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Growth kinetics of Fe2B layer formed on the surface of borided AISI M2 high-speed steel

  • Tuna Aydogmus

    Tuna Aydogmus, Asst. Prof. Dr. Tuna Aydogmus, born in 1987, graduated from the Ondokuz Mayıs University, Turkey in the Educational Sciences Faculty. He completed his MSc and Ph.D. at Osmangazi University. He worked at the İstanbul Gedik University, Turkey in the Machinery and Metal Technologies Department between 2013 and 2019. He has been working at Hitit University, Turkey since 2019. He is an expert in materials science, non-destructive material tests, surface development, diffusion processes, and thin film technologies.

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    , Bünyamin Çicek

    Bünyamin Çicek holds an Assoc. Prof. Dr. Metallurgical and Materials Engineering. He has many studies on biomaterials, alloys, 3D printer products, alloy designed and metallic mechanical properties. He receives serious project support in his works. His work has been cited more than 250 times.

    , Polat Topuz

    Polat Topuz, Assoc. Prof. Dr. Polat Topuz, born in 1975, graduated from Marmara University, Turkey in the Technical Education Faculty. He completed his MSc and Ph.D. at the same university. He worked at the Yildiz Technical University, Turkey in the Metallurgical and Materials Department between 1999 and 2010. He has been working at İstanbul Gedik University, Turkey, since 2010. He is an expert in materials science, destructive and nondestructive material tests, scanning electron microscopy, and diffusion processes.

    and Özlem Aydin

    Özlem Aydin, Assistant Prof. Dr. Özlem Aydin, born 1979, completed her Undergraduate studies at Sakarya University and Graduate and Doctorate studies at Yıldız Technical University. She focuses on surface treatments fields. Between 2010 and 2018 she worked as a Lecturer and since 2018, she has been working as Assistant Professor at Istanbul Gedik University Vocational School.

Published/Copyright: September 2, 2024
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Abstract

In this study, the growth kinetics of the Fe2B layer was investigated and formed on the surface of borided AISI M2 high-speed steel. Boriding treatments carried out by the pack-boriding method were carried out using Ekabor 2 boriding agent at 1,173, 1,273, and 1,373 K for 2, 4, and 6 h. After the boriding processes, the samples were prepared metallographically and their microstructures were examined with the help of backscattered electrons (BE) by scanning electron microscope (SEM). Following SEM examinations, microhardness measurements were carried out from a single sample using 100 g with the Vickers indentation method to understand whether the layer hardness was compatible with Fe2B. When the results of the experimental studies are compared with the results of the literature, it has been determined that AISI M2 high-speed steel can be borided and the boride layer formed on the surface is single-phased (Fe2B), unlike that formed on many other steel types. After determining that the layer formed on the borided AISI M2 surface is single-phase Fe2B, the growth kinetics calculations of this phase were carried out with the help of the Arrhenius equation.


Corresponding author: Tuna Aydogmus, Hitit University, Corum, Türkiye, E-mail:

Funding source: Hitit University BAP Project(2021-Çorum)

Award Identifier / Grant number: TBMYO 19001.20.001

About the authors

Tuna Aydogmus

Tuna Aydogmus, Asst. Prof. Dr. Tuna Aydogmus, born in 1987, graduated from the Ondokuz Mayıs University, Turkey in the Educational Sciences Faculty. He completed his MSc and Ph.D. at Osmangazi University. He worked at the İstanbul Gedik University, Turkey in the Machinery and Metal Technologies Department between 2013 and 2019. He has been working at Hitit University, Turkey since 2019. He is an expert in materials science, non-destructive material tests, surface development, diffusion processes, and thin film technologies.

Bünyamin Çicek

Bünyamin Çicek holds an Assoc. Prof. Dr. Metallurgical and Materials Engineering. He has many studies on biomaterials, alloys, 3D printer products, alloy designed and metallic mechanical properties. He receives serious project support in his works. His work has been cited more than 250 times.

Polat Topuz

Polat Topuz, Assoc. Prof. Dr. Polat Topuz, born in 1975, graduated from Marmara University, Turkey in the Technical Education Faculty. He completed his MSc and Ph.D. at the same university. He worked at the Yildiz Technical University, Turkey in the Metallurgical and Materials Department between 1999 and 2010. He has been working at İstanbul Gedik University, Turkey, since 2010. He is an expert in materials science, destructive and nondestructive material tests, scanning electron microscopy, and diffusion processes.

Özlem Aydin

Özlem Aydin, Assistant Prof. Dr. Özlem Aydin, born 1979, completed her Undergraduate studies at Sakarya University and Graduate and Doctorate studies at Yıldız Technical University. She focuses on surface treatments fields. Between 2010 and 2018 she worked as a Lecturer and since 2018, she has been working as Assistant Professor at Istanbul Gedik University Vocational School.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors declare no conflicts of interest regarding this article.

