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Ethanol-Enhanced Alkaline Pulping of Arundo donax L. Reed: Influence of Solvent on Pulp Yield and Quality

  • A. A. Shatalov and H. Pereira
Published/Copyright: June 1, 2005
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Holzforschung
From the journal Volume 56 Issue 5

Summary

The effect of solvent on yield and properties of ethanol-alkali pulps from Arundo donax L. was studied. Selectivity of pulping was significantly improved with increase in solvent proportion in the cooking liquor. A rise in ethanol concentration from 20 to 60% (by vol.) increased pulp yield from 44.0 to 48.9%, while decreasing residual lignin from 5.0 to 3.0%. Ethanol addition had a positive effect on preservation of carbohydrate complex against degradation in alkaline medium. Intrinsic viscosity of cellulose was improved up to 35% and xylan content increased from 8.6 to 12.1% with increase in ethanol concentration from 20 to 60%. The preservation of minor non-cellulosic polysaccharides with solvent addition was also observed. The papermaking properties of ethanol-alkali pulps were best for 20% ethanol content. An increase in solvent charge led to a drop in burst, tear and tensile pulp strength. Solvent addition assisted the conversion of glucuronic to hexenuronic acids, whereas the content of HexA in ethanol-alkali pulps of Arundo donax (about 10 μmol/g) was substantially lower than reported for kraft pulps from wood.

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Published Online: 2005-06-01
Published in Print: 2002-08-26

Copyright © 2002 by Walter de Gruyter GmbH & Co. KG

Articles in the same Issue

  1. Effect of Growth Rate on Fibre Characteristics in Norway Spruce (Picea abies (L.) Karst.)
  2. Techniques for Measuring Growth Stress on the Xylem Surface Using Strain and Dial Gauges
  3. Use of Soft Rot Cavities to Determine Microfibril Angles in Wood; Advantages, Disadvantages and Possibilities
  4. Surface Roughness and Color Change of Copper-Amine Treated Red Maple (Acer rubrum) Exposed to Artificial Ultraviolet Light
  5. Differences in Resin Acid Concentration between Brown-Rot Resistant and Susceptible Scots Pine Heartwood
  6. Antioxidant Activity of Abietane-Type Diterpenes from Heartwood of Taiwania cryptomerioides Hayata
  7. Hydrothermolysis of Flavonoids in Relation to Steaming of Japanese Larch Wood
  8. Impact of Pulping Conditions on FORMACELL Aspen Lignin: Investigation of Methoxyl and Ester Groups, Carbohydrates, Molar Mass and Glass Transition Temperatures
  9. Ethanol-Enhanced Alkaline Pulping of Arundo donax L. Reed: Influence of Solvent on Pulp Yield and Quality
  10. Reflectance FTIR Microspectroscopy for Studying Effect of Xylan Removal on Unbleached and Bleached Birch Kraft Pulps
  11. Structure of Thermally Modified Wood Studied by Liquid State NMR Measurements
  12. Detection on Incipient Fungal Attack in Wood Using Magnetic Resonance Parameter Mapping Wood Studied by Liquid State NMR Measurements
  13. Wood Density Determination by X- and Gamma-Ray Tomography
  14. The Influence of Wood Specimen Surface Coating on Moisture Movement during Drying
  15. Study of the System Wood – Coating Material. Part 2.Wood – Solid Coating Material
  16. Flake Drying Temperature Affects Mat Properties during Pressing
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