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Surfactant as an anti-corrosive agent: a review

  • Aniruddha Pal

    Aniruddha Pal was born in Burdwan, India. He pursued her M.Sc. from Burdwan University, India, and is currently working as a JRF at the department of chemistry, Burdwan University, WB, India.

         , Ratan Sarkar

    Ratan Sarkar was born in Burdwan, India. He pursued her M.Sc. from Burdwan University, India and is currently working as a JRF at the department of chemistry, Burdwan University, WB, India.

         , Kripasindhu Karmakar

    Kripasindhu Karmakar was born in West Bengal, India. He is currently working as a JRF at the department of chemistry, Burdwan University, WB, India.

         , Monohar Hossain Mondal ORCID logo EMAIL logo and Bidyut Saha

    Bidyut Saha was born in Birbhum, WB, India, in 1975. He obtained his Ph.D. degree from Visva Bharati University, India, in 2007. He was a visiting scientist between 2009 and 2010 in the Department of Chemistry, UBC, Vancouver, Canada. Dr Saha is presently working as the HoD and Professor in the Department of Chemistry, The University of Burdwan, India. His area of interests is bioremediation of toxic metals, micellar catalysis and inorganic reaction mechanisms. He has published more than 140 articles and book chapters in international journals.

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Published/Copyright: June 29, 2022
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 59 Issue 5

Abstract

Metal corrosion has always been a serious problem in industry. There has always been a need to increase the number of possible, cost-effective corrosion inhibitors. However, many commercially available corrosion inhibitors have both high efficiency and high toxicity, which has led environmental authorities to ban their use. As a result, there is growing interest in scientific research into the use of environmentally friendly compounds. Surfactants and biocompatible corrosion inhibitors are special types of chemicals suitable for long-term industrial use. Molecules with unique hydrophilic and hydrophobic properties can be used in a wide range of applications to solve solubilisation problems and improve extraction processes. The use of surfactant-based products to prevent corrosion on metallic surfaces is a new approach in the field of chemical science. This review article addresses the mechanism of corrosion on metal surfaces and discusses in detail the use of environmentally friendly, cost-effective and readily available surfactants as corrosion inhibitors. The properties and applications of different types of surfactants are also discussed.

Keywords: corrosion; corrosion inhibitors; metal surface; micelle; surfactants
Corresponding authors: Bidyut Saha, Department of Chemistry, Homogeneous Catalysis Laboratory, The University of Burdwan, Burdwan 713104, WB, India, E-mail: ; and Monohar Hossain Mondal, Chemical Sciences Laboratory, Government General Degree College, Singur, Hooghly 712409, WB, India, E-mail:

About the authors

Aniruddha Pal

Aniruddha Pal was born in Burdwan, India. He pursued her M.Sc. from Burdwan University, India, and is currently working as a JRF at the department of chemistry, Burdwan University, WB, India.

Ratan Sarkar

Ratan Sarkar was born in Burdwan, India. He pursued her M.Sc. from Burdwan University, India and is currently working as a JRF at the department of chemistry, Burdwan University, WB, India.

Kripasindhu Karmakar

Kripasindhu Karmakar was born in West Bengal, India. He is currently working as a JRF at the department of chemistry, Burdwan University, WB, India.

Bidyut Saha

Bidyut Saha was born in Birbhum, WB, India, in 1975. He obtained his Ph.D. degree from Visva Bharati University, India, in 2007. He was a visiting scientist between 2009 and 2010 in the Department of Chemistry, UBC, Vancouver, Canada. Dr Saha is presently working as the HoD and Professor in the Department of Chemistry, The University of Burdwan, India. His area of interests is bioremediation of toxic metals, micellar catalysis and inorganic reaction mechanisms. He has published more than 140 articles and book chapters in international journals.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Mondal, M. H., Ali, M. A., Pal, A., Saha, B. A review on micellar catalyzed oxidation reactions of organic functional groups in aqueous medium using various transition metals. Tenside Surfactants Deterg. 2019, 56, 516–525; https://doi.org/10.3139/113.110654.Search in Google Scholar

