Startseite Naturwissenschaften Gamma-ray shielding parameters of Li2B4O7 glasses: undoped and doped with magnetite, siderite and Zinc-Borate minerals cases
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Gamma-ray shielding parameters of Li2B4O7 glasses: undoped and doped with magnetite, siderite and Zinc-Borate minerals cases

  • Nergiz Yıldız Yorgun EMAIL logo
Veröffentlicht/Copyright: 10. Mai 2019

Abstract

Designing new shielding materials and calculating their shielding parameters are important task to keep living in safe from hazardous effects of radiation. In this study, the lithium borate glasses with chemical formula (Li2B4O7)(100−x)Yx (x = 0, 10, 20, 30 and 40 wt % and Y = magnetite, siderite and zinc-borate) were fabricated via melt quenching technique. X-ray diffraction method was employed to confirm amorphous structure of fabricated glass samples. The glass sample’s shielding parameters such as mass attenuation coefficient, effective atomic number, and half value layer were measured experimentally by the narrow beam transmission method for 81, 276, 302, 356, and 383 keV of incident photon energies. Also, WinXCom software was used to calculate theoretical shielding parameters from 1 keV to 105 MeV photon energy. Moreover, Geometric Progression (G–P) method was used to calculate exposure buildup factor (EBF) values for incident photon energy 0.015 MeV–15 MeV up to penetration depths of 40 mfp (mean free path). Among the obtained results, while Li2B4O7 glass with magnetite 40 % has the highest mass attenuation and effective atomic number, it has the lowest half value layer and exposure buildup factor. The results show that the fabricated glass systems could be considered as a good candidate for radiation safety.

References

1. Turner, J. E.: Atoms, Radiation, and Radiation Protection, Third edition. Wiley-VCH Verlag GmbH and Co. KGaA, USA (2007).10.1002/9783527616978Suche in Google Scholar

2. Kaplan, M. F.: Concrete Radiation Shielding. John Wiley and Sons, Inc., New York (1989).Suche in Google Scholar

3. Pan, Y., Zhu, R., Banerjee, S. K., Gill, J., Williams, Q.: Rock magnetic properties related to thermal treatment of siderite: behavior and interpretation. J. Geophys. Res. B: Solid Earth. 105, 783 (2000).10.1029/1999JB900358Suche in Google Scholar

4. Schubert, D. M., Alam, F., Visi, M. Z., Knobler, C. B.: Structural characterization and chemistry of the industrially important zinc borate, Zn[B3O4(OH)3]. Chem. Mater. 15, 866 (2003).10.1021/cm020791zSuche in Google Scholar

5. Lakshminarayana, G., Kumar, A., Dong, M. G., Sayyed, M. I., Long, N. V., Mahdi, M. A.: Exploration of gamma radiation shielding features for titanate bismuth borotellurite glasses using relevant software program and Monte Carlo simulation code. J. Non-Cryst. Solids 481, 65 (2018).10.1016/j.jnoncrysol.2017.10.027Suche in Google Scholar

6. Kaur, P., Singh, K. J., Thakur, S., Singh, P., Bajwa, B. S.: Investigation of bismuth borate glass system modified with barium for structural and gamma-ray shielding properties. Spectrochim. Acta, Part A 206, 367 (2019).10.1016/j.saa.2018.08.038Suche in Google Scholar PubMed

7. Kaewjang, S., Maghanemi, U., Kothan, S., Kim, H. J., Limkitjaroenporn, P., Kaewkhao, J.: New gadolinium based glasses for gamma-rays shielding materials. Nucl. Eng. Des. 280, 21 (2014).10.1016/j.nucengdes.2014.08.030Suche in Google Scholar

8. Sayyed, M. I., Lakshminarayana, G.: Structural, thermal, optical features and shielding parameters investigations of optical glasses for gamma radiation shielding and defense applications. J. Non-Cryst. Solids 487, 53(2018).10.1016/j.jnoncrysol.2018.02.014Suche in Google Scholar

9. El-Mallawany, R., Sayyed, M. I.: Comparative shielding properties of some tellurite glasses: Part 1. Physica B 539, 133 (2018).10.1016/j.physb.2017.05.021Suche in Google Scholar

10. Koepke, C., Wisniewski, K., Grinberg, M., Majchrowski, A., Han, T. P. J.: Excited state absorption in chromium doped Li2B4O7 glass. J. Phys.: Condens. Matter 13, 2701 (2001).10.1088/0953-8984/13/11/324Suche in Google Scholar

11. Danilyuk, P. S., Puga, P. P., Krasilinets, V. N., Gomonai, A. I., Puga, G. D., Rizak, V. M., Turok, I. I.: X-ray fluorescence of Eu 3+ ions in glassy and polycrystalline lithium tetraborate. Glass Phys. Chem. 44, 1 (2018).10.1134/S1087659618010066Suche in Google Scholar

12. Padlyak, B., Ryba-Romanowski, W., Lisiecki, R., Pieprzyk, B., Drzewiecki, A., Adamiv, V., Teslyuk, I.: Synthesis and optical spectroscopy of the lithium tetraborate glasses, doped with terbium and dysprosium. Opt. Appl. 42, 365 (2012).10.1109/OMEE.2012.6464898Suche in Google Scholar

13. Yorgun, N. Y., Kavaz, E., Oto, B., Akdemir, F.: Evaluation of gamma-ray attenuation properties of lithium borate glasses doped with barite, limonite and serpentine. Radiochim. Acta 106, 865 (2018).10.1515/ract-2018-2938Suche in Google Scholar

