Effect of Some Vitamins of Group B (B1, B6, B12) on Micellar and Viscosity Properties of Anionic, Cationic and Nonionic Surfactants in Aqueous Solutions

Lusine R. Harutyunyan; Martina L. Lachinyan; Romik S. Harutyunyan

doi:10.3139/113.110513

Enjoy 40% off

academic books on De Gruyter Brill *

Article

Effect of Some Vitamins of Group B (B₁, B₆, B₁₂) on Micellar and Viscosity Properties of Anionic, Cationic and Nonionic Surfactants in Aqueous Solutions

Lusine R. Harutyunyan , Martina L. Lachinyan and Romik S. Harutyunyan

Published/Copyright: September 6, 2017

Published by

Become an author with De Gruyter Brill

Author Information

From the journal Tenside Surfactants Detergents Volume 54 Issue 5

Abstract

The influence of vitamins B₁ (thiamine hydrochloride), B₆ (pyridoxine) and B₁₂ (cyanocobalamine) on the micellization, surface activity and viscometric behavior of anionic surfactant sodium dodecylsulfate, cationic surfactant cetylpyridinium bromide and nonionic surfactant hexadecylpoly[oxyethylene(20)] alcohol at different temperatures was studied. The critical micelle concentration, the micellization thermodynamics, the maximum adsorption density, the standard free energy of adsorption and the other micellar parameters of surfactants in the presence of vitamins B₁, B₆ and B₁₂ were obtained. On the basis of dependence of the relative viscosities on concentration, the viscosity B-coefficients of the Jones-Dole semiempirical equation were calculated for both premicellar and postmicellar regions. The results of our study allowed the conclusion that vitamins B₁, B₆ and B₁₂ are solubilized in micelles.

Kurzfassung

Der Einfluss der Vitamine B₁ (Thiaminhydrochlorid), B₆ (Pyridoxin) und B₁₂ (Cyanocobalamin) auf die Mizellenbildung, die Oberflächenaktivität und das viskose Verhalten des anionischen Tensids Natriumdodecylsulfat, des kationischen Tensids Cetylpyridiniumbromid und des nichtionischen Tensids Hexadecylpoly(oxyethylen (20))alkohol wurde bei verschiedenen Temperaturen untersucht. Die kritische Mizellenbildungskonzentration, die Thermodynamik der Mizellenbildung, die maximale Adsorptionsdichte, die freie Gibbs-Adsorptionsenergie und die anderen mizellaren Parameter von Tensiden wurden in Gegenwart der Vitamine B₁, B₆ und B₁₂ erhalten. Auf der Grundlage der Abhängigkeit der relativen Viskositäten von der Konzentration wurden die Viskositätskoeffizienten der semiempirischen Jones-Dole- Gleichung sowohl für den prämmizellaren als auch für den postmizellaren Bereich berechnet. Die Ergebnisse unserer Studie erlaubten den Schluss, dass die Vitamine B₁, B₆ und B₁₂ in Micellen solubilisiert sind.

Key words: Vitamins of group B; surfactant; micellization; surface activity; Jones-Dole equation

Stichwörter: Vitamine der B-Gruppe; Tenside; Mizellenbildung; Oberflächenaktivität; Jones-Dole-Gleichung

*Correspondence address, Mrs. Dr. Lusine R. Harutyunyan, Department of Chemistry, Yerevan State University, Manukyan 1, 0025 Yerevan, Armenia, Tel.: (+374)93519144, E-Mail: lusinehar@ysu.am

Lusine R. Harutyunyan earned her M. Sc. and Ph. D. degree from Yerevan State University, Armenia. Now she is an Associate Professor in the Chair of Inorganic and Analytical Chemistry, Faculty of Pharmacy and Chemistry, Yerevan State University, Armenia. Her research fields are colloid chemistry, chemistry of surfactant solutions, and purification of water from surfactants.

Martina L. Lachinyan earned her M. Sc. and Ph. D. degree from Yerevan State University, Armenia. She is researcher in Department of Chemistry in Yerevan State University.

Prof. Romik S. Harutyunyan is Head of Chair of Inorganic and Analytical Chemistry, Faculty of Pharmacy and Chemistry, Yerevan State University, Armenia. His main areas of research include the physico-chemical properties of surfactant solutions, micellar catalysis, synthesis and properties of surfactant-modified sorbents.