2. Pal, A., Mondal, M. H., Adhikari, A., Bhattarai, A., Saha, B. Scientific information about sugar-based emulsifiers: a comprehensive review. RSC Adv. 2021, 11, 33004–33016; https://doi.org/10.1039/D1RA04968B.Search in Google Scholar

3. Pal, A., Garain, A., Chowdhury, D., Mondal, M. H., Saha, B. A comparative spectral study on the interaction of organic dye congo-red with selective aqueous micellar media of CPC, Rhamnolipids and Saponin. Tenside Surfactants Deterg. 2020, 57, 401–407; https://doi.org/10.3139/113.110700.Search in Google Scholar

4. Ghosh, S., Ray, A., Pramanik, N. Self-assembly of surfactants: an overview on general aspects of amphiphiles. Biophys. Chem. 2020, 265, 106429; https://doi.org/10.1016/j.bpc.2020.106429.Search in Google Scholar PubMed

5. Fariya, M., Jain, A. K., Dhawan, V., Shah, S., Nagarsenker, M. S. Bolaamphiphiles: a pharmaceutical review. Adv. Pharm. Bull. 2014, 4, 483–491; https://doi.org/10.5681/apb.2014.072.Search in Google Scholar PubMed PubMed Central

6. Menger, F. M., Littau, C. A. Gemini-surfactants: synthesis and properties. J. Am. Chem. Soc. 1991, 113, 1451–1452; https://doi.org/10.1021/ja00004a077.Search in Google Scholar

7. Aslam, R., Mobin, M., Aslam, J., Aslam, A., Zehra, S., Masroor, S. Application of surfactants as anticorrosive materials: a comprehensive review. Adv. Colloid Interface Sci. 2021, 295, 102481; https://doi.org/10.1016/j.cis.2021.102481.Search in Google Scholar PubMed

8. Clint, J. H. Surfactant Aggregation, 1st ed.; Chapman and Hall: New York, 1992.10.1007/978-94-011-2272-6Search in Google Scholar

9. Fendler, J. H. Microemulsions, micelles, and vesicles as media for membrane mimetic photochemistry. J. Phys. Chem. 1980, 48, 1485–1491; https://doi.org/10.1021/j100449a012.Search in Google Scholar

10. Fujimoto, T. New Introduction to Surface Active Agents; Sanyo Chemical Industries Ltd. Publication: Kyoto, Japan, 1985; pp. 156–174.Search in Google Scholar

11. Rosen, M. J. Surfactants in Emerging Technology; Marcel Dekker: New York, 1997.Search in Google Scholar

12. Zhu, Y., Free, M. L., Woollam, R., Durnie, W. A review of surfactants as corrosion inhibitors and associated modeling. Prog. Mater. Sci. 2017, 90, 159–223; https://doi.org/10.1016/j.pmatsci.2017.07.006.Search in Google Scholar

13. Inamuddin, B. R., Ahamed, M. I., Khan, A. Advances in Green Synthesis, Avenues and Sustainability Chapter 3, 2021.10.1007/978-3-030-67884-5Search in Google Scholar

14. Jönsson, B., Lindman, B., Holmberg, K., Kronberg, B. Surfactant Micellization. Surfactants and Polymers in Aqueous Solution; John Wiley and Sons: Chichester, UK, 1998.Search in Google Scholar

15. Zacchariasse, K. A., Phuc, N. V., Kozankiewicz, B. Investigation of micelles, microemulsions, and phospholipid bilayers with the pyridinium-N-phenolbetaine ET(30), a polarity probe for aqueous interfaces. J. Phys. Chem. 1981, 85, 2676–2683; https://doi.org/10.1021/j150618a022.Search in Google Scholar

16. Shinoda, K., Kunieda, H., Arai, T., Saijo, H. Principles of attaining very large solubilization (microemulsion): inclusive understanding of the solubilization of oil and water in aqueous and hydrocarbon media. J. Phys. Chem. 1984, 88, 5126–5129; https://doi.org/10.1021/j150665a065.Search in Google Scholar