  4. Research funding: This article was produced from Hitit University BAP Project(2021-Çorum) numbered TBMYO 19001.20.001 and titled “Boriding of High Speed Tool Steels”.

  5. Data availability: Not applicable.

References

[1] M. Keddam, B. Bouarour, Z. Nait Abdellah and R. Chegroune, “The effective diffusion coefficient of boron in the Fe2B layers formed on the iron substrate,” in MATEC Web of Conferences EDP Sciences, 2013.10.1051/matecconf/20130301012Search in Google Scholar

[2] X. Li, et al.., “Boron diffusion in bcc-Fe studied by first-principles calculations,” Chin. Phys. B, vol. 25, no. 3, 2016, Art. no. 036601, https://doi.org/10.1088/1674-1056/25/3/036601.Search in Google Scholar

[3] S. İ. Ayvaz, “Enhancing the wear performance of Ti-6Al-4V against Al2O3 and WC-6Co via TiBn layer produced by boriding,” Mater. Test., vol. 65, no. 2, pp. 279–290, 2023, https://doi.org/10.1515/mt-2022-0238.Search in Google Scholar

[4] P. Topuz, “Development of boronizing parameters and boronizing of different steels in fluidized bed furnace,” Ph.D. Thesis, Institute of Science, Marmara University, İstanbul, Turkey, 2009.Search in Google Scholar

[5] P. Topuz, E. Gündoğdu, E. Yılmaz, and E. Gümüş, “The fracture toughness of Fe2B formed on boronized AISI 304,” Mater. Test., vol. 56, no. 9, pp. 690–693, 2014, https://doi.org/10.3139/120.110621.Search in Google Scholar

[6] T. Arai, et al., ASM Handbook, Vol. 4: Heat Treating, vol. 448, OH/USA, ASM International, 1991, pp. 437–447.Search in Google Scholar

[7] Ö. Aydın, P. Topuz, and T. Aydoğmuş, “Kinetic characterization of boride layers formed on AISI 316 stainless steel,” Mater. Test., vol. 62, no. 6, pp. 652–656, 2020, https://doi.org/10.3139/120.111530.Search in Google Scholar

[8] W. Gissler and H. A. Jehn, Advanced Techniques for Surface Engineering, vol. 14658, Ispra, Italy, Springer Science & Business Media, 1992.10.1007/978-94-017-0631-5Search in Google Scholar

[9] J. C. Velázquez-Altamirano, et al.., “A stochastic model and investigation into the probability distribution of the thickness of boride layers formed on low-carbon steel,” Coatings, vol. 9, no. 11, p. 756, 2019, https://doi.org/10.3390/coatings9110756.Search in Google Scholar

[10] V. Jain and G. Sundararajan, “Influence of the pack thickness of the boronizing mixture on the boriding of steel,” Surf. Coat. Technol., vol. 149, no. 1, pp. 21–26, 2002, https://doi.org/10.1016/S0257-8972(01)01385-8.Search in Google Scholar

[11] M. Keddam, P. Topuz, and Ö. Aydin, “Simulation of boronizing kinetics of AISI 316 steel with an integral diffusion model,” Mater. Test., vol. 63, no. 10, pp. 906–912, 2021, https://doi.org/10.1515/mt-2021-0023.Search in Google Scholar

[12] J. Dossett and G. Totten, Boriding (Boronizing) of Metals, vol. 4, OH/USA, Diamond, 2013, p. 5000.Search in Google Scholar

[13] A. International, ASTM A600-92a, Standard Specification for Tool Steel High Speed, 2016.Search in Google Scholar

[14] M. Skakov, B. Rakhadilov, M. Scheffler, and E. Batyrbekov, “Microstructure and tribological properties of electrolytic plasma nitrided high-speed steel,” Mater. Test., vol. 57, no. 4, pp. 360–364, 2015, https://doi.org/10.3139/120.110709.Search in Google Scholar

[15] S. Lower, “Arrhenius equation,” 2023. Available: https://chem.libretexts.org/@go/page/1443.Search in Google Scholar

[16] T. Arai, et al., ASM Handbook, Vol. 4: Heat Treating, vol. 448, OH/USA, ASM International, 1991, pp. 978–998.Search in Google Scholar

[17] R. W. Carr, Modeling of Chemical Reactions, London/England, Elsevier, 2007.Search in Google Scholar

[18] B. V. L’vov, Thermal Decomposition of Solids and Melts: New Thermochemical Approach to the Mechanism, Kinetics and Methodology, vol. 7, Russia, Springer Science & Business Media, 2007.Search in Google Scholar

