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A kinetic study of nickel coating on boron nitride micro-particles

  • Fan Li , Dengjun Zhang and Du Sichen
Published/Copyright: May 23, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 98 Issue 6

Abstract

In the present work, the mechanism of nickel coating on BN particles by hydrazine reduction was studied. A nickel sulfate – ammonium sulfate – ammonia – hydrazine hydrate plating system was employed. It was found that Pd on the surface of BN particles acted as an active center for nickel deposition at the initial stage of the process. Thereafter, Ni itself would act as an active center to catch Ni from the solution through the reaction: Ni2+ + 2H*ad ß Ni + 2H+. The rate of the process was found to be controlled by the reaction at the interface under the present experimental conditions. A kinetic model was proposed on the basis of the experimental results. The model predictions were found to be in agreement with the experimental data.

Keywords: Nickel coated BN particle; Kinetics; Chemical plating; Model
* Correspondence address, Prof. Du Sichen, Department of Material Science and Engineering, Royal Institute of technology, Brinellvägen 23, SE 10044, Stockholm, Sweden, Tel.: +46 8 790 8359, Fax: +46 8 790 0939, E-mail:

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Received: 2006-10-6
Accepted: 2007-2-23
Published Online: 2013-05-23
Published in Print: 2007-06-01

© 2007, Carl Hanser Verlag, München

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https://doi.org/10.3139/146.101501
Keywords for this article
Nickel coated BN particle; Kinetics; Chemical plating; Model

Articles in the same Issue

  1. Contents
  2. Contents
  3. Basic
  4. The effect of bismuth segregation on the faceting of Σ3 and Σ9 coincidence boundaries in copper bicrystals
  5. Viscosity measurement of liquid ternary Cu–Ni–Fe alloys by an oscillating cup viscometer and comparison with models
  6. Isothermal oxidation behavior of a precipitation-hardened Pt-base alloy with additions of Al, Cr and Ni
  7. Bismuth activity measurements and thermodynamic re-optimization of the Ni–Bi System
  8. Modelling of the β → α + β transformation in a metastable β Ti alloy based on the growth kinetics and the morphology of the α plates
  9. The microstructure of ball milled nanocrystalline vanadium; variation of the crystal imperfection and the lattice parameter
  10. Study of interfacial reactions between Sn–Ag–Cu alloys and Au substrate
  11. Applied
  12. On the precipitation processes in commercial QE22 magnesium alloy
  13. Cyclic deformation behavior of deep rolled as-quenched aluminium alloy AA6110 at elevated temperatures
  14. Effect of Ho additions on the microstructure and mechanical properties of Nb-22Ti-16Si-7Cr-3Al-3Ta-2Hf alloys
  15. Improved mechanical properties of the high pressure die casting alloy AlSi9Cu3(Fe)(Zn) as a result of the combination of natural and artificial ageing
  16. Effect of quenching temperature on the microstructure and mechanical properties of Fe–B–Ti alloy
  17. A kinetic study of nickel coating on boron nitride micro-particles
  18. Thermal diffusivity measurements of some industrially important alloys by a laser flash method
  19. Notifications
  20. DGM News
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