Effect of AO 4426 on damping properties of PVA/CPE-AO 2246

Jiang Sheng; Zhang Yong

doi:10.1515/polyeng-2024-0219

Article

Effect of AO 4426 on damping properties of PVA/CPE-AO 2246

Jiang Sheng and Zhang Yong

Published/Copyright: February 4, 2025

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From the journal Journal of Polymer Engineering Volume 45 Issue 3

Abstract

To investigate the influence of AO 2246 and AO 4426 on the damping properties of polyvinyl alcohol/chlorinated polyethylene (PVA/CPE) composites, a series of composites were prepared by adding AO 4426 into PVA/CPE-AO 2246 under the constant mass ratio of hindered phenol in the composites. The dynamic mechanical properties and microstructure of materials were investigated by DMA, DSC, SEM, and FT-IR. The results showed that a new damping peak appeared near 50 °C by adding AO 4426, which indicated phase separation between AO 4426 and the matrix occurred. With the increase of AO 4426, the damping peaks in the low-temperature section were improved. The value of low-lying region between the double damping peaks, when the hindered phenol coexisted was higher than that of the composites containing only AO 4426, which indicated that the damping temperature domain of the composites was effectively broadened. At the melting temperature of AO 4426 microcrystalline and AO 2246 microcrystalline, no obvious peaks were observed simultaneously, indicating that the hindered phenols inhibited the crystallization of each other.

Keywords: 4,4′-methylene-bis(2,6-di-tert-butylphenol) (AO 4426); 2,2′-methylene-bis (4-methyl-6-tert-butylphenol) (AO 2246); phase separation; damping performance; spatial resistance effects

Corresponding author: Jiang Sheng, Division of Science and Technology, Jiangsu College of Engineering and Technology, Nantong, Jiangsu 226001, China; and Jiangsu Advanced Textile Engineering Technology Center, Nantong, Jiangsu 226001, China, E-mail: jiangsheng2437@126.com

Funding source: Applied Research Foundation of Nantong city, Jiangsu Province, China

Award Identifier / Grant number: JC2018107

Research ethics: Not applicable.
Informed consent: Not applicable.
Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission. Jiang Sheng: conceptualization, experimental work, data analysis, and writing. Zhang Yong: writing – review & editing.
Use of Large Language Models, AI and Machine Learning Tools: None declared.
Conflict of interest: The authors state no conflict of interest.
Research funding: This work was financially supported by Applied Research Foundation of Nantong city, Jiangsu Province, China (JC2018107).
Data availability: The raw data can be obtained on request from Jiang Sheng.

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Received: 2024-10-14

Accepted: 2024-12-18

Published Online: 2025-02-04

Published in Print: 2025-03-26

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Articles in the same Issue

https://doi.org/10.1515/polyeng-2024-0219

Keywords for this article

4,4′-methylene-bis(2,6-di-tert-butylphenol) (AO 4426); 2,2′-methylene-bis (4-methyl-6-tert-butylphenol) (AO 2246); phase separation; damping performance; spatial resistance effects