Abstract:
Reduction of CO2 into useful fuels is regarded as a new way to deal with increasing CO2 emissions and its bad effects on climate. In this report, simple electrochemical oxidation-reduction method has been utilized to prepare Cu2O/polyaniline (PANI)/stainless steel composite electrode, which was identified as a contributor for CO2 reduction in an aqueous solution. X-ray diffraction (XRD), transmission electron microscope (TEM) and cyclic voltammetry technique were carried out to characterize the as-obtained electrode. As-synthesized composite electrode exhibited excellent electrocatalytic activity. The production of formaldehyde that comes from the reduction of CO2 using Cu2O/PANI/stainless steel based electrode (Cu2O/PANI/stainless steel) in 0.1 mol/L sodium sulfate solution is 0.505 μmol·L–1·h–1 approximately.
Funding statement: This work was financially supported by the Shaanxi Provincial Natural Science Basic Research Program under Contract No. BD11015310002.
References
1. Somnath CR, Oomman KV, Maggie P. ACS Nano. 2010;10:1259–1278.Suche in Google Scholar
2. Marcello DF, Gabriele C, Gaetano I. Green energy and technology. London: Springer-Verlag; 2013.Suche in Google Scholar
3. Gattrell M, Gupta N, Co A. Energy Convers Manage. 2007;4:1255–1265.10.1016/j.enconman.2006.09.019Suche in Google Scholar
4. Shan G, Lin Y, Yi X. Nature. 2016;10:68–82.Suche in Google Scholar
5. Singh DP, Sing JAI, Mishra PR. Bull Mater Sci. 2008;6:319–325.10.1007/s12034-008-0051-zSuche in Google Scholar
6. Chen SJ, Chen XT, You XZ. J Cryst Growth. 2002;9:169–175.10.1016/S0022-0248(02)01902-4Suche in Google Scholar
7. Li HL, Lei YG, Huang Y. J Nat Gas Chem. 2011;3:145–150.10.1016/S1003-9953(10)60166-1Suche in Google Scholar
8. Tang JW. Int J Hydrogen Energy. 2013;3:13017–13022.10.1016/j.ijhydene.2013.03.128Suche in Google Scholar
9. Vicente M, Angel I, Angel I. Appl Catal B Environ. 2015;3:176–177.Suche in Google Scholar
10. Dong YJ, Li YD, Wang C. J Colloid Interface Sci. 1 2001;85–89. .10.1006/jcis.2001.7857Suche in Google Scholar
11. Chang TY, Liang R,M, Wu PW. Mater Lett. 2009;1:1001–1003.10.1016/j.matlet.2009.01.067Suche in Google Scholar
12. Zhang FY, Li YJ, Wang ZH. MCA. 2011;1:103–109.Suche in Google Scholar
13. Ghasemi S, Mousavi MF, Shamsipur M. J Solid State Electrochem. 3 2008;259–268. .10.1007/s10008-007-0386-1Suche in Google Scholar
14. Li GC, Jiang L. Macromolecules. 22 2007;7890–7894. .10.1021/ma070650oSuche in Google Scholar
15. Tang ZY, Liu SQ, Wang ZX. Electrochem Commun. 2000;1:32–35.10.1016/S1388-2481(99)00133-2Suche in Google Scholar
16. Han MG, Cho SK, Oh SJ. Synth Met. 1 2002;53–60. .10.1016/S0379-6779(01)00494-5Suche in Google Scholar
17. Ivanauskas F, Malinauskas M, Liana S. J Math Chem. 8 2014;2020–2029. .10.1007/s10910-014-0366-5Suche in Google Scholar
18. Zhang LX, Liu P, Su ZX. Polym Degrad Stab. 9 2006;2213–2219. .10.1016/j.polymdegradstab.2006.01.002Suche in Google Scholar
19. Gopalakrishnan K, Ramesh C, Elango M. ISRN Mater Sci. 1:1-7 2014. .10.1155/2014/567927Suche in Google Scholar
20. Andrews NG, Song. YC, Mari V. Appl Energy. C 2014;85–94. .Suche in Google Scholar
21. Aydin R, Koleli F. J Electroanal Chem. 1 2002;107–112. .10.1016/S0022-0728(02)01151-8Suche in Google Scholar
22. Koleli F, Ropke T, Hamann CH. Synth Met. 2004;1:65–68.10.1016/S0379-6779(03)00021-3Suche in Google Scholar
