Study of the Compatibilizer Effect on Blends Prepared from Waste Poly(ethylene-terephthalate) and High Density Polyethylene
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L. Kratofil
, Z. Hrnjak-Murgić , J. Jelencć , B. Andricć , T. Kovacć and V. Merzel
Abstract
In this work mechanical recycling of waste poly(ethylene-terephthalate) (PET) in the presence of high density polyethylene (HDPE) was studied. The fraction of HDPE in PET/HDPE blends was 3, 5, 6 and 10 wt.%. Isocyanate HI compatibilizer was first synthesized and then added to the blends at a fraction of 5 wt.%. Ethylene-propylene-diene masterbatch (EPDM-M) was prepared by mixing and added in fraction of 15, 30 and 50 wt.%. All PET/HDPE blends studied were characterized by scanning electron microscopy SEM, differential scanning calorimetry DSC and melt flow rate (MFR). Blends prepared with isocyanate HI compatibilizer were also studied by FTIR spectroscopy. Appearance of new vibrations in the FTIR spectra confirms that during the blending reactions between isocyanate HI compatibilizer and blend components appear. Results show that used compatibilizers significantly improved compatibility of polymers in studied blends. From the results it is obvious that immiscibility of PET and HDPE can be overcome.
References
1 1 Scheirs, J.: Incineration of Plastic Waste with Energy Recovery in: Polymer Recycling, Science, Technology and Applications. Scheirs, J. (Ed.), John Wiley & Sons, New York (1998)Search in Google Scholar
2 2 Paul, D. R., Barlow, J. W., Keskkula, H.: Polymer Blends in: Encyclopedia of Polymer Science and Engineering. Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., (Eds.) John Wiley & Sons, New York (1985)Search in Google Scholar
3 3 Park, H. D., Park, K. O., Cho, W. J., Ha, C. S., Kwon, S. K.: Polym. Recycling2, p. 283 (1996)Search in Google Scholar
4 4 Xanthos, M.: Polym. Eng. Sci. 28, p. 1392 (1988)10.1002/pen.760282108Search in Google Scholar
22 22 Molau, G. E.: Block Copolymers. Aggarwal, S. L. (Ed.), Plenum Press, New York (1970)Search in Google Scholar
6 6 Fayt, R., Jerome, R., Teyssie, P.: J. Polym. Sci. Polym. Phys. Ed. 20, p. 2209 (1982)10.1002/pol.1982.180201204Search in Google Scholar
7 7 Demir, T., Tincer, T.: J. Appl. Polym. Sci. 79, p. 827 (2001)10.1002/1097-4628(20010131)79:5<827::AID-APP70>3.0.CO;2-4Search in Google Scholar
8 8 Stewart, M. E., George, S. E., Miller, R. L.: Polym. Eng. Sci. 33, p. 675 (1993)10.1002/pen.760331104Search in Google Scholar
9 9 Lee, P. C., Kuo, W. F., Chang, F. C.: Polymer35, p. 5641 (1994)10.1016/S0032-3861(05)80038-2Search in Google Scholar
10 10 Akkapeddi, M. K., Vanbuskirk, B.: Polym. Mater. Sci. Eng. 67, p. 317 (1992)Search in Google Scholar
11 11 Yoon, K. H., Lee, H. W., Park, O. O.: J. Appl. Polym. Sci. 70, p. 389 (1998)10.1002/(SICI)1097-4628(19981003)70:2<389::AID-APP20>3.0.CO;2-ZSearch in Google Scholar
12 12 Pawlak, A., Perkins, W. G., Massey, F. L., Hiltner, A., Baer, E.: J. Appl. Polym. Sci. 73, p. 203 (1999)10.1002/(SICI)1097-4628(19990711)73:2<203::AID-APP7>3.0.CO;2-9Search in Google Scholar
13 13 Park, S. H., Park, K. Y., Suh, K. D.: J. Appl. Polym. Sci. 36, p. 447 (1998)10.1002/(SICI)1099-0488(199802)36:3<447::AID-POLB7>3.0.CO;2-OSearch in Google Scholar
14 14 Kim, D. H., Park, K. Y., Kim, J. Y., Suh, K. D.: J. Appl. Polym. Sci. 78, p. 1017 (2000)10.1002/1097-4628(20001031)78:5<1017::AID-APP110>3.0.CO;2-6Search in Google Scholar
15 15 Pracella, M., Rolla, L., Chionna, D., Galeski, A.: Macromol. Chem. Phys. 203, p. 1473 (2002)10.1002/1521-3935(200207)203:10/11<1473::AID-MACP1473>3.0.CO;2-4Search in Google Scholar
16 16 Fox, D. W., Allen, R. B.: Compatibility, in: Encyclopedia of Polymer Science and Engineering. Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G. (Eds.), John Wiley & Sons, New York (1985)Search in Google Scholar
