Study on flame retardant properties and thermal stability of synergistically modified polyurethane foam with ammonium polyphosphate and barium phytate
Abstract
Barium phytate (Pa–Ba) was prepared by phytic acid and barium carbonate, and then the flame-retardant modified polyurethane foam (PUF) was synergized with Pa–Ba and ammonium polyphosphate (APP). The flame retardant properties and thermal stability of the modified PUFs were investigated by thermogravimetric analysis, cone calorimetry (CONE) and smoke density (Ds). The results showed the modified PUF with the addition of 5 % Pa–Ba and 10 % APP (PUF-A10-PB5) had the highest integral programmed decomposition temperature and the activation energy, indicating that its thermal stability was better compared with other samples. In addition, PUF-A10-PB5 had the lowest total heat release under different radiation intensities, and it had the smallest Ds and the highest light transmittance under the flame and flameless condition. The current results indicated that PUF-A10-PB5 had better flame-retardant properties and thermal stability, which can provide a useful reference for future experimental studies on the flame retardant properties of phytate-modified PUF.
Funding source: Scientific Research Fund of Liaoning Provincial Education Department
Award Identifier / Grant number: (Grant No. JYT2020011)
Funding source: College students training program of innovation and entrepreneurship in Shenyang Aerospace University
Award Identifier / Grant number: (Grant No. S202310143022)
Acknowledgments
The financial support from Scientific Research Fund of Liaoning Provincial Education Department (Grant No. JYT2020011) and College students training program of innovation and entrepreneurship in Shenyang Aerospace University (Grant No. S202310143022) is greatly acknowledged.
-
Research ethics: Not applicable.
-
Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
-
Competing interests: The authors state no conflict of interest.
-
Research funding: Scientific Research Fund of Liaoning Provincial Education Department (Grant No. JYT2020011). College students training program of innovation and entrepreneurship in Shenyang Aerospace University (Grant No. S202310143022).
-
Data availability: The raw data can be obtained on request from the corresponding author.
References
Bellayer, S., Jimenez, M., Prieur, B., Dewailly, B., Ramgobin, A., Sarazin, J., Revel, B., Tricot, G., and Bourbigot, S. (2018). Fire retardant sol-gel coated polyurethane foam: mechanism of action. Polym. Degrad. Stab. 147: 159–167, https://doi.org/10.1016/j.polymdegradstab.2017.12.005.Suche in Google Scholar
Bhoyate, S., Ionescu, M., Kahol, P.K., and Gupta, R.K. (2018). Sustainable flame-retardant polyurethanes using renewable resources. Ind. Crops Prod. 123: 480–488, https://doi.org/10.1016/j.indcrop.2018.07.025.Suche in Google Scholar
Cheng, Q. (2008). Thermogravimetric analysis technique and its application in the field of polymer materials. Guangdong Chem. Ind. 35: 50–52+81, https://doi.org/10.3969/j.issn.1007-1865.2008.12.017.Suche in Google Scholar
Coats, A.W. and Redfern, J.P. (1964). Kinetic parameters from the thermogravimetric data. Nature 201: 68–69, https://doi.org/10.1038/201068a0.Suche in Google Scholar
Gao, Y.Y., Deng, C., Wang, Y.Z., Du, Y.Y., and Huang, S.C. (2019). A novel bio-based flame retardant for polypropylene from phytic acid. Polym. Degrad. Stab. 161: 198–380, https://doi.org/10.1016/j.polymdegradstab.2019.02.005.Suche in Google Scholar
Jiang, H.H., Liu, X.L., Zou, Y., Zhou, Z.J., Huang, X.J., and Tang, G. (2019). Preparation and flame retardant properties of rigid polyurethane foam/ammonium polyphosphate composites. Plast. Ind. 47: 89–93, https://doi.org/10.3969/j.issn.1005-5770.2019.01.019.Suche in Google Scholar
Kissinger, H.H.E. (1957). Reaction kinetics in differential thermal analysis. Anal. Chem. 29: 1702–1706, https://doi.org/10.1021/ac60131a045.Suche in Google Scholar
