Abstract
A novel interconnected screw reactor was proposed to convert biomass to bio-oil and bio-char in this study. This reactor is expected to achieve direct heating of pyrolysis feedstocks and increase the reactor processing capacity through the recycling of biochar between the inner and outer screw. Here, we simulated the biomass particle flow and reaction process in this interconnected reactor by an extended discrete element method (DEM), the effect of char circulation on the reactor temperature distribution and the product yields are investigated. The results show that the char circulation increased the heating rate of biomass. At the inner and outer screw speed of 10 rpm and 1 rpm, the char circulation can reach 5.15 kg/h and the average temperature of biomass under the char circulation is about 30 °C higher than that without char circulation. The reaction simulation results show that at 500 °C, the yield of char, bio-oil and non-condensable gas are 18.9%, 40.6% and 40.5% respectively. The predicted product yields of char, bio-oil and non-condensable gas are also in good agreement with the experimental measurements.
Acknowledgments
The authors gratefully acknowledge National Natural Science Foundation of China (Grant No. 51906041) and the Natural Science Foundation of Jiangsu province (Grant NO. BK20190360).
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
Ahmed, A., M. S. Abu Bakar, R. S. Sukri, M. Hussain, A. Farooq, S. Moogi, and Y. K. Park. 2020. “Sawdust Pyrolysis from the Furniture Industry in an Auger Pyrolysis Reactor System for Biochar and Bio-Oil Production.” Energy Conversion and Management 226: 113502. https://doi.org/10.1016/j.enconman.2020.113502.Suche in Google Scholar
An, H. 2019. “Optimal Daily Scheduling of Mobile Machines to Transport Cellulosic Biomass from Satellite Storage Locations to a Bioenergy Plant.” Applied Energy 236: 231–43. https://doi.org/10.1016/j.apenergy.2018.11.073.Suche in Google Scholar
An, H. 2022. “The Closed-Open Truck and Loader Routing Problem for Biomass Transportation from Satellite Storage Locations to a Bioenergy Plant.” Computers and Electronics in Agriculture 194: 106764. https://doi.org/10.1016/j.compag.2022.106764.Suche in Google Scholar
Ansari, K. B., B. Kamal, S. Beg, M. A. Wakeel Khan, M. S. Khan, M. K. Al Mesfer, and M. Danish. 2021. “Recent Developments in Investigating Reaction Chemistry and Transport Effects in Biomass Fast Pyrolysis: A Review.” Renewable and Sustainable Energy Reviews 150: 111454. https://doi.org/10.1016/j.rser.2021.111454.Suche in Google Scholar
Babler, M. U., A. Phounglamcheik, M. Amovic, R. Ljunggren, and K. Engvall. 2017. “Modeling and Pilot Plant Runs of Slow Biomass Pyrolysis in a Rotary Kiln.” Applied Energy 207: 123–33. https://doi.org/10.1016/j.apenergy.2017.06.034.Suche in Google Scholar
Bajpai, P. 2020a. “Chapter 7 – Advantages and disadvantages of biomass utilization.” In Biomass to Energy Conversion Technologies, edited by P. Bajpai, 169–173. Elsevier.10.1016/B978-0-12-818400-4.00007-4Suche in Google Scholar
Bajpai, P. 2020b. “Chapter 8 – Biomass energy projects worldwide.” In Biomass to Energy Conversion Technologies, edited by P. Bajpai, 175–88. Elsevier.10.1016/B978-0-12-818400-4.00008-6Suche in Google Scholar
Batchelor, G. K., and R. W. O’Brien. 1977. “Thermal or Electrical Conduction through a Granular Material.” In Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences, Vol. 355, 313–33.10.1098/rspa.1977.0100Suche in Google Scholar
