Effect of gamma irradiation on the structure characteristics and mass attenuation coefficient of MgO nanoparticles
Abstract
In this work, the structure properties and mass attenuation coefficient of MgO nanoparticles were studied before and after gamma irradiation. The as-synthesized samples of MgO nanoparticles by sol–gel method were analyzed by XRD which suggested the double phase; cubic and hexagonal structures of the material. Crystal defects produced in the cubic and hexagonal lattice were studied before and after exposure to 20 kGy gamma irradiation in order to investigate the changes in the structure properties and mass attenuation coefficients of MgO nanoparticles. XRD data of gamma-irradiated and non-irradiated MgO nanoparticles show that the crystal size of MgO nanoparticles increases after radiation exposure. SEM images after irradiation indicated significant changes in the morphology. The UV-Visible absorption spectra of the nanoparticles were taken and the results of optical band gap of the MgO nanoparticles before and after irradiation show that the value of band gap has changed slightly due to gamma irradiation. The results of comparing experimental values of mass attenuation coefficient for non-irradiated MgO nanoparticles with theoretical values of mass attenuation coefficient for MgO microparticles calculated using the NIST XCOM show that the mass attenuation coefficient not only depends on the effective atomic number but also depends on the size of the particles. Also, it is observed that the mass attenuation coefficient of MgO nanoparticles decreases after the irradiation which shows that by increasing the size of the nanoparticles, the mass attenuation coefficient decreases. It could be because the cross-section of photon interaction with materials depends on the surface to volume ratio of nanoparticles. The experimental results also show that the linear and mass attenuation coefficient of MgO nanoparticles decrease with increasing the photon energy.
References
1. Singh, V. P., Ali, A. M., Badiger, N. M., El-Khayatt, A. M.: Monte Carlo simulation of gamma ray shielding parameters of concretes. Nucl. Eng. Des. 265, 1071 (2013).10.1016/j.nucengdes.2013.10.008Suche in Google Scholar
2. Oto, B.: Gamma-ray shielding of concretes including magnetite in different rate. Int. J. Phys. Sci. 8(8), 310 (2013).Suche in Google Scholar
3. Ehmann, W. D., Vance, D. E.: Radiochemistry and nuclear methods of analysis. John Wiley & Sons, Inc., New York (1993), p. 170.Suche in Google Scholar
4. Nelson, G., Reilly, D.: Gamma-ray interactions with matter. In: Passive nondestructive analysis of nuclear materials. Los Alamos National Laboratory (1991), p. 27.Suche in Google Scholar
5. Singh, V. P., Shirmardi, S. P., Medhat, M. E., Badiger, N. M.: Determination of mass attenuation coefficient for some polymers using Monte Carlo simulation. Vacuum 119, 284 (2015).10.1016/j.vacuum.2015.06.006Suche in Google Scholar
6. Yılmaz, E., Baltas, H., Kırıs, E., Ustabas, I., Cevik, U., El-Khayatt, A. M.: Gamma ray and neutron shielding properties of some concrete materials. Ann. Nucl. Energy 38(10), 2204 (2011).10.1016/j.anucene.2011.06.011Suche in Google Scholar
7. Akkurt, I., Günoğlu, K., Çalik, A., Karakas, M. S.: Determination of gamma ray attenuation coefficients of Al-4% Cu/B 4 C metal matrix composites at 662, 1173 and 1332 keV. Bull. Mater. Sci. 37(5), 1175 (2014).10.1007/s12034-014-0059-5Suche in Google Scholar
8. Akkurt, I., Akyildirim, H., Mavi, B., Kilincarslan, S., Basyigit, C.: Gamma-ray shielding properties of concrete including barite at different energies. Prog. Nucl. Energy 52(7), 620 (2010).10.1016/j.pnucene.2010.04.006Suche in Google Scholar
9. Chanthima, N., Prongsamrong, P., Kaewkhao, J., Limsuwan, P.: Simulated radiation attenuation properties of cement containing with BaSO4 and PbO. Procedia Eng. 32, 976 (2012).10.1016/j.proeng.2012.02.041Suche in Google Scholar
10. Singh, K., Singh, H., Sharma, V., Nathuram, R., Khanna, A., Kumar, R., Bhatti, S. S., Sahota, H. S.: Gamma-ray attenuation coefficients in bismuth borate glasses. Nucl. Instr. Meth. Phys. Res. B 194(1), 1 (2002).10.1016/S0168-583X(02)00498-6Suche in Google Scholar
11. Rahimi, R. A., Raisali, G., Sadrnezhaad, S. K., Alipour, A.: Chemical corrosion and gamma-ray attenuation properties of Zr and Ti containing lead silicate glasses. J. Nucl. Mater. 385(3), 527 (2009).10.1016/j.jnucmat.2008.12.046Suche in Google Scholar
12. Oto, B.: Determination of mass attenuation coefficients for concretes containing tincal concentrator waste. Int. J. Phys. Sci. 7(44), 5861 (2012).Suche in Google Scholar
13. Tekin, H. O., Singh, V. P., Manici, T.: Effects of micro-sized and nano-sized WO3 on mass attenauation coefficients of concrete by using MCNPX code. Appl. Radiat. Isot. 121, 122 (2017).10.1016/j.apradiso.2016.12.040Suche in Google Scholar PubMed
