Home Physical Sciences Effects of Take-up Speed of Melt Spinning on the Structure and Mechanical Propertiesof Maximally Laser Drawn PA9-T Fibers
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Effects of Take-up Speed of Melt Spinning on the Structure and Mechanical Propertiesof Maximally Laser Drawn PA9-T Fibers

  • A. J. Uddin , Y. Ohkoshi , Y. Gotoh , M. Nagura , R. Endo and T. Hara
Published/Copyright: March 26, 2013
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International Polymer Processing
From the journal International Polymer Processing Volume 21 Issue 3

Abstract

A new semiaromatic polyamide, PA9-T, was melt-spun at take-up speeds from 200 to 1000m min−1. The as-spun fibers were drawn with CO2 laser-heated drawing to their maximal draw ratio (DRmax). The drawing stress was recorded during this process. The effects of take-up speed of melt-spinning on maximally drawn fibers were characterized through measurements of density, birefringence, wide-angle X-ray diffraction, crystal orientation, tensile testing, and dynamic viscoelastic analysis. All as-spun fibers were essentially amorphous and their birefringence and density increased slightly with the increase of take-up speed. Lower take-up speeds yielded higher DRmax values, and fibers drawn to their DRmax exhibited superior structure and mechanical properties. The tensile strength and Young's modulus achieved were the highest reported to date for PA9-T: 737 MPa and 5.8 GPa, respectively.

∗ Mail address: Y. Ohkoshi, Faculty of Textile Science & Technology, Shinshu University, Ueda 386-8567, Nagano, Japan. E-mail:

References

1 1 Espero, J. F., Ferrenro, E., Campa, J. G. D. L., Lozano, A. E., Abajo, J. D.: J. Polym. Sci. Part A, 39, p. 475 (2001)10.1002/1099-0518(20010215)39:4<475::AID-POLA1016>3.0.CO;2-ISearch in Google Scholar

2 2 Espero, J. F., Campa, J. G. D. L., Lozano, A. E., Abajo, J. D.: J. Polym. Sci. Part A, 38, p. 1014 (2000)10.1002/(SICI)1099-0518(20000315)38:6<1014::AID-POLA11>3.0.CO;2-HSearch in Google Scholar

3 3 Lozano, A. E., de Abajo, J., de la Campa, J. G., Preston, J.: J. Polym. Sci. Part A, 30, p. 1327 (1992)10.1002/pola.1992.080300710Search in Google Scholar

4 4 Yang, C. P., Lin, J. H.: J. Polym. Sci. Part A, 31, p. 2153 (1993)10.1002/pola.1993.080310821Search in Google Scholar

5 5 Mikroyannidis, J. A.: Polymer37, p. 2715 (1996)10.1016/0032-3861(96)87633-6Search in Google Scholar

6 6 Liaw, D. J., Liaw, B. Y., Chung, C. Y.: Macromol. Chem. Phys. 200, p. 1023 (1999)10.1002/(SICI)1521-3935(19990501)200:5<1023::AID-MACP1023>3.0.CO;2-1Search in Google Scholar

7 7 Lee, C. J., Park, S. K., Kim, S. Y., Lee, J., Min, B. G., Son, T. W., Kim, B. C.: Polym. Int. 36, p. 203 (1995)10.1002/pi.1995.210360211Search in Google Scholar

8 8 Jeong, H. J., Oishi, Y., Kakimoto, M. A., Imai, Y.: J. Polym. Sci. Part A, 28, p. 3293 (1990)10.1002/pola.1990.080281209Search in Google Scholar

9 9 Spiliopoulos, I. K., Mikroyannidis, J.: Macromolecules31, p. 515 (1998)10.1021/ma970490oSearch in Google Scholar

10 10 Hsiao, S. H., Chang, H. Y.: J. Poly. Sci. Part A, 34, p. 1421 (1996)10.1002/(SICI)1099-0518(199606)34:8<1421::AID-POLA5>3.0.CO;2-2Search in Google Scholar

11 11 Liaw, D. J., Liaw, B. Y., Su, K. L.: J. Polym. Sci. Part A, 37, p. 1997 (1999)10.1002/(SICI)1099-0518(19990701)37:13<1997::AID-POLA13>3.0.CO;2-GSearch in Google Scholar