17. Israelachvili, J. N. Intermolecular and Surface Forces, 2nd ed.; Academic Press: London, 1992.Search in Google Scholar

18. Bunton, C. A., Carrasco, N., Huang, S. K., Paik, C., Romsted, L. S. Reagent distribution and micellar catalysis of carbocation reactions. J. Am. Chem. Soc. 1978, 100, 5420–5425; https://doi.org/10.1021/ja00485a028.Search in Google Scholar

19. Chowdhury, S., Rakshit, A., Acharjee, A., Saha, B. Biodegradability and biocompatibility: advancements in synthetic surfactants. J. Mol. Liq. 2021, 324, 115105; https://doi.org/10.1016/j.molliq.2020.115105.Search in Google Scholar

20. Frankel, G. S. Pitting corrosion of metals: a review of the critical factors. J. Electrochem. Soc. 1998, 145, 2186; https://doi.org/10.1149/1.1838615.Search in Google Scholar

21. FitzGerald, K. P., Nairn, J., Skennerton, G., Atrens, A. Atmospheric corrosion of copper and the colour, structure and composition of natural patinas on copper. Corros. Sci. 2006, 48, 2480–2509; https://doi.org/10.1016/j.corsci.2005.09.011.Search in Google Scholar

22. Lyu, B., Liu, H., Li, P., Gao, D., Ma, J. Preparation and properties of polymeric surfactants: a potential corrosion inhibitor of carbon steel in acidic medium. J. Ind. Eng. Chem. 2019, 80, 411–424; https://doi.org/10.1016/j.jiec.2019.08.021.Search in Google Scholar

23. Neto, A. O. W., Moura, E. F., Junior, H. S., Dantas, T. N. C., Neto, A. A. D., Gurgel, A. Preparation and application of self-assembled systems containing dodecylammonium bromide and chloride as corrosion inhibitors of carbon-steel. Colloids Surf. A Physicochem. Eng. Asp. 2012, 398, 76–83; https://doi.org/10.1016/j.colsurfa.2012.02.014.Search in Google Scholar

24. Bregmann, J. I. Corrosion Inhibitors; MacMillan: New York, 1963.Search in Google Scholar

25. Hackerman, N. The theory and practice of corrosion and its control in industry. Langmuir 1987, 3, 922–924; https://doi.org/10.1021/la00078a009.Search in Google Scholar

26. Free, M. L. A new corrosion inhibition model for surfactants that more closely accounts for actual adsorption than traditional models that assume physical coverage is proportional to inhibition. Corros. Sci. 2004, 46, 3101–3113; https://doi.org/10.1016/j.corsci.2004.03.020.Search in Google Scholar

27. McCafferty, E. Corrosion Control by Coatings; Science Press: Princeton, N.J., 2010.Search in Google Scholar

28. Robinson, J. S., Kingston, E. J., Jones, C. T. Studies on experimental growth retardation in sheep. The effect of removal of an endometrial caruncles on fetal size and metabolism. J. Dev. Physiol. 1979, 1, 379–398. PMID: 45373.Search in Google Scholar

29. Mehta, S. K., Bhasin, K. K., Chauhan, R., Dham, S. Effect of temperature on critical micelle concentration and thermodynamic behavior of dodecyldimethylethylammonium bromide and dodecyltrimethylammonium chloride in aqueous media. Colloids Surf. A Physicochem. Eng. Asp. 2005, 255, 153–157; https://doi.org/10.1016/j.colsurfa.2004.12.038.Search in Google Scholar

30. Mata, J., Varade, D., Bahadur, P. Aggregation behavior of quaternary salt based cationic surfactants. Thermochim. Acta 2005, 428, 147–155; https://doi.org/10.1016/j.tca.2004.11.009.Search in Google Scholar

31. Free, M. L. Development and application of useful equations to predict corrosion inhibition by different surfactants in various aqueous environments. Corrosion 2002, 58, 1025–1030; https://doi.org/10.5006/1.3280791.Search in Google Scholar

32. Malik, M. A., Hashim, M. A., Nabi, F., AL-Thabaiti, S. A., Khan, Z. Anti-corrosion ability of surfactants: a review. Int. J. Electrochem. Sci. 2011, 6, 1927–1948.10.1016/S1452-3981(23)18157-0Search in Google Scholar

