Startseite Understanding thermal and rheological behaviors of bimodal polymethyl methacrylate (BPMMA) fabricated via solution blending
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Understanding thermal and rheological behaviors of bimodal polymethyl methacrylate (BPMMA) fabricated via solution blending

  • Yangnan Yu , Bin Yang EMAIL logo , Yang Pan , Ning Jia , Shun Wang , Yingdong Yang , Zhengzhi Zheng , Lifen Su , Jibin Miao , Jiasheng Qian EMAIL logo , Ru Xia und You Shi
Veröffentlicht/Copyright: 1. Juli 2021
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Abstract

In this work, a series of bimodal polymethyl methacrylate (BPMMA) was fabricated via solution-blending two neat PMMA resins. Rheology, DMTA, thermal infrared imager measurements were used in an attempt to probe the internal structure of the as-prepared BPMMA. It was demonstrated that the thermorheological behavior of the BPMMA was heavily dependent on shear rate, temperature as well as blending ratio. In addition, a typical “V-shaped” response, namely, a dip in storage modulus (G′) followed by an upturn in the plot of G′ versus measuring temperature for D4 (with lower weight-average molecular weight) was observed, characteristic of occurrence of thermorheological complexity. Our experimental results of physical–mechanical testings suggested that the BPMMA had better comprehensive properties than those of their neat PMMA counterparts.


Corresponding authors: Bin Yang and Jiasheng Qian, College of Chemistry & Chemical Engineering, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Institute of High Performance Rubber Materials & Products, Anhui University, Hefei, 230601, Anhui, China, E-mail: (B. Yang), (J. S. Qian).

Funding source: National Key R & D Program of China 10.13039/501100012166

Award Identifier / Grant number: 2017YFB0406204

Funding source: National Natural Science Foundation of China 10.13039/501100001809

Award Identifier / Grant number: 51973002

Funding source: University Collaborative Innovation Project of Anhui Province

Award Identifier / Grant number: GXXT-2019-001

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors acknowledge the financial support from the National Key R & D Program of China (2017YFB0406204), the National Natural Science Foundation of China (51973002), and the University Collaborative Innovation Project of Anhui Province (GXXT-2019-001) as well as “211 Project” of Anhui University. Dr. B. Yang is also indebted to Anqing Taihu Jinzhang Sci & Tech Co., China for the financial support received.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-03-26
Accepted: 2021-05-29
Published Online: 2021-07-01
Published in Print: 2021-09-27

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2021-0093/pdf?lang=de
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