12 12 Chiriac, C., Stille, J. K.: Macromolecules10, p. 712 (1997)10.1021/ma60057a045Search in Google Scholar

13 13 Bellomo, M. R., Di Pasquale, G., La Rosa, A., Policino, A., Siracusa, G.: Polymer37, p. 2877 (1996)10.1016/0032-3861(96)87654-3Search in Google Scholar

14 14 Lucas, M., Broke, P., Hedrich, J. L.: J. Polym. Sci. Part A, 31, p. 2179 (1993)10.1002/pola.1993.080310901Search in Google Scholar

15 15 Kuraray's home page: http://www.kuraray.co.jp/en/press/pa9t_e/pa9t_e.htmlSearch in Google Scholar

16 16 Uddin, A. J., Gotoh, Y., Ohkoshi, Y., Nagura, M., Hara, T.: J. Polym. Sci. Part B, 43, p. 1640 (2005)10.1002/polb.20446Search in Google Scholar

17 17 Nikkei Net Newspaper Bulletin http://www.nikkei.co.jp/news/sangyo/20031109AT1D0800E08112003.html Search in Google Scholar

18 18 Uddin, A. J., Ohkoshi, Y., Gotoh, Y., Nagura, M., Endo, R., Hara, T.: J. Polym. Sci. Part B, 42, p. 433 (2004)10.1002/polb.10710Search in Google Scholar

19 19 Jpn. Tokkyo Koho, S41–7892Search in Google Scholar

20 20 Ohkoshi Y. , Watanabe, J., Gotoh, Y., Nagura, M.: Sen'i Gakkaishi58, p. 182 (2002)10.2115/fiber.58.182Search in Google Scholar

21 21 Ikaga, T., Kobayashi, A., Ohkoshi, Y., Gotoh, Y., Nagura, M., Urakawa, H., Kajiwara, K.: Sen'i Gakkaishi58, p. 8 (2002)10.2115/fiber.58.8Search in Google Scholar

22 22 Ikaga, T., Kobayashi, A., Ohkoshi, Y., Gotoh, Y., Nagura, M.: Sen'i Gakkaishi58, p. 16 (2002)10.2115/fiber.58.16Search in Google Scholar

23 23 Suzuki, A., Mochiduki, M.: J. Appl. Polym. Sci. 82, p. 2775 (2001)10.1002/app.2131Search in Google Scholar

24 24 Okumura, W., Kanegae, T., Ohkoshi, Y., Gotoh, Y., Nagura, M.: Int. Polym. Process. 18, p. 46 (2003)10.3139/217.1717Search in Google Scholar

25 25 Ikaga, T., Ohkoshi, Y., Gotoh, Y., Nagura, M., Kawahara, Y.: Sen'i Gakkaishi59, p. 235 (2003)10.2115/fiber.59.235Search in Google Scholar

26 26 Suzuki, A., Ishihara, M.: J. Appl. Polym. Sci. 83, p. 1711 (2002)10.1002/app.10094Search in Google Scholar

27 27 Okumura, W., Ohkoshi, Y., Gotoh, Y., Nagura, M., Urakawa, H., Kajiwara, K.: J. Polym. Sci. Part B42, p. 79 (2004)10.1002/polb.10673Search in Google Scholar

28 28 Suzuki, A., Mochizuki, N.: J. Appl. Polym. Sci. 88, p. 3279 (2003)10.1002/app.12152Search in Google Scholar

29 29 Okumura, W., Yamaguchi, T., Ohkoshi, Y., Gotoh, Y., Nagura, M.: Int. Polym. Process. 17, p. 124 (2002)10.3139/217.1684Search in Google Scholar

30 30 Heuvel, H. M., Huisman, R., Lind, K. C. J. B.: J. Polym. Sci. Part B, 14, p. 921 (1976)10.1002/pol.1976.180140514Search in Google Scholar

31 31 Ruland, W., Tompa, H.: Acta Crystallogr. Section A, 24, p. 93 (1968)10.1107/S0567739468000112Search in Google Scholar

