Startseite Naturwissenschaften Crystal structure of bis(μ3-chlorido)-bis(μ2-chlorido)-tetrakis(μ2-2,6-bis (diphenylmethyl)-4-t-butylphenolato)tetralithium(I)dicobalt(II) toluene solvate, C75.5H70Cl2CoLi2O2
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Crystal structure of bis(μ3-chlorido)-bis(μ2-chlorido)-tetrakis(μ2-2,6-bis (diphenylmethyl)-4-t-butylphenolato)tetralithium(I)dicobalt(II) toluene solvate, C75.5H70Cl2CoLi2O2

  • Donglei Bu , Xiaodan Chen , Miao Meng , Feifeng Zhu und Hao Lei EMAIL logo
Veröffentlicht/Copyright: 7. Februar 2018
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 233 Heft 2

Abstract

C75.5H70Cl2CoLi2O2, triclinic, P1̅ (no. 2), a = 13.1085(7) Å, b = 13.4704(7) Å, c = 18.8367(10) Å, α = 88.604(5)°, β = 88.255(4)°, γ = 68.282(5)°, V = 3088.3(3) Å3, Z = 1, Rgt(F) = 0.0666, wRref(F2) = 0.1743, T = 150 K.

CCDC no.: 1817728

The title crystal structure is shown in the figure. Hydrogen atoms are omitted for clarity. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal:Blue block
Size:0.20 × 0.10 × 0.10 mm
Wavelength:Cu Kα radiation (1.54184 Å)
μ:3.32 mm−1
Diffractometer, scan mode:Xcalibur, Sapphire3, ω-scans
θmax, completeness:62.6°, >97%
N(hkl)measured, N(hkl)unique, Rint:16983, 9602, 0.067
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 5988
N(param)refined:770
Programs:CrysAlisPRO [1], SHELX [2]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

