Design of locally sourced activated charcoal filter from maize cob for wastewater decontamination: an approach to fight waste with waste
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Lawrence Olusegun Ajala
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Ewa Ezeali Ali
Abstract
This research studied decontamination of laboratory wastewater with an activated carbon derived from maize cob, an agricultural waste to ascertaining its adsorption effectiveness for water treatment. The preparation conditions such as the concentration of the activating agent, impregnation ratio, impregnation temperature, impregnation time, activation temperature and activation time were optimized. The adsorbent’s porous properties revealed its adsorption potency was correlated with the iodine value. The test adsorbent showed significant contaminants adsorption in the laboratory wastewater; the results obtained were within the standards for drinking water set by the regulatory agencies. This agricultural waste could be considered for the preparation of activated carbon which would ultimately serve as an alternative method of decontaminating laboratory wastewater.
Funding source: Tertiary Education Trust Fund (TETFund) of the Federal Republic of Nigeria
Funding source: Tertiary Education Trust Fund
Award Identifier / Grant number: Unassigned
Acknowledgments
The authors express their profound gratitude to the Department of Science Laboratory Technology of Akanu Ibiam Federal Polytechnic, Unwana, Nigeria, for providing the facilities for this study. Also, the technical assistance of Gabriel Ocheja and Olusola Akinola of National Steel Raw Materials Exploration Agency, Kaduna, Nigeria and Central Laboratory of Obafemi Awolowo University, Ile-Ife, Nigeria respectively, are appreciated.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This research was proudly supported and sponsored by Tertiary Education Trust Fund (TETFund) of the Federal Republic of Nigeria.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Tak, B, Tak, B, Kim, Y, Park, Y, Yoon, Y, Min, G. Optimization of colour and COD removal from livestock wastewater by electrocoagulation process: application of Box-Behnken design (BBD). J Ind Eng Chem 2015;28:307–15. https://doi.org/10.1016/j.jiec.2015.03.008.Search in Google Scholar
2. Wang, J, Wu, F, Wang, M, Qui, N, Liang, Y, Fang, S, et al.. Preparation of activated carbon from a renewable agricultural residue of pruning mulberry shoot. Afr J Biotechnol 2010;9:2762–7.Search in Google Scholar
3. Ajala, LO, Ali, EE. Potential of groundnut shell-based activated charcoal for laboratory water treatment. J Environ Sci Toxicol Food Technol 2020;14:54–9.Search in Google Scholar
4. Abraham, FA, Thenmozhi, R, Sivakumar, M, Sivakumar, K, Sasikumar, G, Thamaraimuthuayyanraj, S. Waste water treatment unit using activated charcoal. Int Res J Eng Technol 2018;5:312–5.Search in Google Scholar
5. Jacob, AG, Okunola, OJ, Uduma, AU, TijjaniA, HS. Treatment of waste water by activated carbon developed from Borassus aethiopum. Nig J Mat Sci Eng 2017;6:103–7.Search in Google Scholar
6. Olagunju, EO, Ajala, LO, Farombi, AG. Sustainable utilization of rice husk activated charcoal through phytoremediation. Phy Sci Int J 2015;5:81–7. https://doi.org/10.9734/psij/2015/12318.Search in Google Scholar
7. Amirza, MAR, Adib, MMR, Hamdan, R. Application of agricultural wastes activated carbon for dye removal – an overview. MATEC Web Conf 2017;103:6–13. https://doi.org/10.1051/matecconf/201710306013.Search in Google Scholar
8. Reza, MS, Hasan, ABM, Afroze, K, Abu-Bakar, MS, Taweekun, J, Azad, AK. Analysis on preparation, application, and recycling of activated carbon to aid in Covid-19 protection. Int J Integ Eng 2020;12:233–44. https://doi.org/10.30880/ijie.2020.12.05.030.Search in Google Scholar
9. Yusufu, MI, Ariahu, CC, Igbabul, BD. Production and characterization of activated carbon from selected local raw materials. Afr J Pure Appl Chem 2012;6:123–31.10.5897/AJPAC12.022Search in Google Scholar