14. Nabiyouni, G., Boroojerdian, P., Hedayati, K., Ghanbari, D.: A simple method for synthesis of PbS nanoparticles using 2-mercaptoethanol as the capping agent. J. Mater. Chem. 22(47), 2460 (2012).10.1515/htmp-2011-0155Suche in Google Scholar
15. Krishnamoorthy, K., Moon, J. Y., Hyun, H. B., Cho, S. K., Kim, S. J.: Mechanistic investigation on the toxicity of MgO nanoparticles toward cancer cells. J. Mater. Chem. 22(47), 24610 (2012).10.1039/c2jm35087dSuche in Google Scholar
16. Bindhu, M. R., Umadevi, M., Micheal, M. K., Arasu, M. V., Al-Dhabi, N. A.: Structural, morphological and optical properties of MgO nanoparticles for antibacterial applications. Mater. Lett. 166, 19 (2016).10.1016/j.matlet.2015.12.020Suche in Google Scholar
17. Jorfi, S., Barzegar, G., Ahmadi, M., Soltani, R. D. C., Takdastan, A., Saeedi, R., Abtahi, M.: Enhanced coagulation-photocatalytic treatment of Acid red 73 dye and real textile wastewater using UVA/synthesized MgO nanoparticles. J. Environ. Manage. 177, 111 (2016).10.1016/j.jenvman.2016.04.005Suche in Google Scholar PubMed
18. Alavi, M. A., Morsali, A.: Syntheses and characterization of Mg (OH) 2 and MgO nanostructures by ultrasonic method. Ultrason. Sonochem. 17(2), 441 (2010).10.1016/j.ultsonch.2009.08.013Suche in Google Scholar PubMed
19. Oto, B., Yıldız, N., Akdemir, F., Kavaz, E.: Investigation of gamma radiation shielding properties of various ores. Prog. Nucl. Energy 85, 391 (2015).10.1016/j.pnucene.2015.07.016Suche in Google Scholar
20. Raut, A. V., Kurmude, D. V., Jadhav, S. A., Shengule, D. R., Jadhav, K. M.: Effect of 100 kGy γ-irradiation on the structural, electrical and magnetic properties of CoFe2 O4 NPs. J. Alloys Compd. 676, 326 (2016).10.1016/j.jallcom.2016.03.212Suche in Google Scholar
21. Iranizad, E. S., Dehghani, Z., Nadafan, M.: Nonlinear optical properties of nematic liquid crystal doped with different compositional percentage of synthesis of Fe3 O4 nanoparticles. J. Mol. Liq. 190, 6 (2014).10.1016/j.molliq.2013.09.032Suche in Google Scholar
22. Tiwary, K. P., Choubey, S. K., Sharma, K.: Structural and optical properties of ZnS nanoparticles synthesized by microwave irradiation method. Chalcogenide Lett. 10(9), 319 (2013).Suche in Google Scholar
23. Rahdar, A., Arbabi, V., Ghanbari, H.: Study of electro-optical properties of ZnS nanoparticles prepared by colloidal particles method. Int. J. Chem. Biol. Eng. 6, 81 (2012).Suche in Google Scholar
24. Chaudhari, L. M., Raje, D. V.: Investigation of attenuation coefficient of soil samples. Res. J. Agric. For. Sci. 1(2), 20 (2013).Suche in Google Scholar
25. National Institute of Standard and Technology, Physical Measurements Laboratory, XCOM Photon Cross-Section Database, http://Physics.nist.gov/PhysRefData/Xcom/html/xcom1.html.Suche in Google Scholar
©2018 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Determination of the stability constants of Pu(VI) carbonate complexes by capillary electrophoresis coupled with inductively coupled plasma mass spectrometer
- Sequential analysis of uranium and plutonium in environmental matrices by extractive liquid scintillation spectrometry
- A review of the analytical methodology to determine Radium-226 and Radium-228 in drinking waters
- Redox sorption of Ce(III)/Ce(IV) on potassium bismuthate
- Radioiodination, diagnostic nuclear imaging and bioevaluation of olmesartan as a tracer for cardiac imaging
- Synthesis of isotope – labeled selective PDE5 inhibitor sildenafil (UK 92480-10)
- Effect of gamma irradiation on the structure characteristics and mass attenuation coefficient of MgO nanoparticles
- Evaluation of gamma-ray attenuation properties of lithium borate glasses doped with barite, limonite and serpentine
- Corrigendum
- Corrigendum to: Uses of alpha particles, especially in nuclear reaction studies and medical radionuclide production
- Corrigendum to: Definitions of radioisotope thick target yields
Artikel in diesem Heft
- Frontmatter
- Determination of the stability constants of Pu(VI) carbonate complexes by capillary electrophoresis coupled with inductively coupled plasma mass spectrometer
- Sequential analysis of uranium and plutonium in environmental matrices by extractive liquid scintillation spectrometry
- A review of the analytical methodology to determine Radium-226 and Radium-228 in drinking waters
- Redox sorption of Ce(III)/Ce(IV) on potassium bismuthate
- Radioiodination, diagnostic nuclear imaging and bioevaluation of olmesartan as a tracer for cardiac imaging
- Synthesis of isotope – labeled selective PDE5 inhibitor sildenafil (UK 92480-10)
- Effect of gamma irradiation on the structure characteristics and mass attenuation coefficient of MgO nanoparticles
- Evaluation of gamma-ray attenuation properties of lithium borate glasses doped with barite, limonite and serpentine
- Corrigendum
- Corrigendum to: Uses of alpha particles, especially in nuclear reaction studies and medical radionuclide production
- Corrigendum to: Definitions of radioisotope thick target yields