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Hydrogen Production by Hydrolysis of NaBH4 with Cr-Ni-W-B Catalyst: Effects of Cold Plasma and Chromium Content

  • Ömer Şahin , Cafer Saka EMAIL logo , Arzu Ekinci and Asım Balbay
Published/Copyright: January 21, 2016
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International Journal of Chemical Reactor Engineering
From the journal International Journal of Chemical Reactor Engineering Volume 14 Issue 1

Abstract

In this study, the hydrogen generation from the hydrolysis of NaBH4 with Cr0.0125-Ni-W-B catalyst prepared in the presence of cold plasma was investigated based on Cr content, NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma gases effects. The results of the activity tests indicate that the choice of Cr and the catalyst composition greatly influenced the activity as well as the selectivity for hydrogen generation from the hydrolysis of NaBH4. The Cr0.0125-Ni-W-B catalyst was treated with argon, nitrogen and carbon dioxide plasma at different treatment times. The catalysts were characterized using SEM, BET surface area measurement and XRD.

Keywords: cold plasma; sodium borohydride; Cr0.0125-Ni-W-B; hydrogen generation

Funding statement: Funding: The authors are grateful to the Research Foundation of Siirt University for financial support under Project 2013-SİÜMÜH-M5.

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Published Online: 2016-1-21
Published in Print: 2016-2-1

©2016 by De Gruyter

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  1. Frontmatter
  2. Review
  3. Novel Membrane Reactor Concepts for Hydrogen Production from Hydrocarbons: A Review
  4. Research Articles
  5. Modeling and Simulation Study of an Industrial Radial Moving Bed Reactor for Propane Dehydrogenation Process
  6. Oxidative Degradation of Methylene Blue in Aqueous Medium Catalyzed by Lab Prepared Nickel Hydroxide
  7. CFD Modelling of a Hollow Fibre Membrane for CO2 Removal by Aqueous Amine Solutions of MEA, DEA and MDEA
  8. Performance Study of a Thermally Double Coupled Multi-Tubular Reactor by Considering the Effect of Flow Type Patterns
  9. Radiative Three-Dimensional Flow with Chemical Reaction
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  11. Study on the Effect of Nickel Doping on Mo-Bi Based Catalyst for Selective Oxidation of Isobutene to Methacrolein
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  19. Green Approach for Biodiesel Production from Jojoba Oil Supported by Process Modeling and Simulation
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  38. Kinetic Modeling of VOC Photocatalytic Degradation Using a Process at Different Reactor Configurations and Scales
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  41. Performance of a Catalytic Gas–Solid Fluidized Bed Reactor in the Presence of Interparticle Forces
  42. Mathematical Modeling of Biodiesel Production under Intense Agitation
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  44. CFD Modeling of Algae Flash Pyrolysis in the Batch Fluidized Bed Reactor Including Heat Carrier Particles
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  47. Effect of Biomass Compositions on Combustion Kinetic Parameters using Response Surface Methodology
  48. Short Communications
  49. Discussions on Particle Flux Measurement in Gas-Solids Risers
  50. Use of New Regeneration Processes for Thermolabile Amines
  51. Oxidative-Extractive Desulfurization of Liquid Fuel by Dimethyl Sulfoxide and ZnCl2 Based Ionic Liquid
  52. Corrigendum
  53. Corrigendum to: Performance Analysis of Immobilized Enzyme Semifluidised Bed Bioreactors
https://doi.org/10.1515/ijcre-2015-0139
Keywords for this article
cold plasma; sodium borohydride; Cr0.0125-Ni-W-B; hydrogen generation