10. Marichelvan, MK, Azhagurajan, A. Removal of mercury from effluent solution by using banana corm and neem leaves activated charcoal. Environ Nanotechnol Monit Manag 2018;10:360–5.10.1016/j.enmm.2018.08.005Search in Google Scholar
11. Ijaola, OO, Ogedengbe, K, Sangodoyin, AY. On the efficacy of activated carbon derived from bamboo in the adsorption of water contaminants. Int J Eng Inv 2013;2:29–34.Search in Google Scholar
12. Sivakumar, V, Asaithambi, M, Sivakumar, P. Physic-chemical and adsorption studies of activated carbon from agricultural wastes. Adv Appl Sci Res 2012;3:219–26.Search in Google Scholar
13. Ukpaka, CP, Edwin, I. Adsorbent in bioremediation of crude oil polluted environment: influence of physicochemical characteristics of various saw dusts. Int Res J Biotechnol 2013;4:124–41.Search in Google Scholar
14. Hegazi, HA. Removal of heavy metals from wastewater using agricultural and industrial wastes as adsorbents. HBRC J 2013;9:276–82. https://doi.org/10.1016/j.hbrcj.2013.08.004.Search in Google Scholar
15. Gokhale, NA, Trivedi, NS, Mandavgane, SA, Kulkarni, BD. Biomass ashes as potent adsorbent for pesticide: prediction of adsorption capacity by artificial neural network. Int J Environ Sci Tech 2020;17:3209–16. https://doi.org/10.1007/s13762-020-02645-9.Search in Google Scholar
16. Mopoung, S, Moonsri, P, Palas, W, Khumpai, S. Characterization and properties of activated carbon prepared from tamarind seeds by KOH activation for Fe (III) adsorption from aqueous solution. Sci World J 2015;2015:9. https://doi.org/10.1155/2015/415961.Search in Google Scholar PubMed PubMed Central
17. Elelu, S, Adebayo, GB, Abduls-Salam, N, Iriowen, EM. Preparation and characterization of adsorbents from physic nut plant (Jatropha curcas L.). The Chemist 2019;91:42–9.Search in Google Scholar
18. Özsin, G, Kılıç, M, Apaydın-Varol, E, Pütün, AE. Chemically activated carbon production from agricultural waste of chickpea and its application for heavy metal adsorption: equilibrium, kinetic, and thermodynamic studies. Appl Water Sci 2019;9. https://doi.org/10.1007/s13201-019-0942-8.Search in Google Scholar
19. Ani, JU, Akpomie, KG, Okoro, UC, AnekeLE, Onukwuli, OD, Ujam, OT. Potentials of activated carbon produced from biomass materials for sequestration of dyes, heavy metals, and crude oil components from aqueous environment. Appl Water Sci 2020;10. https://doi.org/10.1007/s13201-020-1149-8.Search in Google Scholar
20. Jun, W, Fu-An, W, Meng, W, Ning, Q, Yao, L, Shui-Qin, F, et al.. Preparation of activated carbon from renewable agricultural residue of pruning mulberry shoot. Afr J Biotechnol 2010;9:2762–7.Search in Google Scholar
21. Ajala, LO, Ali, EE. Preparation and characterization of groundnut shell-based activated charcoal. J Appl Sci Environ Manage 2020;24:2139–46.10.4314/jasem.v24i12.20Search in Google Scholar
22. Boonpoke, A, Chiarakorn, S, Laosiripojana, N, Towprayoon, S, Chidthaisong, A. Synthesis of activated carbon and MCM-41 from bagasse and rice husk and their carbon dioxide adsorption capacity. J Sust Energy Environ 2011;2:77–81.Search in Google Scholar
23. Ajala, LO, Onwukeme, VI, Oji, CO, Ejiagha, MC. Sustainable utilization of rice husk activated charcoal as wastewater decontaminant. In: Tüzemen, S, editor. New insights into physical science. India: Book Publisher International; 2020, vol. 2:111–25 pp.Search in Google Scholar
24. Subramani, T, Revathi, PK. Production of activated carbon from agricultural raw waste. J Eng 2015;5:54–63.Search in Google Scholar
25. Alzaydien, AS. Physical chemical and adsorptive characteristics of local oak sawdust based activated carbons. Asian J Sci Res 2016;9:45–56. https://doi.org/10.3923/ajsr.2016.45.56.Search in Google Scholar
26. Gawande, PR, Kaware, JP. Characterization and activation of coconut shell activated carbon. Int J Eng Sci Inv 2017;6:43–9.Search in Google Scholar