33. Elewady, G. Y., El-Said, I. A., Fouda, A. S. Anion surfactants as corrosion inhibitors for aluminum dissolution in HCl solutions. Int. J. Electrochem. Sci. 2008, 3, 177–190.10.1016/S1452-3981(23)15437-XSearch in Google Scholar

34. Neto, A. O. W., Dantas, T. N. C., Neto, A. A. D., Gurgel, A. Recent advances on the use of surfactant systems as inhibitors of corrosion on metallic surfaces. In The Role of Colloidal Systems in Environmental Protection, 2014, pp. 479–508. Chapter 19; https://doi.org/10.1016/B978-0-444-63283-8.00019-3.Search in Google Scholar

35. Otitoju, T. A., Ahmad, A. L., Ooi, B. S. Superhydrophilic (superwetting) surfaces: a review on fabrication and application. J. Ind. Eng. Chem. 2017, 47, 19–40; https://doi.org/10.1016/j.jiec.2016.12.016.Search in Google Scholar

36. Mahdavian, M., Ramezanzadeh, B., Akbarian, M., Ramezanzadeh, M., Kardar, P., Alibakhshi, E., Farashi, S. Enhancement of silane coating protective performance by using a polydimethylsiloxane additive. J. Ind. Eng. Chem. 2017, 55, 244–252; https://doi.org/10.1016/j.jiec.2017.07.001.Search in Google Scholar

37. Golabadi, M., Aliofkhazraei, M., Toorani, M., Rouhaghdam, A. S. Corrosion and cathodic disbondment resistance of epoxy coating on zinc phosphate conversion coating containing Ni2+ and Co2+. J. Ind. Eng. Chem. 2017, 47, 154–168; https://doi.org/10.1016/j.jiec.2016.11.027.Search in Google Scholar

38. Izadi, M., Shahrabi, T., Ramezanzadeh, B. Synthesis and characterization of an advanced layer-by-layer assembled Fe3O4/polyaniline nanoreservoir filled with Nettle extract as a green corrosion protective system. J. Ind. Eng. Chem. 2018, 57, 263–274; https://doi.org/10.1016/j.jiec.2017.08.032.Search in Google Scholar

39. Prabakaran, M., Kim, S. H., Oh, Y. T., Raj, V., Chung, I. M. Anticorrosion properties of momilactone A isolated from rice hulls. J. Ind. Eng. Chem. 2017, 45, 380–386; https://doi.org/10.1016/j.jiec.2016.10.006.Search in Google Scholar

40. Agrawal, Y. K., Talati, J. D., Shah, M. D., Desai, M. N., Shah, N. K. Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid. Corros. Sci. 2004, 46, 633–651; https://doi.org/10.1016/S0010-938X(03)00174-4.Search in Google Scholar

41. Emregul, K. C., Kurtaran, R., Atakol, O. An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel. Corros. Sci. 2003, 45, 2803–2817; https://doi.org/10.1016/S0010-938X(03)00103-3.Search in Google Scholar

42. Li, S., Chen, S., Lei, S., Ma, H., Yu, R., Liu, D. Investigation on some Schiff bases as HCl corrosion inhibitors for copper. Corros. Sci. 1999, 41, 1273–1287; https://doi.org/10.1016/S0010-938X(98)00183-8.Search in Google Scholar

43. Ehteshamzadeh, M., Shahrabi, T., Hosseini, M. G. Inhibition of copper corrosion by self-assembled films of new Schiff bases and their modification with alkanethiols in aqueous medium. Appl. Surf. Sci. 2006, 252, 2949–2959; https://doi.org/10.1016/j.apsusc.2005.05.003.Search in Google Scholar

44. Emregul, K. C., Atakol, O. Corrosion inhibition of mild steel with Schiff base compounds in 1 M HCl. Mater. Chem. Phys. 2003, 82, 188–193; https://doi.org/10.1016/S0254-0584(03)00204-9.Search in Google Scholar

