Startseite Single and Double Bubble Tubular Film Extrusion of Polybutylene Terephthalate
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Single and Double Bubble Tubular Film Extrusion of Polybutylene Terephthalate

  • K. Song und J. L. White
Veröffentlicht/Copyright: 23. Februar 2022
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Abstract

An experimental study of film formation and structure development of polybutylene terephthalate (PBT) in single and double bubble tubular film extrusion processes is presented. PBT was found largely stable in the first stage. In the second stage, the bubble was unstable and biaxial inflation was achieved only with a blow-up ratio of one. The sources of second bubble instabilities were related to the crystalline nature of the first bubble being inflated in the second stage. The structure and properties in the films varied substantially with processing conditions. While the first bubble had poorly ordered α-structure, the double bubble possessed oriented polymorphic texture. The second deformation that induced high film-line stress favored the formation of a stable β phase. The mechanical behavior of the films reflected the crystal perfection as well as orientation in the films.


Prof. Dr. J. L. White, Institute of Polymer Engineering, University of Akron, Akron, OH-44325-0301, USA


Acknowledgements

The authors wish to thank BASF Co. and Hoechst Celanese Co. for supplying the polymer resins studied. They also give special thanks to Mr. M.D. Crist, Dr. K. Mühlbach and Mr. J.J. Ocampo at BASF Co. for their useful discussions concerning the processing of the polymers.

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Received: 1999-02-22
Accepted: 1999-12-26
Published Online: 2022-02-23

© 2000 Walter de Gruyter GmbH, Berlin/Boston, Germany

Heruntergeladen am 6.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ipp-2000-0007/pdf
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