32 32 Murase, Y.: Sen'i Gakkaishi47, p. 564 (1991)10.2115/fiber.47.10_P564Search in Google Scholar

33 33 Mezghani, K., Spruiell, J. E.: J. Polym. Sci. Part B, 36, p. 1005 (1998)10.1002/(SICI)1099-0488(19980430)36:6<1005::AID-POLB9>3.0.CO;2-VSearch in Google Scholar

34 34 Wu, G., Li, H., Wu, Y., Cuculo, J. A.: Polymer43, p. 4915 (2002)10.1016/S0032-3861(02)00306-3Search in Google Scholar

35 35 Cuculo, J. A., Tucker, P. A., Chen, G. Y.: Appl. Polym. Sci. Appl. Polym. Symp. 47, p. 223 (1991)10.1002/app.1991.070470015Search in Google Scholar

36 36 Vasanthan, N., Ruetsch, S. B., Salem, D. R.: J. Polym. Sci. Part B, 40, p. 1940 (2002)10.1002/polb.10247Search in Google Scholar

37 37 Murase, S., Kashima, K., Kudo, K., Hirami, M.: Macromol. Chem. Phys. 198, p. 561 (1997)10.1002/macp.1997.021980228Search in Google Scholar

38 38 Hamana, I., Matsui, M., Kato, S.: Melliand Textilber4, p. 382 (1969), 5, p. 499 (1969)Search in Google Scholar

39 39 Suzuki, A., Murata, H., Kunugi, T.: Polymer39, p. 1351 (1997)10.1016/S0032-3861(97)00430-8Search in Google Scholar

40 40 Sen'i Binran, Society of Fiber Science & Technology, Maruzer, Japan, 2nd ed., p. 11 (1994)Search in Google Scholar

41 41 Sen'i Binran, Society of Fiber Science & Technology, Maruzer, Japan, 2nd ed., p. 187 (1994)Search in Google Scholar

42 42 Suzuki, A., Kawada, T., Hasegawa, T.: J. Polym. Sci. Part B, 39, p. 1629 (2001)10.1002/polb.1134Search in Google Scholar

43 43 Uddin, A. J., Ohkoshi, Y., Gotoh, Y., Nagura, M., Hara, T.: J. Polym. Sci. Part B, 41, p. 2878 (2003)10.1002/polb.10602Search in Google Scholar
Received: 2005-07-14
Accepted: 2006-01-08
Published Online: 2013-03-26
Published in Print: 2006-07-01

© 2006, Hanser Publishers, Munich

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https://doi.org/10.3139/217.0090

Articles in the same Issue

  1. Contents
  2. Contents
  3. Regular Contributed Articles
  4. New Multicomponent Compatibilization System for Polyolefin/Polystyrene Blends
  5. Preparation and Characterization of HMW PA 6 via Anionic Polymerization of ∊-Caprolactam by Using a Mixture of Di- and Tri-functional Chain Initiators
  6. Polymer Processing Extrusion Instabilities and Methods for their Elimination or Minimisation
  7. Microcellular Wood Fibre Reinforced PP Composites
  8. Effects of Take-up Speed of Melt Spinning on the Structure and Mechanical Propertiesof Maximally Laser Drawn PA9-T Fibers
  9. Description of the Pressure/Throughput Behavior of a Single-screw Plasticating Unit in Consideration of Wall Slippage Effects for Non-Newtonian Material and 1-D flow
  10. Study of Starch Gelatinization in a Flow Field Using Simultaneous Rheometric Data Collection and Microscopic Observation
  11. Analysis of the Residual Stresses in the Process of Nanoimprint Lithography
  12. The Reactive Extrusion of Thermoplastic Polyurethane and the Effect of the Depolymerization Reaction
  13. Simulation of Core Deflection in Powder Injection Molding
  14. Experimental Investigation of the Cooling Flow in the Film Blowing Process
  15. Study of the Compatibilizer Effect on Blends Prepared from Waste Poly(ethylene-terephthalate) and High Density Polyethylene
  16. PPS News
  17. PPS News
  18. Seikei-Kakou Abstracts
  19. Seikei-Kakou Abstracts
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