45. Arshadi, M. R., Hosseini, M. G., Ghorbani, M. Inhibition effect of 3,5 bis (2-pyridil) 4-amino 1,2,4 triazole and 1-10 phenantrolin on corrosion of mild steel in acid solutions. Br. Corros. J. 2002, 37, 76–80; https://doi.org/10.1179/000705902225002394.Search in Google Scholar

46. Sorkhabi, H. A., Shaabani, B., Seifzadeh, D. Corrosion inhibition of mild steel by some Schiff base compounds in hydrochloric acid. Appl. Surf. Sci. 2005, 239, 154–164; https://doi.org/10.1016/j.apsusc.2004.05.143.Search in Google Scholar

47. Shokry, H., Yuasa, M., Sekine, I., Issa, R. M., El-Baradie, H. Y., Gomma, G. K. Corrosion inhibition of mild steel by Schiff base compounds in various aqueous solutions: Part 1. Corros. Sci. 1998, 40, 2173–2186; https://doi.org/10.1016/S0010-938X(98)00102-4.Search in Google Scholar

48. Hashi Omar, I, Zucchi, F, Trabanelli, G. Schiff bases as corrosion inhibitors of copper and its alloys in acid media. Surf. Coat. Technol. 1998, 29, 141.10.1016/0257-8972(86)90025-3Search in Google Scholar

49. Li, S. L., Wang, Y. G., Chen, S. H., Yu, R., Lei, S. B., Ma, H. Y., Liu, D. X. Some aspects of quantum chemical calculations for the study of Schiff base corrosion inhibitors on copper in NaCl solutions. Corros. Sci. 1999, 41, 1769–1782; https://doi.org/10.1016/S0010-938X(99)00014-1.Search in Google Scholar

50. Sundaram, R. G., Vengatesh, G., Sundaravadivelu, M. Adsorption behavior and anticorrosion capability of antibiotic drug nitroxoline on copper in nitric acid medium. Bio Tribo. Corros. 2017, 3, 36; https://doi.org/10.1007/s40735-017-0097-9.Search in Google Scholar

51. Voronov, S., Kohut, A., Tarnavchyk, I., Andriy, V. Advances in reactive polymeric surfactants for interface modification. Curr. Opin. Colloid Interface Sci. 2014, 19, 95–121; https://doi.org/10.1016/j.cocis.2014.03.010.Search in Google Scholar

52. Holmberg, K., Shah, D. O., Schwuger, M. J. Handbook of Applied Surface and Colloid Chemistry; Wiley-Blackwell, 2002.Search in Google Scholar

53. Fuchs-Gode, R., Dolecek, V. A effect of sodium dodecylsulfate on the corrosion of copper in sulphuric acid media. Colloids Surf. A Physicochem. Eng. Asp. 2004, 244, 73–76; https://doi.org/10.1016/j.colsurfa.2004.05.015.Search in Google Scholar

54. Villamil, R. F. V., Corio, P., Agostinho, S. M. L., Rubim, J. C. Effect of sodium dodecylsulfate on copper carrion in sulphuric acid media in the absence and presence of benzotriazole. J. Electroanal. Chem. 1999, 472, 112–119; https://doi.org/10.1016/S0022-0728(99)0027-3.Search in Google Scholar

55. Guo, R., Liu, T., Wei, X. Effects of SDS and some alcohols on the inhibition efficiency of corrosion for nickel. Colloids Surf. A Physicochem. Eng. Asp. 2002, 209, 37–45; https://doi.org/10.1016/S0927-7757(02)00032-8.Search in Google Scholar

56. Moura, E. F., Neto, A. O. W., Dantas, T. N. C., Junior, H. S., Gurgel, A. Applications of micelle and microemulsion systems containing amine surfactants synthesized from ricinoleic acid as carbon-steel corrosion inhibitors. Colloids Surf. A Physicochem. Eng. 2009, 340, 199–207; https://doi.org/10.1016/j.colsurfa.2009.03.031.Search in Google Scholar