References

1. Kundu, A. and Kishore, N.: Apparent molar heat capacities and apparent molar volumes of aqueous nicotinamide at different temperatures. J. Solut. Chem.32 (2003) 703–717. 10.1023/B:JOSL.0000002990.73945.c9Search in Google Scholar

2. Banipal, T. S., Singh, H., Banipal, P. K. and Singh, V.: Volumetric and viscometric studies on L-ascorbic acid, nicotinic acid, thiamine hydrochloride and pyridoxine hydrochloride in water at temperatures (288.15–318.15) K and at atmospheric pressure.Thermochim. Acta553 (2013) 31–39. 10.1016/j.tca.2012.10.017Search in Google Scholar

3. Kharkevich, D. A.: Pharmacology, Geotar-Media, Moscow (2005).Search in Google Scholar

4. Shilov, P. A. and YakovlevP.I.: Basics of Clinical Vitaminology, Medicina, Leningrad (1974).Search in Google Scholar

5. Knyazev, A. V., Smirnova, N. N., Plesovskikh, A. S., Shushanov, A. N. and Knyazeva, S. S.: Low-temperature heat capacity and thermodynamic functions of vitamin B₁₂.Thermochim. Acta582 (2014) 35–39. 10.1016/j.tca.2014.02.025Search in Google Scholar

6. Knyazev, A. V., Letyanina, I. A., Plesovskikh, A. S., Smirnova, N. N. and Knyazeva, S. S.: Thermodynamic properties of vitamin B₂.Thermochim. Acta575 (2014) 12–16. 10.1016/j.tca.2013.09.032Search in Google Scholar

7. Harutyunyan, L. R., Lachinyan, M. L. and Harutyunyan, R. S.: Effect of ascorbic acid on the colloidal and micellar properties of anionic, cationic and nonionic surfactants: conductivity, volumetric, viscometric and fluorescence study. J. Chem. Eng. Data58 (2013) 2998–3008. 10.1021/je400667cSearch in Google Scholar

8. Harutyunyan, L. R., Lachinyan, M. L. and Harutyunyan, R. S.: Effect of nicotinic acid on micellization and viscosity of surfactants in aqueous solutions. Colloid J.77 (2015) 404–408. 10.1134/S1061933X15040031Search in Google Scholar

9. Harutyunyan, L. R.: The effect of vitamin E on micellization of sodium pentadecylsulfonate in ethanol solutions. Colloid J.76 (2014) 372–375. 10.1134/S1061933X14030028Search in Google Scholar

10. Harutyunyan, L. R., Lachinyan, M. L., Vardanyan, R. L. and Harutyunyan, R. S.: Effect of surfactants on ascorbic acid and nicotinic acid atmospheric oxidation kinetics. Proceedings of YSU (Chemistry and Biology)1 (2016) 3–9.Search in Google Scholar

11. Zdziennicka, A., Szymczyk, K., Krawczyk, J. and Jańczuk, B.: Critical micelle concentration of some surfactants and thermodynamic parameters of their micellization.Fluid Phase Equil.322–323 (2012) 126–134. 10.1016/j.fluid.2012.03.018Search in Google Scholar

12. Umlong, I. M. and Ismail, K.: Micellization behaviour of sodium dodecyl sulfate in different electrolyte media. Colloids Surf. A: Physicochem. Eng. Asp.299 (2007) 8–14. 10.1016/j.colsurfa.2006.11.010Search in Google Scholar

13. Bakshi, M. S. and Kaur, G.: Mixed micelles of hexadecylpyridinium bromide + tetradecyltrimethylammonium bromide in aqueous glycol oligomers. J. Surf. Deterg.3 (2000) 159–166. 10.1007/s11743-000-0120-5Search in Google Scholar

14. Rakshit, A. K. and Sharma, B.: The effect of amino acids on the surface and thermodynamic properties of poly[oxyethlene(10)] lauryl ether in aqueous solution.Colloid Polym. Sci.281 (2003) 45–51. 10.1007/s00396-002-0743-7Search in Google Scholar

15. Mehta, S. K., Chaudhary, S., Bhasin, K. K., Kumar, R. and Aratono, M.: Conductometric and spectroscopic studies of sodium dodecyl sulfate in aqueous media in the presence of organic chalcogen. Colloid Surf. A: Physicochem. Eng. Asp.304 (2007) 88–95. 10.1016/j.colsurfa.2007.04.031Search in Google Scholar

16. Dubey, N.: A Conductometric study of interaction between sodium dodecyl sulfate and 1-propanol, 1-butanol and 1-hexanol at different temperatures.J. Surf. Sci. Technol.24 (2008) 139–148.Search in Google Scholar

17. Graciani, M., Munoz, M., Rodriguez, A. and Moya, M. L.: Water–N,N-dimethylformamide alkyltrimethylammonium bromide micellar solutions: thermodynamic, structural, and kinetic studies. Langmuir21 (2005) 3303–3310. PMid:15807568; 10.1021/la046833aSearch in Google Scholar

18. Chauhan, M. S., Kumar, G., Kumar, A., Sharma, K. and Chauhan, S.: Conductance and viscosity studies of sodium dodecylsulfate in aqueous solutions of dimethylsulfoxide and methanol. Colloids and Surfaces A: Physicochem.Eng. Aspects180 (2001) 111–119. 10.1016/S0927-7757(00)00761-5Search in Google Scholar

19. Harutyunyan, L. R. and Markarian, S. A.: Effect of dimethylsulfoxide and diethylsulfoxide on micellization and viscometric properties of cetylpyridinium bromide aqueous solutions. J. Molec. Liq.160 (2011) 136–139. 10.1016/j.molliq.2011.03.010Search in Google Scholar

