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Redox sorption of Ce(III)/Ce(IV) on potassium bismuthate

  • R. S. Hassan , H. S. Hassan , Elsayed K. Elmaghraby EMAIL logo and E. H. Borai
Published/Copyright: May 29, 2018

Abstract

Potassium bismuthate rods was synthesized in a form of elongated rods in non-aqueous methanol medium. The material morphology and structure were investigated using energy dispersive spectroscopy, scanning electron microscopy, and X-ray diffraction. The effects of annealing temperature on the material morphology and structure were investigated. Sorption kinetic study and ionic selectivity was investigated using batch technique. The sorption of Ce3+ on potassium bismuthate was found to be Ce3+ cation’s ionic state selective process. Results showed that the chemical sorption of Ce3+ ionic state in KBiO3 follows the reduction of Bi5+ to Bi2− as a result of the formation of cerium bismuthide (Ce23+Bi2O2). The suggested chemo-sorption mechanism includes equilibration parallel processes of the released K+ to form K2CeO2 and Bi2O3 that consumes the original material. The sorption kinetic has two different orders depending on contact time, isotherms fits adequately with Freundlich model and Dubinin-Radushkevich model. The material is considered a candidate for lanthanides radioactivity removal from aqueous media for radioactive waste disposal processes.

References

1. Hassan, H., Elmaghraby, E. K.: Preparation of graphite by thermal annealing of polyacrylamide precursor for adsorption of Cs(I) and Co(II) ions from aqueous solutions. Can. J. Chem. 90, 1 (2012).10.1139/v2012-058Search in Google Scholar

2. Khoiruddin, Aryanti, P. T. P., Hakim, A. N., Wenten, I. G.: The role of ion-exchange membrane in energy conversion. AIP Conf. Proc. 1840(1), 090006 (2017).10.1063/1.4982314Search in Google Scholar

3. Prifti, H., Parasuraman, A., Winardi, S., Lim, T. M., Skyllas-Kazacos, M.: Membranes for redox flow battery applications. Membranes 2(4), 275 (2012).10.3390/membranes2020275Search in Google Scholar PubMed PubMed Central

4. Mills, A., Li, X.: Kinetics of reductive dissolution of sodium bismuthate by CeIII and MnII ions. J. Chem. Soc., Faraday Trans. 90, 2939 (1994).10.1039/ft9949002939Search in Google Scholar

5. Roy, K., Mohapatra, P., Rawat, N., Pal, D., Basu, S., Manchanda, V.: Separation of 90Y from 90Sr using zirconium vanadate as the ion exchanger. Appl. Radiat. Isotopes 60(5), 621 (2004).10.1016/j.apradiso.2003.09.015Search in Google Scholar PubMed

6. Shannon, R. D.: Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A 32(5), 751 (1976).10.1107/S0567739476001551Search in Google Scholar

7. Gupta, C. K., Krishnamurthy, N.: Extractive metallurgy of rare earths. Int. Mater. Rev. 37(1), 197 (1992).10.1179/imr.1992.37.1.197Search in Google Scholar

8. Borai, E., El-Ghany, M., Ahmed, I., Hamed, M., El-Din, A. S., Aly, H.: Modified acidic leaching for selective separation of thorium, phosphate and rare earth concentrates from Egyptian crude monazite. Int. J. Min. Proc. 149, 34 (2016).10.1016/j.minpro.2016.02.003Search in Google Scholar

9. Janots, E., Bernier, F., Brunet, F., noz, M. M., Trcera, N., Berger, A., Lanson, M.: Ce(III) and Ce(IV) (re)distribution and fractionation in a laterite profile from Madagascar: insights from in situ XANES spectroscopy at the Ce LIII-edge. Geochimica et Cosmochimica Acta 153, 134 (2015).10.1016/j.gca.2015.01.009Search in Google Scholar

10. Ali, M., El-Alfy, M., Zayed, M., Rabie, K., El-Hazek, N., Aly, H.: Separation of cerium (III) from Egyptian monazite by oxidation to cerium (IV). Damascus; 1996, Third Arab Conference on the Peaceful Uses of Atomic Energy.Search in Google Scholar

11. Topp, N.: The Chemistry of the Rare-Earth Elements. Topics in Inorganic and General Chemistry, Elsevier Pub. Co., Amsterdam and New York (1965).Search in Google Scholar

12. Fritz, J. S., Grady, H. R., Harris, R. E., Hartford, W. H., Hausman, E. A., Walsh, T. J., Woyski, M. M.: Treatise on Analytical Chemistry; vol. 8; chap. Part II Analytical Chemistry of the Elements Section A Systematic Analytical Chemistry of the Elements, Interscience Publishers, USA (1963), p. 180.Search in Google Scholar