AtomxyzUiso*/Ueq
Cl10.31650(10)0.49555(10)0.11459(6)0.0463(3)
Cl20.59356(10)0.43601(10)0.07100(6)0.0434(3)
Co10.46555(6)0.52126(6)0.15690(4)0.0335(2)
Li10.4944(7)0.6446(7)0.2610(4)0.0418(19)
Li20.4326(6)0.4133(6)0.0169(3)0.0290(16)
O10.4615(2)0.6682(2)0.16278(14)0.0322(7)
O20.5027(2)0.5007(2)0.25728(15)0.0332(7)
C10.4893(4)0.7098(3)0.1033(2)0.0286(9)
C20.6008(3)0.6946(4)0.0891(2)0.0297(9)
C30.6296(4)0.7326(4)0.0254(2)0.0341(10)
C40.5524(4)0.7861(4)−0.0256(2)0.0331(10)
C50.4430(4)0.8016(4)−0.0100(2)0.0327(10)
C60.4088(3)0.7651(3)0.0531(2)0.0296(9)
C70.2907(4)0.7762(4)0.0690(2)0.0351(10)
C80.2100(4)0.8254(4)0.0085(2)0.0383(11)
C90.1788(5)0.9322(5)−0.0109(3)0.0505(13)
C100.1007(5)0.9762(6)−0.0624(3)0.0664(18)
C110.0525(5)0.9138(7)−0.0939(3)0.0702(19)
C120.0818(5)0.8092(7)−0.0755(3)0.0675(18)
C130.1612(4)0.7634(5)−0.0238(3)0.0472(12)
C140.2395(4)0.8348(4)0.1356(2)0.0380(11)
C150.2609(5)0.9208(4)0.1598(3)0.0491(13)
C160.2004(6)0.9818(5)0.2164(3)0.0661(17)
C170.1171(5)0.9556(6)0.2479(3)0.0672(18)
C180.0970(5)0.8678(6)0.2260(3)0.0618(16)
C190.1563(4)0.8100(5)0.1711(3)0.0517(14)
C200.5838(4)0.8316(4)−0.0953(2)0.0393(11)
C210.7070(5)0.8012(5)−0.1043(3)0.0576(15)
C220.5439(5)0.7881(5)−0.1592(3)0.0542(14)
C230.5269(5)0.9523(4)−0.0965(3)0.0557(15)
C240.6824(4)0.6406(4)0.1462(2)0.0334(10)
C250.8023(4)0.6104(4)0.1242(2)0.0397(12)
C260.8673(5)0.5055(6)0.1120(3)0.0599(15)
C270.9785(6)0.4753(7)0.0944(4)0.089(2)
C281.0229(6)0.5526(9)0.0868(4)0.092(3)
C290.9614(6)0.6568(8)0.0974(3)0.077(2)
C300.8504(5)0.6866(6)0.1167(3)0.0573(15)
C310.6575(3)0.7040(4)0.2140(2)0.0325(10)
C320.6192(4)0.8157(4)0.2126(3)0.0438(12)
C330.6022(5)0.8735(5)0.2737(3)0.0503(13)
C340.6196(4)0.8216(5)0.3392(3)0.0486(13)
C350.6546(4)0.7112(5)0.3416(2)0.0451(13)
C360.6745(4)0.6531(4)0.2804(2)0.0355(11)
C370.4667(4)0.4333(4)0.2956(2)0.0288(10)
C380.5372(4)0.3264(4)0.3075(2)0.0310(10)
C390.4922(4)0.2582(4)0.3421(2)0.0333(10)
C400.3842(4)0.2914(4)0.3665(2)0.0319(10)
C410.3201(4)0.3998(4)0.3590(2)0.0341(10)
C420.3595(4)0.4703(4)0.3240(2)0.0312(10)
C430.6552(4)0.2882(4)0.2794(2)0.0354(10)
C440.7242(4)0.3441(4)0.3133(3)0.0413(12)
C460.8231(5)0.3371(5)0.2789(4)0.0607(16)
C470.8924(5)0.3789(6)0.3098(5)0.076(2)
C480.8662(6)0.4268(6)0.3745(5)0.077(2)
C490.7691(6)0.4360(5)0.4088(3)0.0664(18)
C500.6977(5)0.3946(4)0.3773(3)0.0500(14)
C510.7159(4)0.1678(4)0.2864(3)0.0409(12)
C520.7424(4)0.1040(5)0.2276(3)0.0521(14)
C530.7946(5)−0.0059(5)0.2343(4)0.0691(18)
C540.8208(5)−0.0515(5)0.3004(5)0.072(2)
C550.7983(5)0.0099(5)0.3595(4)0.0640(17)
C560.7474(5)0.1189(5)0.3528(3)0.0535(14)
C570.3323(4)0.2145(4)0.3990(2)0.0394(11)
C580.4170(6)0.1026(5)0.4113(5)0.084(2)
C590.2504(8)0.2060(8)0.3462(4)0.101(3)
C600.2740(7)0.2557(5)0.4678(3)0.079(2)
C610.2911(4)0.5896(4)0.3164(2)0.0318(10)
C620.3385(4)0.6575(4)0.3585(2)0.0349(10)
C630.3271(4)0.7586(4)0.3332(3)0.0401(11)