57. Khamis, E., Al-Lohedan, H. A., Al-Mayouf, A., Issa, Z. A. Adsorpsion effect of cationic surfectants on corrosion inhibition of steel. Mater. Werkst. 1997, 28, 46–50; https://doi.org/10.1002/mawe.19970280115.Search in Google Scholar

58. Atia, A. A., Saleh, M. M. Inhibition of acid corrosion of steel using cetylpyridinium chloride. J. Appl. Electrochem. 2003, 33, 171–177; https://10.1023/a:1024083117949.10.1023/A:1024083117949Search in Google Scholar

59. Achouri, M. E., Bensouda, Y., Gouttaya, H. M., Nciri, B., Perez, L., Infante, M. R. Gemini surfactants of the type 1,2-ethanediyl bis-(dimethylalkylammonium bromide). Tenside Surfactants Deterg. 2001, 38, 208–215.10.1515/tsd-2001-380403Search in Google Scholar

60. Zana, R., Xia, J. (Eds.). Gemini Surfactants. Synthesis, Interfacial and Solution-Phase Behavior, and Applications; Marcel Dekker: New York USA, 2004.Search in Google Scholar

61. Menger, F. M., Keiper, J. S. Gemini surfactants. Angew. Chem. Int. Ed. 2000, 39, 1906–1920; https://doi.org/10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-Q.10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-QSearch in Google Scholar

62. Zhao, T., Mu, G. The adsorption and corrosion inhibition of anion surfactants on aluminium surface in hydrochloric acid. Corros. Sci. 1999, 41, 1937–1944; https://doi.org/10.1016/S0010-938X(99)00029-3.Search in Google Scholar

63. Oguzie, E. E. Influence of halide ions on the inhibitive effect of congo red dye on the corrosion of mild steel in sulphuric acid solution. Mater. Chem. Phys. 2004, 87, 212–217; https://doi.org/10.1016/j.matchemphys.2004.06.006.Search in Google Scholar

64. Obot, I. B., Obi-Egbedi, N. O. Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: experimental and theoretical investigation. Corros. Sci. 2010, 52, 198–204; https://doi.org/10.1016/j.corsci.2009.09.002.Search in Google Scholar
Received: 2022-03-09
Accepted: 2022-04-25
Published Online: 2022-06-29
Published in Print: 2022-09-27

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Review
  3. Surfactant as an anti-corrosive agent: a review
  4. Applications
  5. Formulation and evaluation of a novel cubosomal emulgel for topical delivery of luliconazole
  6. Study on graphene-based emulsions as oil displacement agent
  7. Role of mixed surfactants system in preparation of silver nanoparticles
  8. Physical Chemistry
  9. Phase behavior of the sodium lauryl glutamate: effects of the temperature and concentration
  10. Synthesis
  11. Preparation of carbosilane quaternary ammonium surfactants and surface activity
  12. Detergent Ingredients
  13. The effect of tablet detergent wastewater using zeolite from rice husk ash on the chemical water quality and the growth of water hyacinth
  14. Biosurfactants
  15. Optimization of the primary purification process of extracting sphorolipid from the fermentation broth to achieve a higher yield and purity
https://doi.org/10.1515/tsd-2022-2434
Keywords for this article
corrosion; corrosion inhibitors; metal surface; micelle; surfactants

Articles in the same Issue

  1. Frontmatter
  2. Review
  3. Surfactant as an anti-corrosive agent: a review
  4. Applications
  5. Formulation and evaluation of a novel cubosomal emulgel for topical delivery of luliconazole
  6. Study on graphene-based emulsions as oil displacement agent
  7. Role of mixed surfactants system in preparation of silver nanoparticles
  8. Physical Chemistry
  9. Phase behavior of the sodium lauryl glutamate: effects of the temperature and concentration
  10. Synthesis
  11. Preparation of carbosilane quaternary ammonium surfactants and surface activity
  12. Detergent Ingredients
  13. The effect of tablet detergent wastewater using zeolite from rice husk ash on the chemical water quality and the growth of water hyacinth
  14. Biosurfactants
  15. Optimization of the primary purification process of extracting sphorolipid from the fermentation broth to achieve a higher yield and purity
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