14. Ersundu, A. E., Büyükyıldız, M., Ersundu, M. Ç., Şakar, E., Kurudirek, M.: The heavy metal oxide glasses within the WO3-MoO3-TeO2 system to investigate the shielding properties of radiation applications. Prog. Nucl. Energy 104, 280 (2018).10.1016/j.pnucene.2017.10.008Suche in Google Scholar

15. Dong, M. G., Sayyed, M. I., Lakshminarayana, G., Ersundu, M. Ç., Ersundu, A. E., Nayar, P., Mahdi, M. A.: Investigation of gamma radiation shielding properties of lithium zinc bismuth borate glasses using XCOM program and MCNP5 code. J. Non-Cryst. Solids 468, 12 (2017).10.1016/j.jnoncrysol.2017.04.018Suche in Google Scholar

16. Gerward, L., Guilbert, N., Jensen, K. B., Leving, H.: WinXCom–a program for calculating X-ray attenuation coefficients. Radiat. Phys. Chem. 71, 653 (2004).10.1016/j.radphyschem.2004.04.040Suche in Google Scholar

17. Sayyed, M. I.: Bismuth modified shielding properties of zinc boro-tellurite glasses. J. Alloys Compd. 688, 111 (2016).10.1016/j.jallcom.2016.07.153Suche in Google Scholar

18. Issa, S. A., Sayyed, M. I., Zaid, M. H. M., Matori, K. A.: Photon parameters for gamma-rays sensing properties of some oxide of lanthanides. Results Phys. 9, 206 (2018).10.1016/j.rinp.2018.02.039Suche in Google Scholar

19. Elbashir, B. O., Sayyed, M. I., Dong, M. G., Elmahroug, Y., Lakshminarayana, G., Kityk, I. V.: Characterization of Bi2O3ZnOB2O3 and TeO2ZnOCdOLi2OV2O5 glass systems for shielding gamma radiation using MCNP5 and Geant4 codes. J. Phys. Chem. Solids 126, 112 (2019).10.1016/j.jpcs.2018.10.034Suche in Google Scholar

20. Manohara, S. R., Hanagodimath, S. M., Gerward, L.: Energy absorption buildup factors of human organs and tissues at energies and penetration depths relevant for radiotherapy and diagnostics. J. Appl. Clin. Med. Phys. 12, 296 (2011).10.1120/jacmp.v12i4.3557Suche in Google Scholar PubMed PubMed Central

21. Singh, V. P., Badiger, N. M., Kaewkhao, J.: Radiation shielding competence of silicate and borate heavy metal oxide glasses: comparative study. J. Non-Cryst. Solids 404, 167 (2014).10.1016/j.jnoncrysol.2014.08.003Suche in Google Scholar

22. Sayyed, M. I., Lakshminarayana, G., Kityk, I. V., Mahdi, M. A.: Evaluation of shielding parameters for heavy metal fluoride based tellurite-rich glasses for gamma ray shielding applications. Radiat. Phys. Chem. 139, 33 (2017).10.1016/j.radphyschem.2017.05.013Suche in Google Scholar

23. Kavaz, E., Yorgun, N. Y.: Gamma ray buildup factors of lithium borate glasses doped with minerals. J. Alloys Compd. 752, 61 (2018).10.1016/j.jallcom.2018.04.106Suche in Google Scholar

24. Kaur, P., Singh, D., Singh, T.: Gamma rays shielding and sensing application of some rare earth doped lead-alumino-phosphate glasses. Radiat. Phys. Chem. 144, 336 (2018).10.1016/j.radphyschem.2017.09.018Suche in Google Scholar

25. El-Bashir, B. O., Sayyed, M. I., Zaid, M. H. M., Matori, K. A.: Comprehensive study on physical, elastic and shielding properties of ternary BaO-Bi2O3-P2O5 glasses as a potent radiation shielding material. J. Non-Cryst. Solids 468, 92 (2017).10.1016/j.jnoncrysol.2017.04.031Suche in Google Scholar

26. Sayyed, M. I., Kaky, K. M., Gaikwad, D. K., Agar, O., Gawai, U. P., Baki, S. O.: Physical, structural, optical and gamma radiation shielding properties of borate glasses containing heavy metals (Bi2O3/MoO3). J. Non-Cryst. Solids 507, 30 (2019).10.1016/j.jnoncrysol.2018.12.010Suche in Google Scholar

27. Gaikwad, D. K., Sayyed, M. I., Obaid, S. S., Issa, S. A., Pawar, P. P.: Gamma ray shielding properties of TeO2-ZnF2-As2O3-Sm2O3 glasses. J. Alloys Compd. 765, 451 (2018).10.1016/j.jallcom.2018.06.240Suche in Google Scholar

28. Sayyed, M. I., Rammah, Y. S., Abouhaswa, A. S., Tekin, H. O., Elbashir, B. O.: ZnO-B2O3-PbO glasses: synthesis and radiation shielding characterization. Physica B 548, 20 (2018).10.1016/j.physb.2018.08.024Suche in Google Scholar

Received: 2018-12-28
Accepted: 2019-03-22
Published Online: 2019-05-10
Published in Print: 2019-07-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 1.2.2026 von https://www.degruyterbrill.com/document/doi/10.1515/ract-2019-0014/html?lang=de
Button zum nach oben scrollen