s.Suche in Google Scholar
29. Alcantara, M. R., Fernandes, E.Jr. The orientation process of cholesteric lyotropic liquid crystals submitted to shear. Colloids Surf. A Physicochem. Eng. Asp. 2001, 177, 75–82; https://doi.org/10.1016/S0927-7757(00)00573-2.Suche in Google Scholar
30. Alfaro, M., Guerrero, A., Munoz, J. Dynamic viscoelasticity and flow behavior of a polyoxyethylene glycol nonylphenyl ether/toluene/water system. Langmuir 2000, 16, 4711–4719; https://doi.org/10.1021/LA9912040.Suche in Google Scholar
31. Ji, X., Tian, M., Wang, Y. Temperature-induced aggregate transitions in mixtures of cationic ammonium gemini surfactant with anionic glutamic acid surfactant in aqueous solution. Langmuir 2016, 32, 972–981; https://doi.org/10.1021/acs.langmuir.5b04211.Suche in Google Scholar
32. Israelachvili, J. N., Mitchell, D. J., Ninham, B. W. Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers. J. Chem. Soc., Faraday Trans. 1976, 72, 1525–1568; https://doi.org/10.1039/F29767201525.Suche in Google Scholar
33. Mitchell, D., Ninham, B. Curvature elasticity of charged membranes. Langmuir 1989, 5, 1121–1123; https://doi.org/10.1021/LA00088A044.Suche in Google Scholar
34. Chung, J., Yang, Y.-J., Tang, H., Santagata, M., Franses, E. I., Boudouris, B. W. Phase and rheological behavior of aqueous mixtures of an isopropoxylated surfactant. Colloids Surf. A Physicochem. Eng. Asp. 2018, 554, 60–73; https://doi.org/10.1016/J.COLSURFA.2018.06.018.Suche in Google Scholar
35. Bellare, J., Davis, H., Miller, W., Scriven, L. Polarized optical microscopy of anisotropic media: imaging theory and simulation. J. Colloid Interface Sci. 1990, 136, 305–326; https://doi.org/10.1016/0021-9797(90)90379-3.Suche in Google Scholar
© 2022 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Review
- Surfactant as an anti-corrosive agent: a review
- Applications
- Formulation and evaluation of a novel cubosomal emulgel for topical delivery of luliconazole
- Study on graphene-based emulsions as oil displacement agent
- Role of mixed surfactants system in preparation of silver nanoparticles
- Physical Chemistry
- Phase behavior of the sodium lauryl glutamate: effects of the temperature and concentration
- Synthesis
- Preparation of carbosilane quaternary ammonium surfactants and surface activity
- Detergent Ingredients
- The effect of tablet detergent wastewater using zeolite from rice husk ash on the chemical water quality and the growth of water hyacinth
- Biosurfactants
- Optimization of the primary purification process of extracting sphorolipid from the fermentation broth to achieve a higher yield and purity
Artikel in diesem Heft
- Frontmatter
- Review
- Surfactant as an anti-corrosive agent: a review
- Applications
- Formulation and evaluation of a novel cubosomal emulgel for topical delivery of luliconazole
- Study on graphene-based emulsions as oil displacement agent
- Role of mixed surfactants system in preparation of silver nanoparticles
- Physical Chemistry
- Phase behavior of the sodium lauryl glutamate: effects of the temperature and concentration
- Synthesis
- Preparation of carbosilane quaternary ammonium surfactants and surface activity
- Detergent Ingredients
- The effect of tablet detergent wastewater using zeolite from rice husk ash on the chemical water quality and the growth of water hyacinth
- Biosurfactants
- Optimization of the primary purification process of extracting sphorolipid from the fermentation broth to achieve a higher yield and purity