27. Hidayat, A, Sutrisno, B. Comparison on pore development of activated carbon produced by chemical and physical activation from palm empty fruit bunch. IOP Conf Ser Mater Sci Eng 2017;162.10.1088/1757-899X/162/1/012008Search in Google Scholar
28. Saka, C. BET, TG-DTG, FT-IR, SEM, iodine number analysis and preparation of activated carbon from acorn shell by chemical activation with ZnCl2. J Anal Appl Pyrol 2012;95:21–4. https://doi.org/10.1016/j.jaap.2011.12.020.Search in Google Scholar
29. ASTM. Standard test method for determination of iodine number of activated carbon. Philadelphia: American Standard of Testing and Measurement committee on standards; 2006.Search in Google Scholar
30. APHA. Standard methods for the examination of water and waste water, 21th ed. Washington DC: American Public Health Association standard methods; 2005.Search in Google Scholar
31. Abdul-Khalil, HPS, Jawaid, M, Firoozian, P, Rashid, U, Islam, A, Akil, HM. Activated carbon from various agricultural wastes by chemical activation with KOH: preparation and characterization. J Biobased Mater Bioenergy 2013;7. https://doi.org/10.1166/jbmb.2013.1379.Search in Google Scholar
32. Rangaraj, S, Moon, SH, Sivabalan, R, Arabidoo, B, Murugesan, V. Agricultural waste for the removal of organics: adsorption of phenol from water and wastewater by palm seed coat activated carbon. Waste Manag 2002;22:543–8.10.1016/S0956-053X(01)00016-2Search in Google Scholar
33. Morlay, C, Gasperi, J, Guillossou, R, Mailler, R, Le Roux, J, Rocher, V, et al.. Organic micropollutants in a large wastewater treatment plant: what are the benefits of an advanced treatment by activated carbon adsorption in comparison to conventional treatment? Chemosphere 2019;218:1050–60. https://doi.org/10.1016/j.chemosphere.2018.11.182.Search in Google Scholar PubMed
34. Siong, YK, Idris, AJ, Atabaki, AMM. Performance of activated carbon in water filters; 2013. https://www.researchgate.net/publication/234060484mm [Assessed Nov 2019].Search in Google Scholar
35. Zdravkov, BD, Čermák, JJ, Šefara, M, Janků, J. Pore classification in the characterization of porous materials: a perspective. Cent Eur J Chem 2007;5:385–95. https://doi.org/10.2478/s11532-007-0017-9.Search in Google Scholar
36. Ademiluyi, FT, Amadi, SA, Amakama, NJ. Adsorption and treatment of organic contaminants using activated carbon from waste Nigerian bamboo. J Appl Sci Environ Manage 2009;13:39–47.10.4314/jasem.v13i3.55351Search in Google Scholar
37. Williams, D, Fleming, I. Spectroscopic methods in organic chemistry, 6th ed. Berkshire, UK: McGrew Hill; 2008.Search in Google Scholar
38. Pavia, DL, Lampman, GM, Kriz, GS, Vyvyan, JR. Introduction to spectroscopy, 5th ed. USA: Cengage Learning; 2015.Search in Google Scholar
39. WHO. Guidelines for drinking water quality. Geneva: World Health Organization; 2003.Search in Google Scholar
40. SON. Nigerian standard for drinking water quality. Lagos: Nigerian Industrial Standard (NIS) of Standard Organization of Nigeria; 2007.Search in Google Scholar
41. USEPA. Drinking water standards and health advisories. Washington DC: United State Environmental Protection Agency; 2012.Search in Google Scholar
42. Okonkwo, EM, Eboatu, AN. Environmental pollution and degradation, 2nd ed. Awka, Nigeria: Abimac Publishers; 2006.Search in Google Scholar
© 2021 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Reviews
- Influence of lime (CaO) on low temperature leaching of some types of bauxite from Guinea
- Ethnobotanical survey, phytoconstituents and antibacterial investigation of Rapanea melanophloeos (L.) Mez. bark, fruit and leaf extracts
- Catalytic properties of supramolecular polymetallated porphyrins
- Lignin-based polymers
- Bio-based polyhydroxyalkanoates blends and composites
- Biodegradable poly(butylene adipate-co-terephthalate) (PBAT)
- Repurposing tires – alternate energy source?
