Startseite Effect of solution acidity on the structure of amino acid-bearing uranyl compounds
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Effect of solution acidity on the structure of amino acid-bearing uranyl compounds

  • Evgeny V. Nazarchuk , Yuri A. Ikhalaynen , Dmitri O. Charkin EMAIL logo , Oleg I. Siidra , Vladimir G. Petrov , Stepan N. Kalmykov und Artem S. Borisov
Veröffentlicht/Copyright: 5. Januar 2019
Radiochimica Acta
Aus der Zeitschrift Radiochimica Acta Band 107 Heft 4

Abstract

A series of uranyl sulfates and selenates templated by protonated forms of amino acids (glycine, α- and β-alanine, threonine, nicotinic, and isonicotinic acid) has been prepared via isothermal evaporation of strongly acidic solutions. Their structures have been refined by the direct methods and can be classified as inorganic [(UO2)m(TO4)n (H2O)k] (T=S6+, Se6+) moieties combined with the protonated amino acid cations, water molecules and hydronium ions. Their overall motifs demonstrate common features with related structures templated by organic amines. The role of carboxylic acid groups depends on the nature of the corresponding amino acid. They can either link two protonated organic moieties into dimers, or contribute to hydrogen bonding between organic and inorganic parts of the structure. The ammonium ends of the amino acid cations form strong directional bonds to the oxygens of the uranyl and TO4 anions.

Keywords: Amino acids; templated uranyl compounds; crystal structures; X-ray diffraction

Acknowledgements

This work was financially supported by the Russian Science Foundation through the grant 16-17-10085. Technical support by the SPbSU X-ray Diffraction and Microscopy and Microanalysis Resource Centers is gratefully acknowledged.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/ract-2018-3050).

Received: 2018-08-18
Accepted: 2018-11-27
Published Online: 2019-01-05
Published in Print: 2019-03-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Cross-section measurements and production of 72Se with medium to high energy protons using arsenic containing targets
  3. Thorium oxide dissolution in HNO3-HF mixture: kinetics and mechanism
  4. Highly efficient carbonaceous nanofiber/layered double hydroxide nanocomposites for removal of U(VI) from aqueous solutions
  5. Effect of solution acidity on the structure of amino acid-bearing uranyl compounds
  6. A novel method for the determination of uranium and free acidity in nuclear fuel process samples by extraction spectrophotometry
  7. Experimental investigation of photon attenuation parameters for different binary alloys
  8. Radiation protective characteristics of some selected tungstates
  9. New high temperature resistant heavy concretes for fast neutron and gamma radiation shielding
https://doi.org/10.1515/ract-2018-3050
Schlagwörter für diesen Artikel
Amino acids; templated uranyl compounds; crystal structures; X-ray diffraction

Artikel in diesem Heft

  1. Frontmatter
  2. Cross-section measurements and production of 72Se with medium to high energy protons using arsenic containing targets
  3. Thorium oxide dissolution in HNO3-HF mixture: kinetics and mechanism
  4. Highly efficient carbonaceous nanofiber/layered double hydroxide nanocomposites for removal of U(VI) from aqueous solutions
  5. Effect of solution acidity on the structure of amino acid-bearing uranyl compounds
  6. A novel method for the determination of uranium and free acidity in nuclear fuel process samples by extraction spectrophotometry
  7. Experimental investigation of photon attenuation parameters for different binary alloys
  8. Radiation protective characteristics of some selected tungstates
  9. New high temperature resistant heavy concretes for fast neutron and gamma radiation shielding
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