Molecular iodine/aqueous NH4OAc: a green reaction system for direct oxidative synthesis of nitriles from amines
-
Yiming Ren
and
Shuo Jin
Abstract
A green and convenient approach for synthesis of nitriles from amines has been accomplished by using the environmentally friendly and inexpensive reagent molecular iodine/aqueous NH4OAc. The aqueous NH4OAc as a green reagent is more eco-friend than ammonia water, because of gaseous ammonia could be evaporated easily from ammonia water while aqueous NH4OAc is not. The possible mechanism of the present reaction was also proposed.
Funding statement: We gratefully acknowledge the Natural Science Foundation of the Anhui Higher Education Institutions (No. KJ2015A033) and the National Innovation Program for University Students (No. 201510363079) for financial support.
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- Editorial: The importance of advanced oxidation processes in degrading persistent pollutants
- An overview on heterogeneous Fenton and photoFenton reactions using zerovalent iron materials
- Photooxidative Degradation of Pesticides in Water; Response Surface Modeling Approach
- The treatment of aniline in aqueous solutions by gamma irradiation
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- Molecular iodine/aqueous NH4OAc: a green reaction system for direct oxidative synthesis of nitriles from amines
- Catalytic Degradation of Safranin T in Aqueous Medium Using Non-conventional Processes
- Oxidation of 1, 2-dichlorobenzene on a commercial V2O5-WO3/nano-TiO2 catalyst: Effect of HCl addition
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- Wet oxidation of an industrial high concentration pharmaceutical wastewater using hydrogen peroxide as an oxidant
- Oxidation characteristics of heavy crude oil in ignition process
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- Application of photocatalytic paint for destruction of benzo[a]pyrene. Impact of air humidity
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- Kinetics analysis of photocatalytic degradation of Acid Orange 7 by Co/N/Er3+: Y3Al5O12/TiO2 films
- Reaction characteristics of oxygen generation from plate-like potassium superoxide within a confined space
- Electrochemical reduction of CO2 on a Cu2O/polyaniline /stainless steel based electrode
- Role of oxygen-containing functional surface groups of activated carbons on the elimination of 2-hydroxybenzothiazole from waters in A hybrid heterogeneous ozonation system
- The degradation efficiency and mechanism of meclofenamic acid in aqueous solution by UV irradiation
- Effect of electrode oxide film in micro arc oxidation on water treatment
- Photocurrent response and photocatalytic activity of Nd-doped TiO2 thin films prepared by sol-gel method
- Mathematical model involving chemical reaction and mass transfer for the ozonation of dimethyl phthalate in water in a bubble column reactor
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