23. Aydin R, Koleli F. Synth Met. 1 2004;75–80. .10.1016/j.synthmet.2004.02.007Suche in Google Scholar
24. CN-HJ. China Environmental Science Press. 2011. 1-10.Suche in Google Scholar
25. Rahman R, Jayaganthan R. Appl Nanosci. 4 2015;493–498. .10.1007/s13204-014-0342-1Suche in Google Scholar
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Artikel in diesem Heft
- Editorial: The importance of advanced oxidation processes in degrading persistent pollutants
- An overview on heterogeneous Fenton and photoFenton reactions using zerovalent iron materials
- Photooxidative Degradation of Pesticides in Water; Response Surface Modeling Approach
- The treatment of aniline in aqueous solutions by gamma irradiation
- Microwave regeneration of biological activated carbon
- Molecular iodine/aqueous NH4OAc: a green reaction system for direct oxidative synthesis of nitriles from amines
- Catalytic Degradation of Safranin T in Aqueous Medium Using Non-conventional Processes
- Oxidation of 1, 2-dichlorobenzene on a commercial V2O5-WO3/nano-TiO2 catalyst: Effect of HCl addition
- Current conduction mechanisms in thermal nitride and dry gate oxide grown on 4H-silicon carbide (SiC)
- Effect of light and oxygen on repetitive bacterial inactivation on uniform, adhesive, robust and stable Cu-polyester surfaces
- Wet oxidation of an industrial high concentration pharmaceutical wastewater using hydrogen peroxide as an oxidant
- Oxidation characteristics of heavy crude oil in ignition process
- Comparative studies on the performance of porous Ti/Sno2-Sb2O3/Pbo2 enhanced by CNT and Bi Co-doped electrodes for methyl orange oxidation
- Application of photocatalytic paint for destruction of benzo[a]pyrene. Impact of air humidity
- Spray-drying synthesis and characterization of Li4Ti5O12 anode material for lithium ion batteries
- Kinetics analysis of photocatalytic degradation of Acid Orange 7 by Co/N/Er3+: Y3Al5O12/TiO2 films
- Reaction characteristics of oxygen generation from plate-like potassium superoxide within a confined space
- Electrochemical reduction of CO2 on a Cu2O/polyaniline /stainless steel based electrode
- Role of oxygen-containing functional surface groups of activated carbons on the elimination of 2-hydroxybenzothiazole from waters in A hybrid heterogeneous ozonation system
- The degradation efficiency and mechanism of meclofenamic acid in aqueous solution by UV irradiation
- Effect of electrode oxide film in micro arc oxidation on water treatment
- Photocurrent response and photocatalytic activity of Nd-doped TiO2 thin films prepared by sol-gel method
- Mathematical model involving chemical reaction and mass transfer for the ozonation of dimethyl phthalate in water in a bubble column reactor
- Elimination of organic micro-contaminants in municipal wastewater by a combined immobilized biomass reactor and solar photo-Fenton tertiary treatment
- Degradation of catechol on BiOCl: charge transfer complex formation and photoactivity
- Photocatalytic degradation of phenol on strontium titanate supported on HZSM-5
- Selective Fenton-like catalytic oxidation of acid orange II on inorganic heterogeneous molecular imprinted catalysts
- Decoloration of azo dye methyl orange by a novel electro-Fenton internal circulation batch reactor