[19] H. Schmalzried, Chemical Kinetics of Solids, Weinheim/Germany, John Wiley & Sons, 2008.Search in Google Scholar

[20] C. Martini, G. Palombarini, and M. Carbucicchio, “Mechanism of thermochemical growth of iron borides on iron,” J. Mater. Sci., vol. 39, pp. 933–937, 2004, https://doi.org/10.1023/b:jmsc.0000012924.74578.87.10.1023/B:JMSC.0000012924.74578.87Search in Google Scholar

[21] I. Campos, R. Torres, G. Ramírez, R. Ganem, and J. Martínez, “Growth kinetics of iron boride layers: dimensional analysis,” Appl. Surf. Sci., vol. 252, no. 24, pp. 8662–8667, 2006, https://doi.org/10.1016/j.apsusc.2005.12.002.Search in Google Scholar

[22] E. Hernández-Sánchez and J. C. Velázquez, “Kinetics of growth of iron boride layers on a low-carbon steel surface,” in Laboratory Unit Operations and Experimental Methods in Chemical Engineering, Mexico City/Mexico, Materials Science, Engineering, 2018.10.5772/intechopen.73592Search in Google Scholar

[23] J. Jiang, Y. Wang, Q. Zhong, Q. Zhou, and L. Zhang, “Preparation of Fe2B boride coating on low-carbon steel surfaces and its evaluation of hardness and corrosion resistance,” Surf. Coat. Technol., vol. 206, nos. 2–3, pp. 473–478, 2011, https://doi.org/10.1016/j.surfcoat.2011.07.053.Search in Google Scholar

[24] M. Kulka, N. Makuch, and A. Piasecki, “Nanomechanical characterization and fracture toughness of FeB and Fe2B iron borides produced by gas boriding of Armco iron,” Surf. Coat. Technol., vol. 325, pp. 515–532, 2017, https://doi.org/10.1016/j.surfcoat.2017.07.020.Search in Google Scholar

[25] O. Delai, C. Xia, and L. Shiqiang, “Growth kinetics of the FeB/Fe2B boride layer on the surface of 4Cr5MoSiV1 steel: experiments and modelling,” J. Mater. Res. Technol., vol. 11, pp. 1272–1280, 2021, https://doi.org/10.1016/j.jmrt.2021.01.109.Search in Google Scholar

[26] J. Davis, P. J. Wilbur, D. L. Williamson, R. Wei, and J. J. Vajo, “Ion implantation boriding of iron and AISI M2 steel using a high-current density, low energy, broad-beam ion source,” Surf. Coat. Technol., vol. 103, pp. 52–57, 1998, https://doi.org/10.1016/S0257-8972(98)00374-0.Search in Google Scholar

[27] I. Campos, G. Ramírez, U. Figueroa, J. Martínez, and O. Morales, “Evaluation of boron mobility on the phases FeB, Fe2B and diffusion zone in AISI 1045 and M2 steels,” Appl. Surf. Sci., vol. 253, no. 7, pp. 3469–3475, 2007, https://doi.org/10.1016/j.apsusc.2006.07.046.Search in Google Scholar

[28] I. Campos, R. Torres, O. Bautista, G. Ramírez, and L. Zúñiga, “Effect of boron paste thickness on the growth kinetics of polyphase boride coatings during the boriding process,” Appl. Surf. Sci., vol. 252, no. 6, pp. 2396–2403, 2006, https://doi.org/10.1016/j.apsusc.2005.04.022.Search in Google Scholar

[29] M. A. Doñu Ruiz, et al.., “Growth kinetics of boride coatings formed at the surface AISI M2 during dehydrated paste pack boriding,” Thin Solid Films, vol. 596, pp. 147–154, 2015, https://doi.org/10.1016/j.tsf.2015.07.086.Search in Google Scholar

[30] C. Zouzou and M. Keddam, “Boriding kinetics of FeB and Fe2B layers on AISI M2 steel by the integral diffusion model,” Ann. Chim. Sci. Matériaux, vol. 43, no. 3, pp. 159–164, 2019, https://doi.org/10.18280/acsm.430304.Search in Google Scholar

[31] I. Campos-Silva, M. Ortiz-Dominguez, C. Tapia-Quintero, G. Rodríguez-Castro, M. Y. Jiménez-Reyes, and E. Chávez-Gutiérrez, “Kinetics and boron diffusion in the FeB/Fe2B layers formed at the surface of borided high-alloy steel,” J. Mater. Eng. Perform., vol. 21, pp. 1714–1723, 2012, https://doi.org/10.1007/s11665-011-0088-9.Search in Google Scholar

Published Online: 2024-09-02
Published in Print: 2024-10-28

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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