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Characterization of toothpastes for fluorine and other elements by INAA and ICP-OES

  • Mohammad Wasim ORCID logo EMAIL logo , Arfan Tariq , Rashid Nazir Qureshi and Munib Ahmed Shafique
Published/Copyright: November 28, 2022

Abstract

Fluoride toothpastes have made a significant contribution towards oral hygiene. This study proposes instrumental neutron activation analysis (INAA) as a suitable technique for determining fluorine in toothpastes. The method involved a 10 s irradiation, followed by 10–20 s decay, and counting for 10 s, using a pneumatic system and high purity germanium detector. All irradiations were performed at miniature neutron source reactor with thermal neutron flux 1 × 1012 cm−2 s−1. Since Na was present in all toothpastes, the quantification of fluorine required correction for 23Na(n,α)20F threshold reaction. Fluorine determination was validated by analysing the samples by ion chromatography. All toothpastes were also analysed for other elements by k 0-INAA and ICP-OES. Both techniques quantified 28 elements including Al, As, Ba, Ca, Ce, Cl, Co, Cr, Cu, F, Fe, Hf, K, La, Mg, Mn, Na, P, S, Sb, Sc, Si, Sm, Sn, Sr, Ta, Ti and Zn. This study, categorized toothpastes in five groups based on concentrations of Ca, P and Ti.


Corresponding author: Mohammad Wasim, Isotope Production Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-07-19
Accepted: 2022-11-09
Published Online: 2022-11-28
Published in Print: 2023-02-23

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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