C640.3623(5)0.8252(4)0.3730(3)0.0539(14)
C650.4082(5)0.7909(5)0.4384(3)0.0553(15)
C660.4232(5)0.6908(5)0.4626(3)0.0520(14)
C670.3887(4)0.6237(4)0.4240(2)0.0430(12)
C680.1696(4)0.6163(4)0.3338(2)0.0356(11)
C690.1042(4)0.5962(4)0.2828(3)0.0468(12)
C70−0.0055(5)0.6168(5)0.2971(3)0.0565(15)
C71−0.0519(5)0.6572(5)0.3622(4)0.0630(17)
C720.0117(5)0.6760(5)0.4117(4)0.0646(17)
C730.1214(4)0.6564(5)0.3980(3)0.0517(13)
C74a0.9920(11)0.0617(12)0.4704(7)0.072(5)
C75a0.9105(8)0.0663(12)0.5207(8)0.060(6)
C76a0.9192(18)−0.0236(18)0.5616(6)0.095(7)
C77a1.009(2)−0.1180(13)0.5524(9)0.131(16)
C78a1.0909(16)−0.1226(12)0.5021(11)0.117(10)
C79a1.0822(9)−0.0327(17)0.4612(8)0.099(11)
C80a0.9855(18)0.149(2)0.4204(13)0.096(8)
H30.70300.72220.01650.041*
H50.39030.8379−0.04300.039*
H70.29250.70320.07600.042*
H90.21040.97470.01070.061*
H100.08091.0477−0.07560.080*
H11−0.00050.9437−0.12800.084*
H120.04920.7675−0.09730.081*
H130.18100.6917−0.01120.057*
H150.31660.93850.13800.059*
H160.21611.03920.23260.079*
H170.07410.99760.28430.081*
H180.04310.84860.24890.074*
H190.14130.75150.15620.062*
H21A0.73260.8354−0.06850.086*
H21B0.72360.8239−0.15050.086*
H21C0.74290.7251−0.09960.086*
H22A0.58680.7133−0.16410.081*
H22B0.55210.8258−0.20160.081*
H22C0.46800.7981−0.15180.081*
H23A0.44900.9709−0.09090.084*
H23B0.54280.9804−0.14100.084*
H23C0.55290.9819−0.05840.084*
H240.67270.57330.15790.040*
H260.83640.45360.11560.072*
H271.02200.40370.08790.106*
H281.09680.53290.07410.111*
H290.99270.70820.09190.092*
H300.80820.75810.12480.069*
H320.60490.85170.16910.053*
H330.57890.94760.27120.060*
H340.60790.86030.38090.058*
H350.66490.67580.38530.054*
H360.69960.57900.28320.043*
H390.53730.18700.34910.040*
H410.24890.42530.37800.041*
H430.65240.30590.22850.042*
H460.84200.30420.23500.073*
H470.95740.37450.28640.091*
H480.91430.45310.39540.092*
H490.75070.46940.45260.080*
H500.63160.40150.40020.060*
H520.72510.13490.18270.062*
H530.8117−0.04840.19420.083*
H540.8544−0.12530.30500.087*
H550.8172−0.02160.40410.077*
H560.73360.16090.39310.064*
H58A0.45100.07340.36680.126*
H58B0.38140.05790.43220.126*
H58C0.47190.10610.44270.126*
H59A0.19610.27570.33720.152*
H59B0.21510.15990.36550.152*
H59C0.28820.17700.30260.152*
H60A0.32400.26820.49940.119*
H60B0.24750.20400.48880.119*
H60C0.21330.32140.45940.119*
H610.29620.60840.26620.038*
H630.29570.78210.28930.048*
H640.35500.89270.35560.065*
H650.42880.83640.46600.066*
H660.45730.66710.50570.062*
H670.39870.55570.44160.052*
H690.13500.56880.23900.056*
H70−0.04830.60330.26300.068*
H71−0.12590.67140.37190.076*
H72−0.01930.70260.45560.077*
H730.16310.67050.43260.062*
H75a0.85020.12950.52680.072*
H76a0.8647−0.02050.59520.114*
H77a1.0152−0.17820.57980.158*
H78a1.1512−0.18580.49600.141*
H79a1.1367−0.03580.42760.119*
H80Aa0.91180.20060.42060.144*
H80Ba1.00550.12060.37350.144*
H80Ca1.03490.18210.43430.144*