- Theoretical investigation of the stability, reactivity, and the interaction of methyl-substituted peridinium-based ionic liquids
- Polymeric membranes for biomedical applications
- Design of locally sourced activated charcoal filter from maize cob for wastewater decontamination: an approach to fight waste with waste
- Synthesis of biologically active heterocyclic compounds from allenic and acetylenic nitriles and related compounds
- Magnetic measurement methods to probe nanoparticle–matrix interactions
- Health and exposure risk assessment of heavy metals in rainwater samples from selected locations in Rivers State, Nigeria
- Evaluation of raw, treated and effluent water quality from selected water treatment plants: a case study of Lagos Water Corporation
- A chemoinformatic analysis of atoms, scaffolds and functional groups in natural products
- Hemicyanine dyes
- Thermodynamics of the micellization of quaternary based cationic surfactants in triethanolamine-water media: a conductometry study
- Compounds isolated from hexane fraction of Alternanthera brasiliensis show synergistic activity against methicillin resistant Staphylococcus aureus
- Internal structures and mechanical properties of magnetic gels and suspensions
- SPIONs and magnetic hybrid materials: Synthesis, toxicology and biomedical applications
- Magnetic field controlled behavior of magnetic gels studied using particle-based simulations
- The microstructure of magnetorheological materials characterized by means of computed X-ray microtomography
- Core-modified porphyrins: novel building blocks in chemistry
- Anticancer potential of indole derivatives: an update
- Novel drug design and bioinformatics: an introduction
- Multi-objective optimization of CCUS supply chains for European countries with higher carbon dioxide emissions
- Exergy analysis of an atmospheric residue desulphurization hydrotreating process for a crude oil refinery
- Development in nanomembrane-based filtration of emerging contaminants
- Supply chain optimization framework for CO2 capture, utilization, and storage in Germany
- Naturally occurring heterocyclic anticancer compounds
- Part-II- in silico drug design: application and success
- Advances in biopolymer composites and biomaterials for the removal of emerging contaminants
- Nanobiocatalysts and photocatalyst in dye degradation
- 3D tumor model – a platform for anticancer drug development
- Hydrogen production via water splitting over graphitic carbon nitride (g-C3N4 )-based photocatalysis
Articles in the same Issue
- Frontmatter
- Reviews
- Influence of lime (CaO) on low temperature leaching of some types of bauxite from Guinea
- Ethnobotanical survey, phytoconstituents and antibacterial investigation of Rapanea melanophloeos (L.) Mez. bark, fruit and leaf extracts
- Catalytic properties of supramolecular polymetallated porphyrins
- Lignin-based polymers
- Bio-based polyhydroxyalkanoates blends and composites
- Biodegradable poly(butylene adipate-co-terephthalate) (PBAT)
- Repurposing tires – alternate energy source?
- Theoretical investigation of the stability, reactivity, and the interaction of methyl-substituted peridinium-based ionic liquids
- Polymeric membranes for biomedical applications
- Design of locally sourced activated charcoal filter from maize cob for wastewater decontamination: an approach to fight waste with waste
- Synthesis of biologically active heterocyclic compounds from allenic and acetylenic nitriles and related compounds
- Magnetic measurement methods to probe nanoparticle–matrix interactions
- Health and exposure risk assessment of heavy metals in rainwater samples from selected locations in Rivers State, Nigeria
- Evaluation of raw, treated and effluent water quality from selected water treatment plants: a case study of Lagos Water Corporation
- A chemoinformatic analysis of atoms, scaffolds and functional groups in natural products
- Hemicyanine dyes
- Thermodynamics of the micellization of quaternary based cationic surfactants in triethanolamine-water media: a conductometry study
- Compounds isolated from hexane fraction of Alternanthera brasiliensis show synergistic activity against methicillin resistant Staphylococcus aureus
- Internal structures and mechanical properties of magnetic gels and suspensions
- SPIONs and magnetic hybrid materials: Synthesis, toxicology and biomedical applications
- Magnetic field controlled behavior of magnetic gels studied using particle-based simulations
- The microstructure of magnetorheological materials characterized by means of computed X-ray microtomography
- Core-modified porphyrins: novel building blocks in chemistry
- Anticancer potential of indole derivatives: an update
- Novel drug design and bioinformatics: an introduction
- Multi-objective optimization of CCUS supply chains for European countries with higher carbon dioxide emissions
- Exergy analysis of an atmospheric residue desulphurization hydrotreating process for a crude oil refinery
- Development in nanomembrane-based filtration of emerging contaminants
- Supply chain optimization framework for CO2 capture, utilization, and storage in Germany
- Naturally occurring heterocyclic anticancer compounds
- Part-II- in silico drug design: application and success
- Advances in biopolymer composites and biomaterials for the removal of emerging contaminants
- Nanobiocatalysts and photocatalyst in dye degradation
- 3D tumor model – a platform for anticancer drug development
- Hydrogen production via water splitting over graphitic carbon nitride (g-C3N4 )-based photocatalysis