13. Kedari, C. S., Pandit, S. S., Ramanujam, A.: Studies on the in situ electrooxidation and selective permeation of cerium(IV) across a bulk liquid membrane containing tributyl phosphate as the ion transporter. Sep. Sci. Technol. 34(9), 1907 (1999).10.1081/SS-100100746Search in Google Scholar

14. Donohue, T.: Photochemical separation of cerium from rare earth mixtures in aqueous solution. Chem. Phys. Lett. 61(3), 601 (1979).10.1016/0009-2614(79)87181-XSearch in Google Scholar

15. Hirai, T., Komasawa, I.: Separation of ce from La/Ce/Nd mixture by photooxidation and liquid-liquid extraction. J. Chem. Eng. Jpn. 29(4), 731 (1996).10.1252/jcej.29.731Search in Google Scholar

16. Sun, C., Li, H., Chen, L.: Nanostructured ceria-based materials: synthesis, properties, and applications. Energy Environ. Sci. 5, 8475 (2012).10.1039/c2ee22310dSearch in Google Scholar

17. Zdenek, K., Jana, S., Ivan, K., Marianna, H.: Vermiculite as efficient sorbent of CeIII and CeIV. Environ. Chem. 14, 39 (2016).10.1071/EN16112Search in Google Scholar

18. Irvine, J. T. S.: Chapter 20. New compounds and structures. Annu. Rep. Prog. Chem. Sect. A: Inorg. Chem. 88, 397 (1991).10.1039/ic9918800397Search in Google Scholar

19. Villars, P., Cenzual, K.: KBiO3 Crystal Structure. Springer-Verlag Berlin Heidelberg & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), (Japan) 2018. Accessed Jul. 14, 2017.Search in Google Scholar

20. Arora, A.: Text Book of Inorganic Chemistry, Discovery Publishing House Pvt. Limited, New Delhi (2005). ISBN 9788183560139.Search in Google Scholar

21. Kodialam, S., Korthius, V., Hoffmann, R. D., Sleight, A.: Electrodeposition of potassium bismuthate: KBiO3. Mater. Res. Bull. 27(12), 1379 (1992).10.1016/0025-5408(92)90002-HSearch in Google Scholar

22. Nguyen, T. N., Giaquinta, D. M., Davis, W. M., zur Loye, H. C.: Electrosynthesis of KBiO3 (potassium bismuth oxide): a potassium ion conductor with the ksbo3 (potassium antimony oxide) tunnel structure. Chem. Mater. 5(9), 1273 (1993).10.1021/cm00033a015Search in Google Scholar

23. Jansen, M.: Darstellung von wasserfreiem KBiO3. Z. Naturforsch. B 32b, 1340 (1977).10.1515/znb-1977-1123Search in Google Scholar

24. Zhang, Q., Sando, D., Nagarajan, V.: Chemical route derived bismuth ferrite thin films and nanomaterials. J. Mater. Chem. C 4, 4092 (2016).10.1039/C6TC00243ASearch in Google Scholar

25. Hamed, M. M., Ali, M., Holiel, M.: Preparation of activated carbon from doum stone and its application on adsorption of 60Co and 152+154Eu: equilibrium, kinetic and thermodynamic studies. J. Environ. Radioact. 164, 113 (2016).10.1016/j.jenvrad.2016.07.005Search in Google Scholar

26. Ho, Y., McKay, G.: The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Res. 34(3), 735 (2000).10.1016/S0043-1354(99)00232-8Search in Google Scholar

27. Ho, Y. S.: Review of second-order models for adsorption systems. J. Hazard. Mater. 136(3), 681 (2006).10.1016/j.jhazmat.2005.12.043Search in Google Scholar PubMed

28. Langmuir, I.: The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 40(9), 1361 (1918).10.1021/ja02242a004Search in Google Scholar

29. Hamed, M. M., Attallah, M. F., Shehata, F. A.: Synthesis, characterization and sorption behavior of some radionuclides on zirconium tungstate ion exchanger. Arab. J. Nul. Sci. App. 45, 37 (2012).Search in Google Scholar

30. Hamed, M. M.: Sorbent extraction behavior of a nonionic surfactant, triton X-100, onto commercial charcoal from low level radioactive waste. J. Radioanal. Nucl. Chem. 302(1), 303 (2014).10.1007/s10967-014-3250-7Search in Google Scholar

31. Tang, D., Zhang, G.: Efficient removal of fluoride by hierarchical Ce-Fe bimetal oxides adsorbent: thermodynamics, kinetics and mechanism. Chem. Eng. J. 283, 721 (2016).10.1016/j.cej.2015.08.019Search in Google Scholar

