Spray-drying synthesis and characterization of Li4Ti5O12 anode material for lithium ion batteries
-
Chunyang Li
,
Sijing Wen
Abstract
Spherical and nanostructured Li4Ti5O12 powders were successfully prepared through spray-drying method. Li4Ti5O12 began to be formed after calcining the spray-dried amorphous precursor at approximately 350 °C, and a single phase was obtained at 750 °C. Spherical and porous Li4Ti5O12 particles consisting of polyhedral particles assembled from 21–45 nm grains and 4–24 nm pores. An about 1 nm-thick amorphous layer can also be observed on the surface of the nano-sized grains. The Li4Ti5O12 prepared at 750 °C exhibits the initial discharge capacities of 218 and 211 mAh g−1 and a high retention of 99.90 % and 99.67 % for 50 times at a rate of 1 C or 2 C in the voltage range of 1.0–2.5 V, respectively.
Funding statement: The work was financially supported by Department of Education of Liaoning Province of China.
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- Editorial: The importance of advanced oxidation processes in degrading persistent pollutants
- An overview on heterogeneous Fenton and photoFenton reactions using zerovalent iron materials
- Photooxidative Degradation of Pesticides in Water; Response Surface Modeling Approach
- The treatment of aniline in aqueous solutions by gamma irradiation
- Microwave regeneration of biological activated carbon
- Molecular iodine/aqueous NH4OAc: a green reaction system for direct oxidative synthesis of nitriles from amines
- Catalytic Degradation of Safranin T in Aqueous Medium Using Non-conventional Processes
- Oxidation of 1, 2-dichlorobenzene on a commercial V2O5-WO3/nano-TiO2 catalyst: Effect of HCl addition
- Current conduction mechanisms in thermal nitride and dry gate oxide grown on 4H-silicon carbide (SiC)
- Effect of light and oxygen on repetitive bacterial inactivation on uniform, adhesive, robust and stable Cu-polyester surfaces
- Wet oxidation of an industrial high concentration pharmaceutical wastewater using hydrogen peroxide as an oxidant
- Oxidation characteristics of heavy crude oil in ignition process
- Comparative studies on the performance of porous Ti/Sno2-Sb2O3/Pbo2 enhanced by CNT and Bi Co-doped electrodes for methyl orange oxidation
- Application of photocatalytic paint for destruction of benzo[a]pyrene. Impact of air humidity
- Spray-drying synthesis and characterization of Li4Ti5O12 anode material for lithium ion batteries
- Kinetics analysis of photocatalytic degradation of Acid Orange 7 by Co/N/Er3+: Y3Al5O12/TiO2 films
- Reaction characteristics of oxygen generation from plate-like potassium superoxide within a confined space
- Electrochemical reduction of CO2 on a Cu2O/polyaniline /stainless steel based electrode
- Role of oxygen-containing functional surface groups of activated carbons on the elimination of 2-hydroxybenzothiazole from waters in A hybrid heterogeneous ozonation system
- The degradation efficiency and mechanism of meclofenamic acid in aqueous solution by UV irradiation
- Effect of electrode oxide film in micro arc oxidation on water treatment
- Photocurrent response and photocatalytic activity of Nd-doped TiO2 thin films prepared by sol-gel method
- Mathematical model involving chemical reaction and mass transfer for the ozonation of dimethyl phthalate in water in a bubble column reactor
- Elimination of organic micro-contaminants in municipal wastewater by a combined immobilized biomass reactor and solar photo-Fenton tertiary treatment
- Degradation of catechol on BiOCl: charge transfer complex formation and photoactivity
- Photocatalytic degradation of phenol on strontium titanate supported on HZSM-5
- Selective Fenton-like catalytic oxidation of acid orange II on inorganic heterogeneous molecular imprinted catalysts
- Decoloration of azo dye methyl orange by a novel electro-Fenton internal circulation batch reactor