Kong, K., Cheedarala, R.K., Kim, M., Roh, H.D., Park, Y.B., and Park, H.W. (2016). Electrical thermal heating and piezoresistive characteristics of hybrid CuO–woven carbon fiber/vinyl ester composite laminates. Compos. Appl. Sci. Manuf. 85: 103–112, https://doi.org/10.1016/j.compositesa.2016.03.015.Suche in Google Scholar
Laufer, G., Kirkland, C., Cain, A.A., and Grunlan, J.C. (2012). Claychitosan nanobrick walls: completely renewable gas barrier and flame-retardant nanocoatings. ACS Appl. Mater. Interfaces 4: 1643–1649, https://doi.org/10.1021/am2017915.Suche in Google Scholar PubMed
Li, D.F., Deng, C., Wang, Y.Z., and Wang, X.L. (2020). Effect of calcium phytate/ammonium polyphosphate intumescent flame retardant on the properties of toughen poly(lactic acid). Polym. Mater. Sci. Eng. 36: 23–29, https://doi.org/10.16865/j.cnki.1000-7555.2020.0056.Suche in Google Scholar
Nabipour, H., Hu, Y., Wang, X., and Song, L. (2020). A fully bio-based coating made: from alginate, chitosan and hydroxyapatite for protecting flexible polyurethane foam from fire carbohydrate. Carbohydr. Polym. 246: 246–257, https://doi.org/10.1016/j.carbpol.2020.116641.Suche in Google Scholar PubMed
Ozawa, T.A. (1965). New method of analyzing thermogravimetric data. Bull. Chem. Soc. Jpn. 38: 1881–1886, https://doi.org/10.1246/bcsj.38.1881.Suche in Google Scholar
Parcheta, P., Koltsov, I., and Datta, J. (2018). Fully bio-based poly(propylene succinate)synthesis and investigation of thermal degradation kinetics with released gases analysis. Polym. Degrad. Stab. 151: 90–99, https://doi.org/10.1016/j.polymdegradstab.2018.03.002.Suche in Google Scholar
Price, D., Liu, Y., Milness, G.J., Hull, R., Baljinder, K., and A.Richard Horrocks, R. (2002). An investigation into the mechanism of flame retardancy and smoke suppression by melamine in flexible polyurethane foam. Fire Mater. 26: 201–206, https://doi.org/10.1002/fam.810.Suche in Google Scholar
Qin, K. and Xu, J.J. (2017). Comparative analysis of domestic and international standards for conical calorimeter method. Stand. Sci. 10: 89–92, https://doi.org/10.3969/j.issn.1674-5698.2017.10.015.Suche in Google Scholar
Taher, R.A., Zahra, S., Minna, H., and Vahid, H.A. (2019). Polyacrylonitrile/N, P Co-doped graphene quantum dots-layered double hydroxide nanocomposite: flame retardant property, thermal stability and fire hazard. Eur. Polym. J. 120: 2–8, https://doi.org/10.1016/j.eurpolymj.2019.109256.Suche in Google Scholar
Wang, J.L., Zhan, J., Mu, X.W., Jin, X., Chu, F.K., Kan, Y.C., and Xing, W.Y. (2018). Manganese phytate dotted polyaniline shell enwrapped carbon nanotube: towards the reinforcements in fire safety and mechanical property of polymer. J. Colloid Interface Sci. 529: 345–356, https://doi.org/10.1016/j.jcis.2018.06.038.Suche in Google Scholar PubMed
Wang, P.J., Liao, J.D., Hu, P.X., Pan, N., Li, W.X., Wang, D.Y., and Yao, Y. (2019). Facile fabrication of biobased P-N-C-containing nano-layered hybrid: preparation, growth mechanism and its efficient fire retardancy in epoxy. Polym. Degrad. Stab. 159: 153–162, https://doi.org/10.1016/j.polymdegradstab.2018.11.024.Suche in Google Scholar
Xia, Q.R., Zong, Y.P., Liu, Y.L., and Ding, H. (1997). Development and application prospects of phytic acid. J. Heilongjiang Cereals Oil Sci. Technol. 2: 48–49, https://doi.org/CNKI:SUN:HLLK.0.1997-02-01.Suche in Google Scholar
Yang, W., Tawiah, B., Yu, C., Qian, Y.F., Wang, L.L., Yuen, A.C.Y., Zhu, S.E., Hu, E.Z., Chen, T.B.Y., Yu, B., et al.. (2018). Manufacturing, mechanical and flame retardant properties of poly(lactic acid) biocomposites based on calcium magnesium phytate and carbon nanotubes. Compos. Appl. Sci. Manuf. 110: 227–236, https://doi.org/10.1016/j.compositesa.2018.04.027.Suche in Google Scholar