  1. aOccupancy: 0.5.

Source of material

Lithium 2,6-dibenzhydryl-4-(tert-butyl)phenolate (ArOLi) was prepared by following literature procedures [3]. The synthesis and handling of the title compound was performed using standard Schlenk technique under a N2 atmosphere. A solution of ArOLi (1.09 g, 1.93 mmol) in 50 mL of diethyl ether was transferred into a Schlenk flask charged with anhydrous CoCl2 (0.12 g, 0.91 mmol) at 0 oC. The mixture was allowed to warm up to room temperature and stirred for 12 hours. All volatiles were removed under reduced pressure and the residue was extracted with 30 mL of toluene. The filtrate was layered with n-hexane and blue crystals of the title compound were obtained after several days.

Experimental details

Hydrogen atoms were placed in calculated positions (C—H = 0.93 Å for C(sp2) atoms and C—H = 0.96 and 0.98 Å for C(sp3) atoms), assigned fixed Uiso values (Uiso = 1.2Ueq(Csp2) and 1.5Ueq(sp3)) and allowed to ride. The plane of solvent toluene is disordered over a center of inversion and refined by suppressing the symmetry restriction with a “part −1” instruction of the SHELX program [2]. The aromatic ring of toluene was refined as a hexagon of 1.39 Å sides (AFIX 66 option of the SHELX program [2]).

Discussion

Structurally characterized open-shell, low-coordinate (coordination number less than 4) transition metal complexes are very rare [4] and have drawn increasing attention in recent decades, partly due to their potential application as molecular magnets [5], [6], [7]. The synthesis and isolation of such compounds are usually facilitated by the employment of sterically hindered organic ligands. Herein we report the preparation and crystallographic characterization of a dicobalt complexes supported by bulky phenolate ligands.

The asymmetric unit contains half of the dimeric cobalt compound, which is composed of one cobalt atom, two lithium atoms, two chlorine atoms and two [ArO]− ligands and one half of a toluene molecule. The cobalt center is four-coordinate in a pseudo tetrahedral geometry, bonded to two oxygen and two chlorine atoms. One lithium atom (Li1) is coordinated to two oxygen atoms, and two flanking aryl rings from the ligand framework in η2-fashion. The other lithium atom (Li2) is bound to two chlorine atoms, and bridges the asymmetric unit to a symmetry related one through short Li-Cl contacts and η6-metal-π interaction with aryl rings. Thus, the connectivity in the core structure resembles that of a previously reported monomeric cobalt complex supported by bulky diorganoboroxide ligands [8]. The Co-O distances (1.966(3) and 1.954(3) Å) are comparable to that in the cobalt diorganoboroxide complex (1.951(2) Å) [8], but longer than the corresponding values for two- or three-coordinate cobalt aryloxide species [9], [10], [11]. The synthesis and isolation of the title compound suggests that the presence of too many aromatic rings in the ligand might be detrimental to the successful isolation of low-coordinate homoleptic complexes (e.g. Co(OAr)2), due to possible inclusion of Li and Cl atoms in the resulting structure.

