Home Performance of photocatalytic oxidation surface with new geometry for indoor environment application: experimental and simulation
Article
Licensed
Unlicensed Requires Authentication

Performance of photocatalytic oxidation surface with new geometry for indoor environment application: experimental and simulation

  • Fatemeh Khoshpasand , Ahmad Nikpay EMAIL logo and Mehrdad Keshavarz
Published/Copyright: March 6, 2023

Abstract

Many studies of the photocatalytic oxidation process investigated on the removal efficiency and other variables of the input and output photoreactor. In the laboratory scale, it’s impossible, examination of the removal efficiency details, such as mass and energy transfer with air flow rate. Also, experimental methods request time consumption and money. For this reason, the simulation method can be used. The aim of this study was to prove that the validation of modeling approach in the photocatalytic oxidation process in the removal of toluene from air. Investigation of bed surface morphology, with FESEM, BET and TGA, shows acceptable monotonous of TiO2 nanoparticles on the ss plate. Furthermore, it was observed good adherence of nanoparticles on it. Experimental results on photocatalytic bed surface exhibited in the toluene concentration range of 10–40 ppm and flow rate of 2–5 l/min, with increasing flow and decreasing concentration, removal efficiency increased. The optimum removal point was 59% and 25 g/m3 min for 3.75 ppm and 5.61 l/min. For bed surface performance, the correlation between experimental results and simulation data was obtained 98%. According to the results, the photocatalytic oxidation process performed well for removal of low concentration of toluene from air. In addition, the obtained simulation method eliminated the random factors which can be affected by photocatalytic bed surface and it can show dependence of results based on reality.


Corresponding author: Ahmad Nikpay, Health Products Safety Research Center, Qazvin University of Medical Sciences, P.O.Box 34197-659811, Qazvin, Iran, E-mail:

Funding source: Qazvin University of Medical Sciences

Award Identifier / Grant number: 14004340 (IR.QUMS.REC.1399.056)

  1. Research funding: This study is done as a research project with a code of 14004340 (IR.QUMS.REC.1399.056). This work is supported by the Qazvin University of Medical Sciences in all stages. We thank the University for technical assistance in the experimental examination.

  2. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Alvarado-Rolon, O., R. Natividad, R. Romero, L. Hurtado, and A. Ramírez-Serrano. 2018. “Modelling and Simulation of the Radiant Field in an Annular Heterogeneous Photoreactor Using a Four-Flux Model.” International Journal of Photoenergy 2018: 1–16, https://doi.org/10.1155/2018/1678385.Search in Google Scholar

Ao, C., and S. Lee. 2005. “Indoor Air Purification by Photocatalyst TiO2 Immobilized on an Activated Carbon Filter Installed in an Air Cleaner.” Chemical Engineering Science 60 (1): 103–9. https://doi.org/10.1016/j.ces.2004.01.073.Search in Google Scholar

Carneiro, J., V. Teixeira, P. Carvalho, S. Azevedo, and N. Manninen. 2011. “Self-Cleaning Smart Nanocoatings.” In Nanocoatings and Ultra-Thin Films, 397–413. Texas: Elsevier.10.1533/9780857094902.2.397Search in Google Scholar

da Costa Filho, B. M., and V. J. Vilar. 2020. “Strategies for the Intensification of Photocatalytic Oxidation Processes towards Air Streams Decontamination: A Review.” Chemical Engineering Journal 391: 123531. https://doi.org/10.1016/j.cej.2019.123531.Search in Google Scholar

Hosseini, S., S. Borghei, M. Vossoughi, and N. Taghavinia. 2007. “Immobilization of TiO2 on Perlite Granules for Photocatalytic Degradation of Phenol.” Applied Catalysis B: Environmental 74 (1–2): 53–62. https://doi.org/10.1016/j.apcatb.2006.12.015.Search in Google Scholar

Khoshpasand, F., A. Nikpay, and M Keshavarz. 2023. “Optimization of the Photocatalytic Oxidation Process in Toluene Removal from Air.” Pollution 9 (2): 567–78, https://doi.org/10.22059/poll.2022.347254.1595.Search in Google Scholar

Liang, W., J. Li, and H. He. 2012. “Photo-Catalytic Degradation of Volatile Organic Compounds (VOCs) over Titanium Dioxide Thin Film.” Advanced Aspects of Spectroscopy 12: 341–72.10.5772/48160Search in Google Scholar

Mamaghani, A. H., F. Haghighat, and C.-S. Lee. 2017. “Photocatalytic Oxidation Technology for Indoor Environment Air Purification: The State-Of-The-Art.” Applied Catalysis B: Environmental 203: 247–69. https://doi.org/10.1016/j.apcatb.2016.10.037.Search in Google Scholar