Zhang, L.P. and Wang, Q. (2006). Study on the effects of different flame retardants on the flame retardant properties of polyurethane soft foam. Mater. Dev. Appl. 3: 4–6, https://doi.org/10.19515/j.cnki.1003-1545.2006.03.002.Suche in Google Scholar
Zhang, X., Li, S., Wang, Z., Sun, G.H., and Hu, P. (2020a). Thermal stability of flexible polyurethane foams containing modified layered double hydroxides and zinc borate. Int. J. Polym. Anal. Charact. 25: 499–516, https://doi.org/10.1080/1023666X.2020.1812920.Suche in Google Scholar
Zhang, X., Li, S., Wang, Z., and Wang, D.L. (2020b). Study on thermal stability of typical carbon fiber epoxy composites after airworthiness fire protection test. Fire Mater. 44: 202–210, https://doi.org/10.1002/fam.2788.Suche in Google Scholar
Zhang, X., Li, R.Z., Sun, S.M., Wang, Z., and Xie, H. (2024a). Effect of prepared barium phytate on thermal stability and combustion properties of flexible polyurethane foams. Fire Mater., https://doi.org/10.1002/fam.3197.Suche in Google Scholar
Zhang, X., Wang, Z.Q., Sun, S.M., Yuan, D.H., Wen, Y.Q., Su, Z.P., Wang, Z., and Xie, H. (2024b). Fabrication of soybean oil-based polyol modified polyurethane foam from ammonium polyphosphate and its thermal stability and flame retardant properties. Int. Polym. Process. 39: 32–46, https://doi.org/10.1515/IPP-2023-4399.Suche in Google Scholar
© 2024 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Research Articles
- Estimation of friction and wear properties of additively manufactured recycled-ABS parts using artificial neural network approach: effects of layer thickness, infill rate, and building direction
- Investigation of the mechanical, thermal and wear properties of eggshell/PLA composites
- Impact of fiber diameter on mechanical and water absorption properties of short bamboo fiber-reinforced polyester composites
- Polyurethane foam reinforced with Ag nanoparticle decorated ZnO nanorods: a dual-functional approach for improved antibacterial and mechanical properties
- Synthesis and characterization of ethylenediamine-modified F-44 phenolic epoxy fiber
- Study on flame retardant properties and thermal stability of synergistically modified polyurethane foam with ammonium polyphosphate and barium phytate
- Investigation on the mechanical and moisture uptake properties of epoxy-Terminalia arjuna fiber natural composites containing nano-silica
- Tribo-mechanical and structural characterizations of LLDPE matrix bio-composite reinforced with almond shell micro-particles: effects of the processing methodology
- Influence of the injection velocity profile on the properties of injection moulded parts
Artikel in diesem Heft
- Frontmatter
- Research Articles
- Estimation of friction and wear properties of additively manufactured recycled-ABS parts using artificial neural network approach: effects of layer thickness, infill rate, and building direction
- Investigation of the mechanical, thermal and wear properties of eggshell/PLA composites
- Impact of fiber diameter on mechanical and water absorption properties of short bamboo fiber-reinforced polyester composites
- Polyurethane foam reinforced with Ag nanoparticle decorated ZnO nanorods: a dual-functional approach for improved antibacterial and mechanical properties
- Synthesis and characterization of ethylenediamine-modified F-44 phenolic epoxy fiber
- Study on flame retardant properties and thermal stability of synergistically modified polyurethane foam with ammonium polyphosphate and barium phytate
- Investigation on the mechanical and moisture uptake properties of epoxy-Terminalia arjuna fiber natural composites containing nano-silica
- Tribo-mechanical and structural characterizations of LLDPE matrix bio-composite reinforced with almond shell micro-particles: effects of the processing methodology
- Influence of the injection velocity profile on the properties of injection moulded parts