Acknowledgements

We gratefully acknowledge support from Pearl River S&T Nova Program of Guangzhou (No. 201610010118), the National Natural Science Foundation of China (No. 21301070), the Fundamental Research Funds for the Central Universities (Nos. 21615401 and 21617321), Natural Science Foundation of Guangdong Province (No. 2016A030313093), China Postdoctoral Science Foundation (No. 2016M592598) and Jinan University.

References

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Received: 2017-10-6
Accepted: 2018-1-17
Published Online: 2018-2-7
Published in Print: 2018-3-28

©2018 Donglei Bu et al., published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Crystal structure and optical properties of diaqua-tris(nitrato-κ2O,O′)-bis(4,4,5,5-tetramethyl-2-(p-pyridyl)imidazoline-1-oxyl 3-oxide-κN)praseodymium(III), C24H36N9O15Pr
  3. Crystal structure of dimethanol-bis(μ2-methanol-κ2O:O)-bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}dimanganese(II), C38H38Mn2N2O14
  4. Crystal structure of catena-poly[diaqua-bis(μ2-2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κ3O,O′:O′)calcium(II)], C56H48N4Ca2Cl8O12
  5. Crystal structure of catena-poly[triaqua-(isophthalato-κO)-(μ2-1,6-di(1H-imidazol-1-yl)hexane-κ2N:N′)]nickel(II), C20H28N4NiO7
  6. Crystal structure of cyclo[hexaqua-bis[1-[(2-ethyl-1H-imidazol-1-yl) methyl]-1H-benzotriazole-κ2N:N′]-bis(sulfato-κ1O)dicadmium(II)] monohydrate, C24H42Cd2N10O16S2
  7. Crystal Structure of bis(2-fluorbenzoato-κO)-bis(1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate, C38H28F2MnN4O6
  8. Crystal structure of tetrapropylammonium 5-hydroxyisophthalate tetrahydrate, C20H41NO9
  9. Crystal structural of 2-amino-4-(3-bromophenyl)-3-cyano-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C18H17BrN2O2
  10. Crystal structural of 2-amino-4-(4-methoxyphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C17H16N2O3
  11. Crystal structure of catena-poly[aqua(μ2-1,3-bis(1H-benzo[d]imidazol-1-yl)propane-κ2N:N′)-(μ2-5-(tert-butyl)isophthalate-κ3O,O′:O′′)nickel(II)], C29H30N4NiO5
  12. Crystal structure of catena-poly[(μ2-dicyanamido-κ2N:N′)-(μ2-2-(pyridin-2-yl)ethan-1-olato-κ3N,O:O′)copper(II)], C9H8CuN4O
  13. Crystal structure of bis(5,5′-((butane-1,4-diylbis(azanylylidene))bis(methanylylidene))bis(3-(ethoxycarbonyl)-2,4-dimethylpyrrol-1-ido-k4N,N′,N′′,N′′′)copper(II), C24H32CuN4O4
  14. The crystal structure of the formamide solvate of (17b)-estra-1,3,5(10)-triene-3,17diol, C19H27NO3
  15. Crystal structure of catena-poly[diaqua-bis(μ2-1H-benzo[d]imidazole-5-carboxylato-κ2N:O)nickel(II)] dihydrate, C16H18N4NiO8
  16. Crystal structure of dibromido[(1,2-bis(diisopropylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]nickel(II), C14H38B10NiBr2P2
  17. The crystal structure of catena-poly[aquachlorido(3,3′-([4,4′-bipyridine]-1,1′-diium-1,1′-diylbis(methylene))dibenzoato-κ2O:O′)copper(II)] chloride dihydrate, C26H26Cl2CuN2O7
  18. The crystal structure of N′-(2-nitrobenzylidene)-2-phenylacetohydrazide, C15H13N3O3
  19. Crystal structure of dichlorido bis[1-[(2-methyl-1H-benzoimidazol-1-yl)methyl]-1H-benzotriazole-κ1N]cadmium(II), C30H26CdCl2N10
  20. Crystal structure of aqua-bis(3-(2-pyridyl)-5-(4-pyridyl)-1H-1,2,4-triazole-κ2N,N′)copper(II) sulfate tetrahydrate, C24H28CuN10O9S
  21. Crystal structure of dibromido-carbonyl-(η6-p-cymene)osmium(II), C11H14Br2OOs
  22. Crystal structure of catena-poly[chlorido-(μ2-chlorido)-bis(imidazole-κN)copper(II)] C6H8Cl2CuN4
  23. Crystal structure of [(1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]dibromidonickel(II)), C26H54B10NiBr2P2
  24. Crystal structure of dichlorido[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]zinc(II), C34H28FeCl2P2Zn
  25. Crystal structure of tris(μ2-2-(pyridin-2-yl)ethan-1-olato-κ3N,O:O)-trithiocyanato-κN-dicobalt(III), C24H24Co2N6O3S3
  26. The crystal structure of diaqua-2,2′-((cyclohexane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenolato-κ4N,N′,O,O′)manganese(III) perchlorate, C20H24MnClN2O4
  27. Crystal structure of bis(μ3-chlorido)-bis(μ2-chlorido)-tetrakis(μ2-2,6-bis (diphenylmethyl)-4-t-butylphenolato)tetralithium(I)dicobalt(II) toluene solvate, C75.5H70Cl2CoLi2O2
