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Synthesis and catalytic performance of MCM-41 modified with tetracarboxylphthalocyanine

  • Ya-Ping Zhang EMAIL logo , Ke-Chuang Xue , Wei-Ping Zhang , Chao Song , Rong-Lan Zhang and Jian-She Zhao
Published/Copyright: January 9, 2013
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Chemical Papers
From the journal Chemical Papers Volume 67 Issue 4

Abstract

A series of tetracarboxylphthalocyanines (MPc(COOH)4, M = H, Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II)) were anchored onto MCM-41 by the following procedures: functionalization of MCM-41 with (EtO)3SiCH2CH2CH2NH2 reacting with surface Si-OH, and anchoring MPc(COOH)4 onto MCM-41 with a substitution reaction between chloroformyl and amino groups. The samples were characterized by infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, N2 adsorption-desorption, and X-ray photoelectron spectroscopy. Catalytic activity of oxidation was tested using solutions of ethanethiol in petroleum ether and thiophene in octane; CoPc-CONH-MCM-41 displayed the highest conversion ratio of 90.15 % and 93.79 %, respectively.

Keywords: anchoring; tetracarboxylphthalocyanine; MCM-41; catalytic oxidation

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Published Online: 2013-1-9
Published in Print: 2013-4-1

© 2012 Institute of Chemistry, Slovak Academy of Sciences

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  1. Identification of carbohydrate isomers in flavonoid glycosides after hydrolysis by hydrophilic interaction chromatography
  2. Preparation of a new metallomicelle catalyst for the hydrolysis of bis(4-nitrophenyl) phosphate
  3. Synthesis and catalytic performance of MCM-41 modified with tetracarboxylphthalocyanine
  4. Comparison of polymeric and ceramic membranes performance in the process of micellar enhanced ultrafiltration of cadmium(II) ions from aqueous solutions
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https://doi.org/10.2478/s11696-012-0288-2
Keywords for this article
anchoring; tetracarboxylphthalocyanine; MCM-41; catalytic oxidation

Articles in the same Issue

  1. Identification of carbohydrate isomers in flavonoid glycosides after hydrolysis by hydrophilic interaction chromatography
  2. Preparation of a new metallomicelle catalyst for the hydrolysis of bis(4-nitrophenyl) phosphate
  3. Synthesis and catalytic performance of MCM-41 modified with tetracarboxylphthalocyanine
  4. Comparison of polymeric and ceramic membranes performance in the process of micellar enhanced ultrafiltration of cadmium(II) ions from aqueous solutions
  5. Pertraction of cadmium and zinc ions using a supported liquid membrane impregnated with different carriers
  6. Effect of lentil and bean flours on rheological and baking properties of wheat dough
  7. Preparation, structural characterisation, and magnetic properties of [Cu(men)2][Cu2Cd2Cl2(CN)6] (men = N-methylethane-1,2-diamine)
  8. Structure and properties of 2-[(E)-2-(4-dipropylaminophenyl)-1-ethenyl]-1,3,3-trimethyl-3H-indolium chloride
  9. Properties of water-soluble carboxymethyl chitosan film modified by hydrophobic poly(propylene glycol)
  10. Characterisation of hydroxyapatite surface modified by poly(ethylene glycol) and poly(hydroxyethyl methacrylate) grafting
  11. Synthesis and keto-enol tautomerism of ethyl 4-oxo-3,4-dihydro-1H-pyrano[3,4-b]quinoline-3-carboxylate
  12. An efficient method for the preparation of benzyl γ-ketohexanoates
  13. Micelle nano-reactors as mediators of water-insoluble ligand complexation with Cu(II) ions in aqueous medium
  14. Reactivity of base catalysed hydrolysis of 2-pyridinylmethylene-8-quinolinyl-Schiff base iron(II) iodide complexes: solvent effects
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