Startseite Fabrication of magnetic core–shell Fe nanowires by electrochemical deposition
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Fabrication of magnetic core–shell Fe nanowires by electrochemical deposition

  • Xiaoming Cao , Aiman Mukhtar EMAIL logo , Liyuan Gu und Kai Ming Wu
Veröffentlicht/Copyright: 25. Februar 2022
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Abstract

Highly-ordered Fe nanowires (NWs) were successfully electrodeposited in a laboratory made anodic aluminum oxide template with a diameter of 30 nm. The as prepared Fe NWs were used as a substrate to prepare core–shell Fe@Fe3O4 NWs after annealing and hydrogen reduction at high temperature. The phase transformation of the oxide shell of electrodeposited Fe NWs took the form Fe2O3 → α-Fe2O3 → Fe3O4. Transmission electron microscopy images revealed that the surface of Fe@Fe x−1O x NWs was smooth and orderly, and the oxide layer was dense and uniform. The magnetic analysis of Fe@Fe x−1 O x nanowires was carried out using a vibrating sample magnetometer. It was found that Fe@Fe3O4 nanowires manifested the characteristics of super-paramagnetism in the direction perpendicular to the nanowires due to smaller coercive force, and they can be suitable material for future biomedical applications.


Corresponding author: Aiman Mukhtar, The State Key Laboratory of Refractories and Metallurgy, Hubei Province Key Laboratory of Systems Science in Metallurgical Process, International Research Institute for Steel Technology, Collaborative Innovation Center for Advanced Steels, Wuhan University of Science and Technology, Wuhan, P. R. China, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors are grateful to the financial support by Natural Science Foundation of China (Grant No. U1532268) and the Wuhan Science and Technology Program (Grant No. 2019010701011382).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-06-17
Accepted: 2021-10-05
Published Online: 2022-02-25
Published in Print: 2022-02-23

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