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Effect of lyocell fiber cross-sectional shape on structure and properties of lyocell/PLA composites

  • Yang Shen , Gesheng Yang ORCID logo , Kevin J. Edgar , Huihui Zhang ORCID logo EMAIL logo and Huili Shao
Published/Copyright: July 20, 2022
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Abstract

Three kinds of lyocell fibers with different cross-sectional profiles including circular, Y-shape, and H-shape (abbreviated as O-, Y-, and H-lyocell) and similar mechanical properties were used to reinforce polylactic acid (PLA) by melt compounding and injection molding. The influence of lyocell cross-section shape on the interfacial shearing force, interface morphology, and mechanical properties of lyocell/PLA composites was investigated. Single fiber pull-out tests showed that the interfacial shearing force between lyocell fibers and PLA matrix was in the order of H-lyocell > Y-lyocell > O-lyocell, which was correlated with the fiber non-roundness factor. The higher the non-roundness factor of lyocell fibers, the better were the mechanical properties of lyocell/PLA composites. The tensile strength, impact strength, and initial dynamic storage modulus of different lyocell/PLA composites were in the order of H-lyocell/PLA > Y-lyocell/PLA > O-lyocell/PLA, which was attributed to higher interfacial contact area and stronger interfacial adhesion of profiled lyocell/PLA composites. Therefore, profiled lyocell fibers may be more promising for use in bio-composite reinforcement than conventional circular lyocell fibers.


Corresponding author: Huihui Zhang, State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China, E-mail:

Funding source: National Key Research and Development Program of China

Award Identifier / Grant number: 2017YFB0309501

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was financial supported by the National Key Research and Development Program of China (2017YFB0309501).

  3. Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.

References

1. Auras, R., Harte, B., Selke, S. An overview of polylactides as packaging materials. Macromol. Biosci. 2004, 4, 835–864; https://doi.org/10.1002/mabi.200400043.Search in Google Scholar

2. Lim, L. T., Auras, R., Rubino, M. Processing technologies for poly(lactic acid). Prog. Polym. Sci. 2008, 33, 820–852; https://doi.org/10.1016/j.progpolymsci.2008.05.004.Search in Google Scholar

3. Drumright, R. E., Gruber, P. R., Henton, D. E. Polylactic acid technology. Adv. Mater. 2000, 12, 1841–1846; https://doi.org/10.1002/1521-4095(200012)12:23<1841::aid-adma1841>3.0.co;2-e.10.1002/1521-4095(200012)12:23<1841::AID-ADMA1841>3.0.CO;2-ESearch in Google Scholar

4. Murariu, M., Dubois, P. PLA composites: from production to properties. Adv. Drug Deliv. Rev. 2016, 107, 17–46; https://doi.org/10.1016/j.addr.2016.04.003.Search in Google Scholar

5. Hamad, K., Kaseem, M., Yang, H. W., Deri, F., Ko, Y. G. Properties and medical applications of polylactic acid: a review. Express Polym. Lett. 2015, 9, 435–455; https://doi.org/10.3144/expresspolymlett.2015.42.Search in Google Scholar

6. Ma, H., Joo, C. W. Structure and mechanical properties of jute-polylactic acid biodegradable composites. J. Compos. Mater. 2011, 45, 1451–1460; https://doi.org/10.1177/0021998310382316.Search in Google Scholar

7. Rajesh, G., Prasad, A. V. R. Tensile properties of successive alkali treated short jute fiber reinforced PLA composites. Procedia Mater. Sci. 2014, 5, 2188–2196; https://doi.org/10.1016/j.mspro.2014.07.425.Search in Google Scholar

8. Arao, Y., Fujiura, T., Itani, S., Tanaka, T. Strength improvement in injection-molded jute-fiber-reinforced polylactide green-composites. Compos. Part B. 2015, 68, 200–206; https://doi.org/10.1016/j.compositesb.2014.08.032.Search in Google Scholar

9. Hu, R., Lim, J. K. Fabrication and mechanical properties of completely biodegradable hemp fiber reinforced polylactic acid composites. J. Compos. Mater. 2007, 41, 1655–1669; https://doi.org/10.1177/0021998306069878.Search in Google Scholar

10. Sawpan, M. A., Pickering, K. L., Fernyhough, A. Improvement of mechanical performance of industrial hemp fibre reinforced polylactide biocomposites. Compos. Part A. 2011, 42, 310–319; https://doi.org/10.1016/j.compositesa.2010.12.004.Search in Google Scholar

11. Orue, A., Jauregi, A., Peña-Rodriguez, C., Labidi, J., Eceiza, A., Arbelaiz, A. The effect of surface modifications on sisal fiber properties and sisal/poly (lactic acid) interface adhesion. Compos. Part B. 2015, 73, 132–138; https://doi.org/10.1016/j.compositesb.2014.12.022.Search in Google Scholar

12. Gunti, R., Prasad, A. V. R., Gupt, A. V. S. K. S. Mechanical and degradation properties of natural fiber-reinforced PLA composites: jute, sisal, and elephant grass. Polym. Compos. 2018, 39, 1125–1136; https://doi.org/10.1002/pc.24041.Search in Google Scholar