Berruti, B. F. 2010. A Mobile Pyrolyzer for Converting Agricultural and Forestry Residues into Liquid Bio-Oil and Bio-Char, 356–7. London, ON: CO2 Summit: Technology and Opportunity.Suche in Google Scholar
Brassard, P., S. Godbout, and V. Raghavan. 2017. “Pyrolysis in Auger Reactors for Biochar and Bio-Oil Production: A Review.” Biosystems Engineering 161: 80–92. https://doi.org/10.1016/j.biosystemseng.2017.06.020.Suche in Google Scholar
Brown, J. N., and R. C. Brown. 2012. “Process Optimization of an Auger Pyrolyzer with Heat Carrier Using Response Surface Methodology.” Bioresource Technology 103 (1): 405–14. https://doi.org/10.1016/j.biortech.2011.09.117.Suche in Google Scholar PubMed
Brown, D., A. Rowe, and P. Wild. 2013. “A Techno-Economic Analysis of Using Mobile Distributed Pyrolysis Facilities to Deliver a Forest Residue Resource.” Bioresource Technology 150: 367–76. https://doi.org/10.1016/j.biortech.2013.10.018.Suche in Google Scholar PubMed
Cai, W., and R. Liu. 2016. “Performance of a Commercial-Scale Biomass Fast Pyrolysis Plant for Bio-Oil Production.” Fuel 182: 677–86. https://doi.org/10.1016/j.fuel.2016.06.030.Suche in Google Scholar
Campuzano, F., R. C. Brown, and J. D. Martínez. 2019. “Auger Reactors for Pyrolysis of Biomass and Wastes.” Renewable and Sustainable Energy Reviews 102: 372–409. https://doi.org/10.1016/j.rser.2018.12.014.Suche in Google Scholar
Chireshe, F., F. X. Collard, and J. F. Görgens. 2020. “Production of Low Oxygen Bio-Oil via Catalytic Pyrolysis of Forest Residues in a Kilogram-Scale Rotary Kiln Reactor.” Journal of Cleaner Production 260: 120987. https://doi.org/10.1016/j.jclepro.2020.120987.Suche in Google Scholar
Di Blasi, C. 1993. “Analysis of Convection and Secondary Reaction Effects within Porous Solid Fuels Undergoing Pyrolysis.” Combustion Science and Technology 90 (5–6): 315–40. https://doi.org/10.1080/00102209308907620.Suche in Google Scholar
Fakayode, O. A., E. A. A. Aboagarib, C. Zhou, and H. Ma. 2020. “Co-pyrolysis of Lignocellulosic and Macroalgae Biomasses for the Production of Biochar – A Review.” Bioresource Technology 297: 122408. https://doi.org/10.1016/j.biortech.2019.122408.Suche in Google Scholar PubMed
Ghodake, G. S., S. K. Shinde, A. A. Kadam, R. G. Saratale, G. D. Saratale, M. Kumar, R. R. Palem, H. A. Al-Shwaiman, A. M. Elgorban, A. Syed, and D. Y. Kim. 2021. “Review on Biomass Feedstocks, Pyrolysis Mechanism and Physicochemical Properties of Biochar: State-Of-The-Art Framework to Speed up Vision of Circular Bioeconomy.” Journal of Cleaner Production 297: 126645. https://doi.org/10.1016/j.jclepro.2021.126645.Suche in Google Scholar
Golecha, R., and J. Gan. 2016. “Biomass Transport Cost from Field to Conversion Facility when Biomass Yield Density and Road Network Vary with Transport Radius.” Applied Energy 164: 321–31. https://doi.org/10.1016/j.apenergy.2015.11.070.Suche in Google Scholar
Golshan, S., R. Sotudeh-Gharebagh, R. Zarghami, N. Mostoufi, B. Blais, and J. A. M. Kuipers. 2020. “Review and Implementation of CFD-DEM Applied to Chemical Process Systems.” Chemical Engineering Science 221: 115646. https://doi.org/10.1016/j.ces.2020.115646.Suche in Google Scholar
Horabik, J., M. Beczek, R. Mazur, P. Parafiniuk, M. Ryżak, and M. Molenda. 2017. “Determination of the Restitution Coefficient of Seeds and Coefficients of Visco-Elastic Hertz Contact Models for DEM Simulations.” Biosystems Engineering 161: 106–19. https://doi.org/10.1016/j.biosystemseng.2017.06.009.Suche in Google Scholar