  28. The crystal structure of hexaaqua-bis(μ2-3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κ2O:O′)-tetrakis(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κO)dierbium(III) octahydrate, C60H76N18O32Er2
  29. Crystal structure of dimethylammonium bis(naphthalene-2,3-diolato)borate, C22H20BNO4
  30. Crystal structure of 2-amino-4-(4-nitro-phenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H17N3O4
  31. The crystal structure of (E)-4-chloro-2-(((5-methylpyridin-2-yl)imino)methyl)phenol, C13H11ClN2O
  32. Crystal structure of bis(N,N,N-trimethylbutanaminium) poly[heptaselenidotristannate(IV)], C14H36N2Se7Sn3
  33. The crystal structure of N-((3,5-di-tert-butyl-4-hydroxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide, C28H35N3S
  34. Crystal structure of 2-(4-chlorophenyl)-2,3-dihydro-1H-perimidine, C17H13Cl1N2
  35. The Crystal structure of 2-iodo-1-(p-tolyl)propan-1-one, C10H11IO
  36. Crystal structure of ethyl 1-(4-bromobenzyl)-3-phenyl-1H-pyrazole-5-carboxylate, C19H17BrN2O2
  37. Crystal structure of ethyl 1-(4-fluorobenzyl)-3-phenyl-1H-pyrazole-5-carboxylate, C19H17FN2O2
  38. Crystal structure of catena-poly[diaqua-(μ2-2,5-dihydroxyterephthalato-κ4O,O′:O′′,O′′′)cadmium(II)], C8H8O8Cd
  39. Crystal structure of tetraaqua-bis[6-(1H-imidazol-1-yl-κN)nicotinato]zinc(II), C18H20N6O8Zn
  40. Crystal structure of dichlorido-bis(N-phenyl-2-(quinolin-8-yloxy)acetamide-κ2N,O) – acetone (2/1), C35.5H31N4O4.5Cl2Cu
  41. Crystal Structure of ethyl (E)-3,4-dimethyl-5-((2-(4-methylbenzoyl)hydrazono)methyl)-1H-pyrrole-2-carboxylate — water — ethanol (1/1/1), C20H29N3O5
  42. Crystal structure of 5-((4-(1H-benzo[d]imidazol-2-yl)-2-methoxyphenoxy)methyl)-2-chlorothiazole - trichloromethane - methanol (1/1/1), C20H19Cl4N3O3S
  43. The crystal structure of a matrine derivative: 41S,7aS,12S,13aR,13bR)-12-(4-methylpiperazin-1-yl)dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one, C20H34N4O
  44. Crystal structure of cesium beryllophosphate, Be3Cs2P4O14
  45. Crystal Structure of 3-((3-hydroxybenzyl)ammonio)-3-phenylpropanoate, C16H17NO3
  46. Crystal structure of 9,10-dimethoxy-5,6-dihydro-[1,3]dioxolo[4,5-g]isoquinolino[3,2-a]isoquinolin-7-ium chloride — 4-hydroxy-3-methoxybenzoic acid — water (2/1/5), C48H54N2Cl2O17
  47. The crystal structure of (1R, 2R)-N1,N2-diferrocenyl-1,2-cyclohexanedicarboxamide, C28H30Fe2N2O2
  48. Crystal structure of N-(2-methylphenyl)ethoxycarbothioamide, C10H13NOS
  49. Crystal Structure of ethyl (E)-2,4-dimethyl-5-((2-tosylhydrazono)methyl)-1H-pyrrole-3-carboxylate monohydrate, C17H23N3O5
  50. Crystal structure of Diiodo-(N′-((quinolin-8-yl)methylene)isonicotinohydrazide κ3N,N′,O)cadium(II) – dimethylformamide (1/1), C19H19N5O2CdI2
  51. Crystal structure of dinitrato-(N′-((quinolin-8-yl)methylene)isonicotinohydrazide κ3-N,N′,O)copper(II), C16H12N6O7Cu
  52. Crystal structure of benzoato-κO-bis(1,3,5-triaza-7-phosphaadamantane-κP)silver(I) monohydrate C19H31AgN6O3P2
  53. Crystal structure of (E)-2-(anthracen-9-ylmethylene)hydrazine-1-carbothioamide, C16H13N3S
  54. The crystal structure of 8-chloro-7-ethyl-1,3-dimethyl-1H-purine-2,6(3H,7H)-dione, C9H11ClN4O2
  55. Crystal structure of {5,5′-((propane-1,3-diylbis(azanylylidene))bis(methanylylidene))bis(3-(ethoxycarbonyl)-2,4-dimethylpyrrol-1-ido)-κ4N,N′,N′′,N′′′}zinc(II), C23H30N4O4Cu
  56. Crystal structure of bis(4-dimethylamino-pyridin-1-ium)tetrafluorosuccinate, C18H22F4N4O4
  57. Crystal structure of dimethyl 3,9-dibenzyl-6,12-dicyclohexyl-3,9-diazahexacyclo [6.4.0.02,7.04,11.05,10]-dodecane-1,11-dicarboxylate, C40H50N2O4
  58. Crystal structure of diethyl 3,9-diphenyl-6,12-bis(3-methoxyphenyl)-3,9-diazahexacyclo[6.4.0.02,7.04,11.05,10]dodecane-1,11-dicarboxylate, C42H42N2O6
  59. Crystal structure of bis(acetato-κO)-bis(1-(pyridin-2-yl)ethan-1-one oxime-κ2N,N′)nickel(II), C18H22N4NiO6
  60. Crystal structure of (N-(3-ethoxy-2-oxidobenzylidene)-4-fluorobenzohydrazonato-κ3N,O,O′)-diphenyltin(IV), C28H23FN2O3Sn
  61. Crystal structure of {N-(3-ethoxy-2-oxidobenzylidene)-4-fluorobenzohydrazonato-κ3O,N,O′}dimethyltin(IV), C18H19FN2O3Sn
https://doi.org/10.1515/ncrs-2017-0238
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Artikel in diesem Heft