Articles in the same Issue

  1. Frontmatter
  2. Review
  3. Novel Membrane Reactor Concepts for Hydrogen Production from Hydrocarbons: A Review
  4. Research Articles
  5. Modeling and Simulation Study of an Industrial Radial Moving Bed Reactor for Propane Dehydrogenation Process
  6. Oxidative Degradation of Methylene Blue in Aqueous Medium Catalyzed by Lab Prepared Nickel Hydroxide
  7. CFD Modelling of a Hollow Fibre Membrane for CO2 Removal by Aqueous Amine Solutions of MEA, DEA and MDEA
  8. Performance Study of a Thermally Double Coupled Multi-Tubular Reactor by Considering the Effect of Flow Type Patterns
  9. Radiative Three-Dimensional Flow with Chemical Reaction
  10. Three-Phase Model of a Fluidized-Bed Catalytic Reactor for Polyethylene Synthesis
  11. Study on the Effect of Nickel Doping on Mo-Bi Based Catalyst for Selective Oxidation of Isobutene to Methacrolein
  12. DM Water Plant Sedimentation as a Cheap and Waste Source of Catalyst for Biodiesel Production
  13. Recovery of Biogas from Meat Industry Wastewater Using Continuously Stirred Tank Reactor (CSTR): Modeling and Optimization
  14. Comparison of CFD Simulation and Simplified Modeling of a Fluidized Bed CO2 Capture Reactor
  15. Kinetic Study for Platinum Extraction from Spent Catalyst in Cyanide Solution at High Temperatures
  16. Hydroisomerization of Biomass Derived n-Hexadecane Towards Diesel Pool: Effect of Selective Removal External Surface Sites from Pt/ZSM-22
  17. Heat Flux and Variable Thermal Conductivity Effects on Casson Flow and Heat Transfer due to an Exponentially Stretching Sheet with Viscous Dissipation and Heat Generation
  18. Optimization of Nickel Chemical Extraction from Hazardous Residue
  19. Green Approach for Biodiesel Production from Jojoba Oil Supported by Process Modeling and Simulation
  20. Differentiating Process Performance of Various Coagulants in Removal of Congo red and Orange G Dyes
  21. CFD Simulation of Hydrodynamic of a Bubble Column Reactor Operating in Churn-Turbulent Regime and Effect of Gas Inlet Distribution on System Characteristics
  22. Transformation of Phenolic Compounds by Fe(III) in the Aqueous Solution in Dark and Under Irradiation
  23. Transient Predictive Model for Dynamic Analysis, Kinetic Study, and Reactor Design of Triglycerides Transesterification to Biodiesel
  24. Screening of Alternative Carbon Sources for Recombinant Protein Production in Pichia pastoris
  25. Optimization of a Large Scale Industrial Reactor Towards Tailor Made Polymers Using Genetic Algorithm
  26. Model of Reactive Transport within a Light Photocatalytic Textile
  27. Preparation of Chitosan based Nanofibers: Optimization and Modeling
  28. Adsorption of As (III) on Iron Coated Quartz Sand: Influence of Temperature on the Equilibrium Isotherm, Thermodynamics and Isosteric Heat of Adsorption Analysis
  29. Resistance Characteristics of Coal Slime in Pipe Flow at High Pressure
  30. Activity Comparison of Acidic Resins in the Production of Valuable Glycerol Acetates
  31. Bulk Polymerization of Styrene using Multifunctional Initiators in a Batch Reactor: A Comprehensive Mathematical Model
  32. An Effective Reaction Rate Model for Gas-Solid Reactions with High Intra-Particle Diffusion Resistance
  33. Heart-Like Micro-Flow Mixer
  34. Hydrogen Production by Hydrolysis of NaBH4 with Cr-Ni-W-B Catalyst: Effects of Cold Plasma and Chromium Content
  35. Prediction of Reactivity Ratios in Free Radical Copolymerization from Monomer Resonance–Polarity (Q–e) Parameters: Genetic Programming-Based Models
  36. Steady-State Modeling of Pt-Catalyzed H2 Combustion in a Monolithic Reactor: From Micro- to Macro-kinetics
  37. Premixed Methanol–Air Combustion Characteristics in a Mini-scale Catalytic Combustor
  38. Kinetic Modeling of VOC Photocatalytic Degradation Using a Process at Different Reactor Configurations and Scales
  39. Improvement of Activated Sludge Process Using a Nonlinear PI Controller Design via Adaptive Gain
  40. Modeling and Simulation of a Pilot-Scale Bubbling Fluidized Bed Gasifier for the Gasification of High Ash Indian Coal Using Eulerian Granular Approach
  41. Performance of a Catalytic Gas–Solid Fluidized Bed Reactor in the Presence of Interparticle Forces
  42. Mathematical Modeling of Biodiesel Production under Intense Agitation
  43. Extended Aeration Activated Sludge Reactor (EAASR) for Removal of Nitrobenzene: Air Stripped or Biologically Removed?
  44. CFD Modeling of Algae Flash Pyrolysis in the Batch Fluidized Bed Reactor Including Heat Carrier Particles
  45. A Robust Extended State Observer for the Estimation of Concentration and Kinetics in a CSTR
  46. Dynamic Modeling of CATOFIN® Fixed-Bed Iso-Butane Dehydrogenation Reactor for Operational Optimization
  47. Effect of Biomass Compositions on Combustion Kinetic Parameters using Response Surface Methodology
  48. Short Communications
  49. Discussions on Particle Flux Measurement in Gas-Solids Risers
  50. Use of New Regeneration Processes for Thermolabile Amines
  51. Oxidative-Extractive Desulfurization of Liquid Fuel by Dimethyl Sulfoxide and ZnCl2 Based Ionic Liquid
  52. Corrigendum
  53. Corrigendum to: Performance Analysis of Immobilized Enzyme Semifluidised Bed Bioreactors
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