Husár, J., P. Šuhaj, and J. Haydary. 2021. “Experimental Validation of Complex Mathematical Model of Screw Reactor Coupled with Particle Model Describing Pyrolysis of Lignocellulosic Biomass.” Journal of Environmental Chemical Engineering 9 (4): 105543. https://doi.org/10.1016/j.jece.2021.105543.Suche in Google Scholar
Kan, T., V. Strezov, and T. J. Evans. 2016. “Lignocellulosic Biomass Pyrolysis: A Review of Product Properties and Effects of Pyrolysis Parameters.” Renewable and Sustainable Energy Reviews 57: 1126–40. https://doi.org/10.1016/j.rser.2015.12.185.Suche in Google Scholar
Lu, L., X. Gao, M. Shahnam, and W. A. Rogers. 2021. “Simulations of Biomass Pyrolysis Using Glued-Sphere CFD-DEM with 3-D Intra-particle Models.” Chemical Engineering Journal 419: 129564. https://doi.org/10.1016/j.cej.2021.129564.Suche in Google Scholar
Park, J. Y., J. K. Kim, C. H. Oh, J. W. Park, and E. E. Kwon. 2019. “Production of Bio-Oil from Fast Pyrolysis of Biomass Using a Pilot-Scale Circulating Fluidized Bed Reactor and its Characterization.” Journal of Environmental Management 234: 138–44. https://doi.org/10.1016/j.jenvman.2018.12.104.Suche in Google Scholar PubMed
Perkins, G., T. Bhaskar, and M. Konarova. 2018. “Process Development Status of Fast Pyrolysis Technologies for the Manufacture of Renewable Transport Fuels from Biomass.” Renewable and Sustainable Energy Reviews 90: 292–315. https://doi.org/10.1016/j.rser.2018.03.048.Suche in Google Scholar
Pichler, M., B. Haddadi, C. Jordan, H. Norouzi, and M. Harasek. 2021a. “Influence of Particle Residence Time Distribution on the Biomass Pyrolysis in a Rotary Kiln.” Journal of Analytical and Applied Pyrolysis 158: 105171. https://doi.org/10.1016/j.jaap.2021.105171.Suche in Google Scholar
Pichler, M., B. Haddadi, C. Jordan, H. Norouzi, and M. Harasek. 2021b. “Dataset for the Simulated Biomass Pyrolysis in Rotary Kilns with Varying Particle Residence Time Distributions.” Data in Brief 39: 107603. https://doi.org/10.1016/j.dib.2021.107603.Suche in Google Scholar PubMed PubMed Central
Qi, F. L., and M. M. Wright. 2018. “Particle Scale Modeling of Heat Transfer in Granular Flows in a Double Screw Reactor.” Powder Technology 335: 18–34. https://doi.org/10.1016/j.powtec.2018.04.068.Suche in Google Scholar
Qi, F., and M. M. Wright. 2020. “A DEM Modeling of Biomass Fast Pyrolysis in a Double Auger Reactor.” International Journal of Heat and Mass Transfer 150: 119308. https://doi.org/10.1016/j.ijheatmasstransfer.2020.119308.Suche in Google Scholar
Rong, D., and M. Horio. 1999. DEM Simulation of Char Combustion in a Fluidized Bed, 65–70. Melbourne: Second International Conference on CFD in the Minerals and Process Industries.Suche in Google Scholar
Schnorf, V., E. Trutnevyte, G. Bowman, and V. Burg. 2021. “Biomass Transport for Energy: Cost, Energy and CO2 Performance of Forest Wood and Manure Transport Chains in Switzerland.” Journal of Cleaner Production 293: 125971. https://doi.org/10.1016/j.jclepro.2021.125971.Suche in Google Scholar
Tran, Q. K., M. L. Le, H. V. Ly, H. C. Woo, J. Kim, and S. S. Kim. 2021. “Fast Pyrolysis of Pitch Pine Biomass in a Bubbling Fluidized-Bed Reactor for Bio-Oil Production.” Journal of Industrial and Engineering Chemistry 98: 168–79. https://doi.org/10.1016/j.jiec.2021.04.005.Suche in Google Scholar
Wang, N., H. Si, W. Yi, Y. Li, and Y. Zhang. 2021a. “Design and Operation of a Mobile Fast Pyrolysis System Utilizing a Novel Double Pipe Fluidized Bed Reactor.” Fuel Processing Technology 224: 107005. https://doi.org/10.1016/j.fuproc.2021.107005.Suche in Google Scholar