  1. Cover and Frontmatter
  2. Crystal structure and optical properties of diaqua-tris(nitrato-κ2O,O′)-bis(4,4,5,5-tetramethyl-2-(p-pyridyl)imidazoline-1-oxyl 3-oxide-κN)praseodymium(III), C24H36N9O15Pr
  3. Crystal structure of dimethanol-bis(μ2-methanol-κ2O:O)-bis{3-((4-methoxy-2-oxidobenzylidene)amino)-2-oxo-2H-chromen-4-olato-κ3O,N,O′}dimanganese(II), C38H38Mn2N2O14
  4. Crystal structure of catena-poly[diaqua-bis(μ2-2-(2-((2,6-dichlorophenyl)amino)phenyl)acetato-κ3O,O′:O′)calcium(II)], C56H48N4Ca2Cl8O12
  5. Crystal structure of catena-poly[triaqua-(isophthalato-κO)-(μ2-1,6-di(1H-imidazol-1-yl)hexane-κ2N:N′)]nickel(II), C20H28N4NiO7
  6. Crystal structure of cyclo[hexaqua-bis[1-[(2-ethyl-1H-imidazol-1-yl) methyl]-1H-benzotriazole-κ2N:N′]-bis(sulfato-κ1O)dicadmium(II)] monohydrate, C24H42Cd2N10O16S2
  7. Crystal Structure of bis(2-fluorbenzoato-κO)-bis(1,10-phenanthroline-κ2N,N′)manganese(II) dihydrate, C38H28F2MnN4O6
  8. Crystal structure of tetrapropylammonium 5-hydroxyisophthalate tetrahydrate, C20H41NO9
  9. Crystal structural of 2-amino-4-(3-bromophenyl)-3-cyano-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran, C18H17BrN2O2
  10. Crystal structural of 2-amino-4-(4-methoxyphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C17H16N2O3
  11. Crystal structure of catena-poly[aqua(μ2-1,3-bis(1H-benzo[d]imidazol-1-yl)propane-κ2N:N′)-(μ2-5-(tert-butyl)isophthalate-κ3O,O′:O′′)nickel(II)], C29H30N4NiO5
  12. Crystal structure of catena-poly[(μ2-dicyanamido-κ2N:N′)-(μ2-2-(pyridin-2-yl)ethan-1-olato-κ3N,O:O′)copper(II)], C9H8CuN4O
  13. Crystal structure of bis(5,5′-((butane-1,4-diylbis(azanylylidene))bis(methanylylidene))bis(3-(ethoxycarbonyl)-2,4-dimethylpyrrol-1-ido-k4N,N′,N′′,N′′′)copper(II), C24H32CuN4O4
  14. The crystal structure of the formamide solvate of (17b)-estra-1,3,5(10)-triene-3,17diol, C19H27NO3
  15. Crystal structure of catena-poly[diaqua-bis(μ2-1H-benzo[d]imidazole-5-carboxylato-κ2N:O)nickel(II)] dihydrate, C16H18N4NiO8
  16. Crystal structure of dibromido[(1,2-bis(diisopropylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]nickel(II), C14H38B10NiBr2P2
  17. The crystal structure of catena-poly[aquachlorido(3,3′-([4,4′-bipyridine]-1,1′-diium-1,1′-diylbis(methylene))dibenzoato-κ2O:O′)copper(II)] chloride dihydrate, C26H26Cl2CuN2O7
  18. The crystal structure of N′-(2-nitrobenzylidene)-2-phenylacetohydrazide, C15H13N3O3
  19. Crystal structure of dichlorido bis[1-[(2-methyl-1H-benzoimidazol-1-yl)methyl]-1H-benzotriazole-κ1N]cadmium(II), C30H26CdCl2N10
  20. Crystal structure of aqua-bis(3-(2-pyridyl)-5-(4-pyridyl)-1H-1,2,4-triazole-κ2N,N′)copper(II) sulfate tetrahydrate, C24H28CuN10O9S
  21. Crystal structure of dibromido-carbonyl-(η6-p-cymene)osmium(II), C11H14Br2OOs
  22. Crystal structure of catena-poly[chlorido-(μ2-chlorido)-bis(imidazole-κN)copper(II)] C6H8Cl2CuN4
  23. Crystal structure of [(1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane-κ2P,P′]dibromidonickel(II)), C26H54B10NiBr2P2
  24. Crystal structure of dichlorido[1,1′-bis(diphenylphosphanyl)ferrocene-κ2P,P′]zinc(II), C34H28FeCl2P2Zn
  25. Crystal structure of tris(μ2-2-(pyridin-2-yl)ethan-1-olato-κ3N,O:O)-trithiocyanato-κN-dicobalt(III), C24H24Co2N6O3S3
  26. The crystal structure of diaqua-2,2′-((cyclohexane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenolato-κ4N,N′,O,O′)manganese(III) perchlorate, C20H24MnClN2O4
  27. Crystal structure of bis(μ3-chlorido)-bis(μ2-chlorido)-tetrakis(μ2-2,6-bis (diphenylmethyl)-4-t-butylphenolato)tetralithium(I)dicobalt(II) toluene solvate, C75.5H70Cl2CoLi2O2
  28. The crystal structure of hexaaqua-bis(μ2-3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κ2O:O′)-tetrakis(3-(3-(pyridin-4-yl)-1,2,4-oxadiazol-5-yl)propanoato-κO)dierbium(III) octahydrate, C60H76N18O32Er2
  29. Crystal structure of dimethylammonium bis(naphthalene-2,3-diolato)borate, C22H20BNO4