20. Roy, M. N., Das, R. K. and Bhattacharjee, A.: Apparent molar volume, viscosity B-coefficient and adiabatic compressibility of tetrabutylammonium bromide in aqueous ascorbic acid solutions at T = 298.15, 308.15 and 318.15 K.Russ. J. Physical Chem. A84 (2010) 2201–2210. 10.1134/S0036024410130017Search in Google Scholar

21. Chauhan, M. S., Kumar, G., Kumar, A. and Chauhan, S.: Micellization of ionic surfactants in aqueous-rich region of organic solvents: a conductometric study of micellization behaviour of sodium dodecylsulfate in aqueous-rich region of 1-BuOH, 2-BuOH, t-BuOH at different temperatures.Colloid Surf A: Physicochem. Eng. Asp.166 (2000) 51–57. 10.1016/S0927-7757(99)00460-4Search in Google Scholar

22. Turner, D., Gracie, K., Taylor, T. and Palepu, R.: Micellar and thermodynamic properties of sodium dodecyl sulfate in binary aqueous solutions of di-, tri-, and tetraethylene glycols. J. Colloid Interface Sci.202 (1998) 359–368. 10.1006/jcis.1998.5484Search in Google Scholar

23. Bales, B. L.: A definition of the degree of ionization of a micelle based on its aggregation number. J. Phys. Chem. B105 (2001) 6798–6804. 10.1021/jp004576mSearch in Google Scholar

24. Zana, R.: Critical micellization concentration of surfactants in aqueous solution and free energy of micellization. Langmuir12 (1996) 1208–1211. 10.1021/la950691qSearch in Google Scholar

25. Hoeiland, H. K. S. and Blokhus, A. M.: Handbook of Surface and Colloid Chemistry, 3rd ed., Taylor and Frances Group, LLC, London (2009).Search in Google Scholar

26. Bakshi, M. S.: How surfactants control crystal growth of nanomaterials. Cryst. Growth Des.16 (2016) 1104–1133. 10.1021/acs.cgd.5b01465Search in Google Scholar

27. Myers, D.: Surfactants Science and Technology, 2nd ed., VCH, New York (1992).Search in Google Scholar

28. Zdziennicka, A., Szymczyk, K., Krawczyk, J. and Jańczuk, B.: Activity and thermodynamic parameters of some surfactants adsorption at the water-air interface. Fluid Phase Equil.318 (2012) 25–33. 10.1016/j.fluid.2012.01.014Search in Google Scholar

29. Ali, A., Farooq, U., Uzair, S. and Patel, R.: Conductometric and tensiometric studies on the mixed micellar systems of surface-active ionic liquid and cationic surfactants in aqueous medium. J. Mol. Liq.223 (2016) 589–602. 10.1016/j.molliq.2016.08.082Search in Google Scholar

30. Siddiqui, H., Kamal, M. and Fatima, N.: Surface and solution properties of single and mixed gemini/conventional micelles on solubilization of polycyclic aromatic hydrocarbons. Indian J. Chem. Technol.22 (2015) 194–200.Search in Google Scholar

31. Jones, G. and Dole, M.: The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride, J. Am. Chem. Soc.51 (1929) 2950–2960. 10.1021/ja01385a012Search in Google Scholar

32. Falkenhagen, H. and Dole, M.: Die innere reibung von elektrolytis-chen und ihre deutung nach der debeschen theorie. Z. Physik30 (1992) 611–622.Search in Google Scholar

33. Stokes, R. H. and Mills, R.: Viscosity of Electrolytes and Related Properties, Aus der Series “The International Encyclopedia of Physical Chemistry and Chemical Physics”, Pergamon Press, New York, 1965.Search in Google Scholar

34. Erdey-Gruz, T.: Transport Phenomena in Aqueous Solutions.Akademiai Kiado, Budapest (1974).Search in Google Scholar

35. Feakins, D., Freemantle, D. J. and Lawrence, K. G.: Transition state treatment of the relative viscosity of electrolytic solutions. Applications to aqueous, non-aqueous and methanol+water systems, J. Chem. Soc. Faraday Trans.70 (1974) 795806. 10.1039/F19747000795Search in Google Scholar

36. Feakins, D., Bates, F. M., Waghorne, W. E. and Lawrence, K. G.: Relative viscosities and quasi-thermodynamics of solutions of tert-butyl alcohol in the methanol-water systems, J. Chem. Soc. Faraday Trans.89 (1993) 3381–3388. 10.1039/FT9938903381Search in Google Scholar

Received: 2017-01-27

Accepted: 2017-04-17

Published Online: 2017-09-06

Published in Print: 2017-09-15

You are currently not able to access this content.

Articles in the same Issue

https://doi.org/10.3139/113.110513

Keywords for this article

Vitamins of group B; surfactant; micellization; surface activity; Jones-Dole equation