Medina-Valtierra, J., E. Moctezuma, M. Sánchez-Cárdenas, and C. Frausto-Reyes. 2005. “Global Photonic Efficiency for Phenol Degradation and Mineralization in Heterogeneous Photocatalysis.” Journal of Photochemistry and Photobiology A: Chemistry 174 (3): 246–52. https://doi.org/10.1016/j.jphotochem.2005.03.020.Search in Google Scholar

Merajin, M. T., S. Sharifnia, S. Hosseini, and N. Yazdanpour. 2013. “Photocatalytic Conversion of Greenhouse Gases (CO2 and CH4) to High Value Products Using TiO2 Nanoparticles Supported on Stainless Steel Webnet.” Journal of the Taiwan Institute of Chemical Engineers 44 (2): 239–46. https://doi.org/10.1016/j.jtice.2012.11.007.Search in Google Scholar

Nikzad, A., and D. Iranshahi. 2021. “Analysis of Integrated System for Ammonia Synthesis and Methyl Formate Production in the Thermally Coupled Reactor.” Chemical Engineering and Processing-Process Intensification 166: 108418. https://doi.org/10.1016/j.cep.2021.108418.Search in Google Scholar

Rice, R. G., and D. D. Do. 2012. Applied Mathematics and Modeling for Chemical Engineers. John Wiley & Sons.Search in Google Scholar

Shang, J., W. Li, and Y. Zhu. 2003. “Structure and Photocatalytic Characteristics of TiO2 Film Photocatalyst Coated on Stainless Steel Webnet.” Journal of Molecular Catalysis A: Chemical 202 (1–2): 187–95. https://doi.org/10.1016/s1381-1169(03)00200-0.Search in Google Scholar

Shaveisi, Y., and S. Sharifnia. 2018. “Deriving Ag3PO4CaO Composite as a Stable and Solar Light Photocatalyst for Efficient Ammonia Degradation from Wastewater.” Journal of Energy Chemistry 27 (1): 290–9. https://doi.org/10.1016/j.jechem.2017.06.012.Search in Google Scholar

Shayegan, Z., C.-S. Lee, and F. Haghighat. 2018. “TiO2 Photocatalyst for Removal of Volatile Organic Compounds in Gas Phase–A Review.” Chemical Engineering Journal 334: 2408–39. https://doi.org/10.1016/j.cej.2017.09.153.Search in Google Scholar

Sokhansanj, A., S. M. Abdoli, and M. Zabihi. 2020. “Insight into Simultaneous Catalytic Oxidation of Benzene and Toluene in Air over the Nano-Catalyst: Experimental and Modeling via CFD-ANN Hybrid Method.” Process Safety and Environmental Protection 141: 321–32. https://doi.org/10.1016/j.psep.2020.05.035.Search in Google Scholar

Vaiano, V., O. Sacco, D. Pisano, D. Sannino, and P. Ciambelli. 2015. “From the Design to the Development of a Continuous Fixed Bed Photoreactor for Photocatalytic Degradation of Organic Pollutants in Wastewater.” Chemical Engineering Science 137: 152–60. https://doi.org/10.1016/j.ces.2015.06.023.Search in Google Scholar

Van Gerven, T., G. Mul, J. Moulijn, and A. Stankiewicz. 2007. “A Review of Intensification of Photocatalytic Processes.” Chemical Engineering and Processing: Process Intensification 46 (9): 781–9. https://doi.org/10.1016/j.cep.2007.05.012.Search in Google Scholar

van Walsem, J., J. Roegiers, B. Modde, S. Lenaerts, and S. Denys. 2018. “Integration of a Photocatalytic Multi-Tube Reactor for Indoor Air Purification in HVAC Systems: A Feasibility Study.” Environmental Science and Pollution Research 25 (18): 18015–26. https://doi.org/10.1007/s11356-018-2017-z.Search in Google Scholar PubMed

Verbruggen, S. W. 2015. “TiO2 Photocatalysis for the Degradation of Pollutants in Gas Phase: From Morphological Design to Plasmonic Enhancement.” Journal of Photochemistry and Photobiology C: Photochemistry Reviews 24: 64–82. https://doi.org/10.1016/j.jphotochemrev.2015.07.001.Search in Google Scholar

Vione, D., C. Minero, V. Maurino, M. E. Carlotti, T. Picatonotto, and E. Pelizzetti. 2005. “Degradation of Phenol and Benzoic Acid in the Presence of a TiO2-Based Heterogeneous Photocatalyst.” Applied Catalysis B: Environmental 58 (1–2): 79–88. https://doi.org/10.1016/j.apcatb.2004.11.018.Search in Google Scholar

Zhong, L., and F. Haghighat. 2015. “Photocatalytic Air Cleaners and Materials Technologies–Abilities and Limitations.” Building and Environment 91: 191–203. https://doi.org/10.1016/j.buildenv.2015.01.033.Search in Google Scholar


Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/ijcre-2022-0173).


Received: 2022-09-03
Accepted: 2023-02-12
Published Online: 2023-03-06

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 11.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ijcre-2022-0173/html
Scroll to top button