Wang, N., H. Si, W. Yi, Y. Li, and Y. Zhang. 2021b. “Design and Operation of a Mobile Fast Pyrolysis System Utilizing a Novel Double Pipe Fluidized Bed Reactor.” Fuel Processing Technology 224: 107005. https://doi.org/10.1016/j.fuproc.2021.107005.Suche in Google Scholar
Yogalakshmi, K. N., D. T. Poornima, P. Sivashanmugan, S. Kavitha, R. K. Yukesh, S. Varjani, S. K. Adish, G. Kumar, and J. B. Rajesh. 2022. “Lignocellulosic Biomass-Based Pyrolysis: A Comprehensive Review.” Chemosphere 286: 131824. https://doi.org/10.1016/j.chemosphere.2021.131824.Suche in Google Scholar PubMed
Zhong, W., A. Yu, X. Liu, Z. Tong, and H. Zhang. 2016. “DEM/CFD-DEM Modelling of Non-spherical Particulate Systems: Theoretical Developments and Applications.” Powder Technology 302: 108–52. https://doi.org/10.1016/j.powtec.2016.07.010.Suche in Google Scholar
Zhu, H. P., Z. Y. Zhou, R. Y. Yang, and A. B. Yu. 2007. “Discrete Particle Simulation of Particulate Systems: Theoretical Developments.” Chemical Engineering Science 62 (13): 3378–96. https://doi.org/10.1016/j.ces.2006.12.089.Suche in Google Scholar
© 2022 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Articles
- Enhanced mechanical stirring by eccentric impeller stirring system in zinc hydrometallurgy process for cadmium removal
- DEM simulation of biomass pyrolysis in a novel interconnected screw reactor
- Numerical and experimental investigations on enhancement mixing performance of multi-blade stirring system for fluids with different viscosities
- The technical and economic analysis of processing and conversion of heavy oil cuts to valuable refinery products
- Effect of inlet gas velocity on gas-solid fluidization characteristics in fluidized bed
- Investigation into a multiple input/output bifurcated biochemical reaction with substrate inhibition in a real CSTR based on Cholette’s model
- Performance of photocatalytic oxidation surface with new geometry for indoor environment application: experimental and simulation
- Optimization of hydrothermal liquefaction process for bio-oil products from kitchen residue under subcritical conditions
- Value-added biochar production from microwave pyrolysis of peanut shell
- Short Communications
- Environmentally sustainable synthesis of cyclic carbonates from epoxides and CO2 promoted by MCM-41 supported dual imidazolium ionic liquids catalysts
Artikel in diesem Heft
- Frontmatter
- Articles
- Enhanced mechanical stirring by eccentric impeller stirring system in zinc hydrometallurgy process for cadmium removal
- DEM simulation of biomass pyrolysis in a novel interconnected screw reactor
- Numerical and experimental investigations on enhancement mixing performance of multi-blade stirring system for fluids with different viscosities
- The technical and economic analysis of processing and conversion of heavy oil cuts to valuable refinery products
- Effect of inlet gas velocity on gas-solid fluidization characteristics in fluidized bed
- Investigation into a multiple input/output bifurcated biochemical reaction with substrate inhibition in a real CSTR based on Cholette’s model
- Performance of photocatalytic oxidation surface with new geometry for indoor environment application: experimental and simulation
- Optimization of hydrothermal liquefaction process for bio-oil products from kitchen residue under subcritical conditions
- Value-added biochar production from microwave pyrolysis of peanut shell
- Short Communications
- Environmentally sustainable synthesis of cyclic carbonates from epoxides and CO2 promoted by MCM-41 supported dual imidazolium ionic liquids catalysts