32. Dubinin, M.: The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chem. Rev. 60(2), 235 (1960).10.1021/cr60204a006Search in Google Scholar

33. Okoli, C. P., Diagboya, P. N., Anigbogu, I. O., Olu-Owolabi, B. I., Adebowale, K. O.: Competitive biosorption of Pb(II) and Cd(II) ions from aqueous solutions using chemically modified moss biomass (Barbula lambarenensis). Environ. Earth Sci. 76(1), 33 (2016).10.1007/s12665-016-6368-9Search in Google Scholar

34. Manes, M., Hofer, L. J. E.: Application of the Polanyi adsorption potential theory to adsorption from solution on activated carbon. J. Phys. Chem. 73(3), 584 (1969).10.1021/j100723a018Search in Google Scholar

35. Angn, D., Köse, T. E., Selengil, U.: Production and characterization of activated carbon prepared from safflower seed cake biochar and its ability to absorb reactive dyestuff. Appl. Sur. Sci. 280, 705 (2013).10.1016/j.apsusc.2013.05.046Search in Google Scholar

36. Schneider, C. A., Rasband, W. S., Eliceiri, K. W.: NIH image to ImageJ: 25 years of image analysis. Nat. Meth. 9(7), 671 (2012).10.1038/nmeth.2089Search in Google Scholar PubMed PubMed Central

37. Rita Cornelis Joe Caruso, H. C. K. G. H.: Handbook of Elemental Speciation; vol. I: Techniques and Methodology, John Wiley & Sons Inc., USA (2003).10.1002/0470868384Search in Google Scholar

38. Rita Cornelis Joe Caruso, H. C. K. G. H.: Handbook of Elemental Speciation; vol. II: Species in the Environment, Food, Medicine and Occupational Health. John Wiley & Sons Inc., USA (2003).10.1002/0470868384Search in Google Scholar

39. Zhao, D., Yang, X., Zhang, H., Chen, C., Wang, X.: Effect of environmental conditions on Pb(II) adsorption on β-Mno2. Chem. Eng. J. 164(1), 49 (2010).10.1016/j.cej.2010.08.014Search in Google Scholar

40. Helgeson, H. C., Kirkham, D. H., Flowers, G. C.: Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures; IV, calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 degrees C and 5kb. Am. J. Sci. 281(10), 1249 (1981).10.2475/ajs.281.10.1249Search in Google Scholar

41. Oelkers, E. H., Helgeson, H. C.: Calculation of dissociation constants and the relative stabilities of polynuclear clusters of 1:1 electrolytes in hydrothermal solutions at supercritical pressures and temperatures. Geochimi Cosmochimi Acta 57(12), 2673 (1993).10.1016/0016-7037(93)90383-8Search in Google Scholar

42. Nakada, R., Takahashi, Y., Tanimizu, M.: Isotopic and speciation study on cerium during its solid-water distribution with implication for Ce stable isotope as a paleo-redox proxy. Geochimica et Cosmochimica Acta 103, 49 (2013).10.1016/j.gca.2012.10.045Search in Google Scholar

43. Arenas, L., de Leon, C. P., Walsh, F.: Electrochemical redox processes involving soluble cerium species. Electrochim. Acta 205, 226 (2016).10.1016/j.electacta.2016.04.062Search in Google Scholar

44. Borai, E., Eid, M., Aly, H.: Determination of REEs distribution in monazite and xenotime minerals by ion chromatography and ICP-AES. Anal. Bioanal. Chem. 372(4), 537 (2002).10.1007/s00216-001-1204-8Search in Google Scholar PubMed

45. Hamed, M. M., Hilal, M., Borai, E.: Chemical distribution of hazardous natural radionuclides during monazite mineral processing. J. Environ. Radioact. 162, 166 (2016).10.1016/j.jenvrad.2016.05.028Search in Google Scholar PubMed

46. Sardar, K., Playford, H. Y., Darton, R. J., Barney, E. R., Hannon, A. C., Tompsett, D., Fisher, J., Kashtiban, R. J., Sloan, J., Ramos, S., Cibin, G., Walton, R. I.: Nanocrystalline cerium-bismuth oxides: synthesis, structural characterization, and redox properties. Chem. Mater. 22(22), 6191 (2010).10.1021/cm1025848Search in Google Scholar

47. Ciobanu, G., Bargan, A. M., Luca, C.: New cerium(IV)-substituted hydroxyapatite nanoparticles: preparation and characterization. Ceramics Int. 41(9), 12192 (2015).10.1016/j.ceramint.2015.06.040Search in Google Scholar

Received: 2017-12-05
Accepted: 2018-04-12
Published Online: 2018-05-29
Published in Print: 2018-10-25

©2018 Walter de Gruyter GmbH, Berlin/Boston

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