  30. Crystal structure of 2-amino-4-(4-nitro-phenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile, C18H17N3O4
  31. The crystal structure of (E)-4-chloro-2-(((5-methylpyridin-2-yl)imino)methyl)phenol, C13H11ClN2O
  32. Crystal structure of bis(N,N,N-trimethylbutanaminium) poly[heptaselenidotristannate(IV)], C14H36N2Se7Sn3
  33. The crystal structure of N-((3,5-di-tert-butyl-4-hydroxyphenyl)(phenyl)methyl)-4-methylbenzenesulfonamide, C28H35N3S
  34. Crystal structure of 2-(4-chlorophenyl)-2,3-dihydro-1H-perimidine, C17H13Cl1N2
  35. The Crystal structure of 2-iodo-1-(p-tolyl)propan-1-one, C10H11IO
  36. Crystal structure of ethyl 1-(4-bromobenzyl)-3-phenyl-1H-pyrazole-5-carboxylate, C19H17BrN2O2
  37. Crystal structure of ethyl 1-(4-fluorobenzyl)-3-phenyl-1H-pyrazole-5-carboxylate, C19H17FN2O2
  38. Crystal structure of catena-poly[diaqua-(μ2-2,5-dihydroxyterephthalato-κ4O,O′:O′′,O′′′)cadmium(II)], C8H8O8Cd
  39. Crystal structure of tetraaqua-bis[6-(1H-imidazol-1-yl-κN)nicotinato]zinc(II), C18H20N6O8Zn
  40. Crystal structure of dichlorido-bis(N-phenyl-2-(quinolin-8-yloxy)acetamide-κ2N,O) – acetone (2/1), C35.5H31N4O4.5Cl2Cu
  41. Crystal Structure of ethyl (E)-3,4-dimethyl-5-((2-(4-methylbenzoyl)hydrazono)methyl)-1H-pyrrole-2-carboxylate — water — ethanol (1/1/1), C20H29N3O5
  42. Crystal structure of 5-((4-(1H-benzo[d]imidazol-2-yl)-2-methoxyphenoxy)methyl)-2-chlorothiazole - trichloromethane - methanol (1/1/1), C20H19Cl4N3O3S
  43. The crystal structure of a matrine derivative: 41S,7aS,12S,13aR,13bR)-12-(4-methylpiperazin-1-yl)dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one, C20H34N4O
  44. Crystal structure of cesium beryllophosphate, Be3Cs2P4O14
  45. Crystal Structure of 3-((3-hydroxybenzyl)ammonio)-3-phenylpropanoate, C16H17NO3
  46. Crystal structure of 9,10-dimethoxy-5,6-dihydro-[1,3]dioxolo[4,5-g]isoquinolino[3,2-a]isoquinolin-7-ium chloride — 4-hydroxy-3-methoxybenzoic acid — water (2/1/5), C48H54N2Cl2O17
  47. The crystal structure of (1R, 2R)-N1,N2-diferrocenyl-1,2-cyclohexanedicarboxamide, C28H30Fe2N2O2
  48. Crystal structure of N-(2-methylphenyl)ethoxycarbothioamide, C10H13NOS
  49. Crystal Structure of ethyl (E)-2,4-dimethyl-5-((2-tosylhydrazono)methyl)-1H-pyrrole-3-carboxylate monohydrate, C17H23N3O5
  50. Crystal structure of Diiodo-(N′-((quinolin-8-yl)methylene)isonicotinohydrazide κ3N,N′,O)cadium(II) – dimethylformamide (1/1), C19H19N5O2CdI2
  51. Crystal structure of dinitrato-(N′-((quinolin-8-yl)methylene)isonicotinohydrazide κ3-N,N′,O)copper(II), C16H12N6O7Cu
  52. Crystal structure of benzoato-κO-bis(1,3,5-triaza-7-phosphaadamantane-κP)silver(I) monohydrate C19H31AgN6O3P2
  53. Crystal structure of (E)-2-(anthracen-9-ylmethylene)hydrazine-1-carbothioamide, C16H13N3S
  54. The crystal structure of 8-chloro-7-ethyl-1,3-dimethyl-1H-purine-2,6(3H,7H)-dione, C9H11ClN4O2
  55. Crystal structure of {5,5′-((propane-1,3-diylbis(azanylylidene))bis(methanylylidene))bis(3-(ethoxycarbonyl)-2,4-dimethylpyrrol-1-ido)-κ4N,N′,N′′,N′′′}zinc(II), C23H30N4O4Cu
  56. Crystal structure of bis(4-dimethylamino-pyridin-1-ium)tetrafluorosuccinate, C18H22F4N4O4
  57. Crystal structure of dimethyl 3,9-dibenzyl-6,12-dicyclohexyl-3,9-diazahexacyclo [6.4.0.02,7.04,11.05,10]-dodecane-1,11-dicarboxylate, C40H50N2O4
  58. Crystal structure of diethyl 3,9-diphenyl-6,12-bis(3-methoxyphenyl)-3,9-diazahexacyclo[6.4.0.02,7.04,11.05,10]dodecane-1,11-dicarboxylate, C42H42N2O6
  59. Crystal structure of bis(acetato-κO)-bis(1-(pyridin-2-yl)ethan-1-one oxime-κ2N,N′)nickel(II), C18H22N4NiO6
  60. Crystal structure of (N-(3-ethoxy-2-oxidobenzylidene)-4-fluorobenzohydrazonato-κ3N,O,O′)-diphenyltin(IV), C28H23FN2O3Sn
  61. Crystal structure of {N-(3-ethoxy-2-oxidobenzylidene)-4-fluorobenzohydrazonato-κ3O,N,O′}dimethyltin(IV), C18H19FN2O3Sn
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