13. Aydın, M., Tozlu, H., Kemaloglu, S., Aytac, A., Ozkoc, G. Effects of alkali treatment on the properties of short flax fiber–poly(lactic acid) eco-composites. J. Polym. Environ. 2011, 19, 11–17; https://doi.org/10.1007/s10924-010-0233-9.Search in Google Scholar

14. Nassiopoulos, E., Njuguna, J. Thermo-mechanical performance of poly(lactic acid)/flax fibre-reinforced biocomposites. Mater. Des. 2015, 66, 473–485; https://doi.org/10.1016/j.matdes.2014.07.051.Search in Google Scholar

15. Sun, Z., Zhang, L., Liang, D., Xiao, W., Lin, J. Mechanical and thermal properties of PLA biocomposites reinforced by coir fibers. Int. J. Polym. Sci. 2017, 2017, 1–8; https://doi.org/10.1155/2017/2178329.Search in Google Scholar

16. Venkateshwaran, N., Perumal, A. E., Arunsundaranayagam, D. Fiber surface treatment and its effect on mechanical and visco-elastic behaviour of banana/epoxy composite. Mater. Des. 2013, 47, 151–159; https://doi.org/10.1016/j.matdes.2012.12.001.Search in Google Scholar

17. Jiang, G., Huang, W., Li, L., Wang, X., Pang, F., Zhang, Y., Wang, H. Structure and properties of regenerated cellulose fibers from different technology processes. Carbohydr. Polym. 2012, 87, 2012–2018; https://doi.org/10.1016/j.carbpol.2011.10.022.Search in Google Scholar

18. Sharma, A., Nagarkar, S., Thakre, S., Kumaraswamy, G. Structure–property relations in regenerated cellulose fibers: comparison of fibers manufactured using viscose and lyocell processes. Cellulose. 2019, 26, 3655–3669; https://doi.org/10.1007/s10570-019-02352-w.Search in Google Scholar

19. Graupner, N., Herrmann, A. S., Müssig, J. Natural and man-made cellulose fibre-reinforced poly(lactic acid) (PLA) composites: an overview about mechanical characteristics and application areas. Compos. Part A. 2009, 40, 810–821; https://doi.org/10.1016/j.compositesa.2009.04.003.Search in Google Scholar

20. Baghaei, B., Skrifvars, M. Characterisation of polylactic acid biocomposites made from prepregs composed of woven polylactic acid/hemp–Lyocell hybrid yarn fabrics. Compos. Part A. 2016, 81, 139–144; https://doi.org/10.1016/j.compositesa.2015.10.042.Search in Google Scholar

21. Baghaei, B., Skrifvars, M., Rissanen, M., Ramamoorthy, S. K. Mechanical and thermal characterization of compression moulded polylactic acid natural fiber composites reinforced with hemp and lyocell fibers. J. Appl. Polym. Sci. 2014, 131, 40534; https://doi.org/10.1002/app.40534.Search in Google Scholar

22. Yu, M., Zhang, H., Liu, Z., Ge, Z., Kong, F., Shao, H., Hu, X. Effects of fiber dimension and its distribution on the properties of Lyocell and ramie fibers reinforced polylactide composites. Fibers Polym. 2019, 20, 1726–1732; https://doi.org/10.1007/s12221-019-1171-3.Search in Google Scholar

23. Graupner, N., Albrecht, K., Hegemann, D., Müssig, J. Plasma modification of man-made cellulose fibers (Lyocell) for improved fiber/matrix adhesion in poly(lactic acid) composites. J. Appl. Polym. Sci. 2013, 128, 4378–4386; https://doi.org/10.1002/app.38663.Search in Google Scholar

24. Xu, Z., Li, J., Wu, X., Huang, Y., Chen, L., Zhang, G. Effect of kidney-type and circular cross sections on carbon fiber surface and composite interface. Compos. Part A. 2008, 39, 301–307; https://doi.org/10.1016/j.compositesa.2007.10.015.Search in Google Scholar

25. Liu, X., Wang, R., Wu, Z., Liu, W. The effect of triangle-shape carbon fiber on the flexural properties of the carbon fiber reinforced plastics. Mater. Lett. 2012, 73, 21–23; https://doi.org/10.1016/j.matlet.2012.01.003.Search in Google Scholar

26. Zhang, H., Shen, Y., Edgar, K. J., Yang, G., Shao, H. Influence of cross-section shape on structure and properties of Lyocell fibers. Cellulose. 2021, 28, 1191–1201; https://doi.org/10.1007/s10570-020-03605-9.Search in Google Scholar

27. Bueno, M. A., Aneja, A. P., Renner, M. Influence of the shape of fiber cross section on fabric surface characteristics. J. Mater. Sci. 2004, 39, 557–564; https://doi.org/10.1023/b:jmsc.0000011511.66614.48.10.1023/B:JMSC.0000011511.66614.48Search in Google Scholar

28. Graupner, N., Rößler, J., Ziegmann, G., Müssig, J. Fibre/matrix adhesion of cellulose fibres in PLA, PP and MAPP: a critical review of pull-out test, microbond test and single fibre fragmentation test results. Compos. Part A. 2014, 63, 133–148.10.1016/j.compositesa.2014.04.011Search in Google Scholar


Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/polyeng-2022-0070).


Received: 2022-03-25
Accepted: 2022-06-07
Published Online: 2022-07-20
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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