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Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)

Published/Copyright: March 19, 2016
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Chemistry International
From the journal Chemistry International Volume 38 Issue 2

D.A. Armstrong, R.E. Huie, W.H. Koppenol, S.V. Lymar, G. Merényi, P. Neta, B. Ruscic, D. M. Stanbury, S. Steenken, and P. Wardman

Pure and Applied Chemistry 2015

Volume 87, Issue 11-12, pp. 1139-1150

Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.

http://dx.doi.org/10.1515/pac-2014-0502

Published Online: 2016-3-19
Published in Print: 2016-3-1

©2016 by Walter de Gruyter Berlin/Boston

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https://doi.org/10.1515/ci-2016-0217

Articles in the same Issue

  1. Masthead - Full issue pdf
  2. Guest Editorial
  3. Outer Limits: Pushing the Extremities
  4. Contents
  5. Officer’s Column
  6. Secretary General’s Column
  7. Features
  8. The Three-letter Element Symbols:
  9. Procedures for the Naming of a New Element
  10. The Chemical Structure Association Trust
  11. IUPAC Wire
  12. Discovery and Assignment of Elements with Atomic Numbers 113, 115, 117 and 118
  13. Open Data in a Big Data World
  14. UN Secretary General Appoints ICSU Executive Director to Special Advisory Group on the SDGs
  15. Project Place
  16. Company Associates Reengineering Project
  17. Postgraduate Course in Polymer Science, Prague, Czech Republic
  18. Critically Evaluated ESR (EPR) Spectra of Important Polymerization-related Radicals
  19. Which Elements Belong in Group 3 of the Periodic Table?
  20. Making an imPACt
  21. Discovery of the elements with atomic numbers Z = 113, 115 and 117 (IUPAC Technical Report)
  22. Discovery of the element with atomic number Z = 118 completing the 7th row of the periodic table (IUPAC Technical Report)
  23. Glossary of terms used in computational drug design, part II (IUPAC Recommendations)
  24. Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
  25. Maritime pollutants in shipping and commercial European ports based on relevant physical and biogeochemical environmental parameters (IUPAC Technical Report)
  26. Latest Updates from PAC Conferences & More—Brief
  27. IUPAC Provisional Recommendations
  28. Glossary of Terms Used in Developmental and Reproductive Toxicology
  29. How to Name Atoms in Phosphates, Polyphosphates, their Analogues, and Transition State Analogues for Enzyme-catalysed Phosphoryl Transfer Reactions
  30. Comprehensive Definition of Oxidation State
  31. Stamps International
  32. Berzelius and the Chemical Alphabet
  33. Conference Call
  34. Latin American Pesticide Residue Workshop—Food and Environment
  35. Ecological Risk Assessment
  36. Where 2B & Y
  37. New Chemistries for Phytomedicines and Crop Protection Chemicals
  38. Function Through Disorder: Intrinsically Disordered Proteins in Biology and Medicine
  39. Phosphorus Chemistry
  40. Self-assembly in the World of Polymers
  41. Solubility Phenomena
  42. Blood-Biomaterial Interactions
  43. CODATA-RDA School of Research Data Science
  44. 28th National [Turkish] Chemistry Congress with International Participation
  45. The Power of Norms
  46. Selenium Research (Se2017)
  47. Mark Your Calendar
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