17 17 Dreyfuss, P., Quirk, R. P.: Graft Copolymers, in. Encyclopedia of Polymer Science and Engineering. Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G. (Eds.), John Wiley & Sons, New York (1988)Search in Google Scholar
18 18 Allen, N. S., Edge, M., Mohammadian, M., Jones, K.: Polym. Degrad. Stab. 41, p. 191 (1993)10.1016/0141-3910(93)90043-ISearch in Google Scholar
19 19 Berzin, F., Vergnes, B., Delamare, L.: J. Appl. Polym. Sci. 80, p. 1243 (2001)10.1002/app.1210Search in Google Scholar
20 20 Rosales, C., Perere, R., Ichazo, M., Gonzalez, J., Rojas, H., Sanchez, A., Barrias, A. D.: J. Appl. Polym. Sci. 70, p. 161 (1998)10.1002/(SICI)1097-4628(19981003)70:1<161::AID-APP16>3.0.CO;2-ASearch in Google Scholar
21 21 Grassie, N., Bain, D. R.: J. Polym. Sci. Part I8, p. 2653 (1970)10.1002/pol.1970.150080930Search in Google Scholar
22 22 Hrnjak-Murgić, Z., Kratofil, L., Jelčvic, Ž., Jelenčic, J., Janović, Z.: Int. Polym. Process. 19, p. 139 (2004)10.3139/217.1817Search in Google Scholar
23 23 Brandrup, I., Immergut, E. H.: Polymer Handbook, John Wiley & Sons, New York (1975)Search in Google Scholar
24 24 Pluta, M., Bartczak, Z., Pawlak, A., Galeski, A., Pracella, A.: J. Appl. Polym. Sci. 82, p. 1423 (2001)10.1002/app.1980Search in Google Scholar
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Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- New Multicomponent Compatibilization System for Polyolefin/Polystyrene Blends
- Preparation and Characterization of HMW PA 6 via Anionic Polymerization of ∊-Caprolactam by Using a Mixture of Di- and Tri-functional Chain Initiators
- Polymer Processing Extrusion Instabilities and Methods for their Elimination or Minimisation
- Microcellular Wood Fibre Reinforced PP Composites
- Effects of Take-up Speed of Melt Spinning on the Structure and Mechanical Propertiesof Maximally Laser Drawn PA9-T Fibers
- Description of the Pressure/Throughput Behavior of a Single-screw Plasticating Unit in Consideration of Wall Slippage Effects for Non-Newtonian Material and 1-D flow
- Study of Starch Gelatinization in a Flow Field Using Simultaneous Rheometric Data Collection and Microscopic Observation
- Analysis of the Residual Stresses in the Process of Nanoimprint Lithography
- The Reactive Extrusion of Thermoplastic Polyurethane and the Effect of the Depolymerization Reaction
- Simulation of Core Deflection in Powder Injection Molding
- Experimental Investigation of the Cooling Flow in the Film Blowing Process
- Study of the Compatibilizer Effect on Blends Prepared from Waste Poly(ethylene-terephthalate) and High Density Polyethylene
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- New Multicomponent Compatibilization System for Polyolefin/Polystyrene Blends
- Preparation and Characterization of HMW PA 6 via Anionic Polymerization of ∊-Caprolactam by Using a Mixture of Di- and Tri-functional Chain Initiators
- Polymer Processing Extrusion Instabilities and Methods for their Elimination or Minimisation
- Microcellular Wood Fibre Reinforced PP Composites
- Effects of Take-up Speed of Melt Spinning on the Structure and Mechanical Propertiesof Maximally Laser Drawn PA9-T Fibers
- Description of the Pressure/Throughput Behavior of a Single-screw Plasticating Unit in Consideration of Wall Slippage Effects for Non-Newtonian Material and 1-D flow
- Study of Starch Gelatinization in a Flow Field Using Simultaneous Rheometric Data Collection and Microscopic Observation
- Analysis of the Residual Stresses in the Process of Nanoimprint Lithography
- The Reactive Extrusion of Thermoplastic Polyurethane and the Effect of the Depolymerization Reaction
- Simulation of Core Deflection in Powder Injection Molding
- Experimental Investigation of the Cooling Flow in the Film Blowing Process
- Study of the Compatibilizer Effect on Blends Prepared from Waste Poly(ethylene-terephthalate) and High Density Polyethylene
- PPS News
- PPS News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts