Crystal structure and spectra of bis[p-chloro-benzoyl-di-(2-pyridyl)ketonohydrazono]uranyl
Abstract
The crystal structure of the title compound, (C18H12ClN4O2)2U, has been determined from three-dimensional X-ray diffraction data. The structure is monoclinic, space group P21/c, with a = 7.545(1), b = 19.890(1), c = 12.210(1) Å, β = 110.66(1)°, V = 1714.52 Å3 and Z = 2. The structure was solved by direct methods and refined by least-squares to a final R = 0.025 (Rw = 0.027, Rg = 0.036). The uranium atom lies on a crystallographic symmetry center, while the tridentate organic ligand binds equatorially to the uranyl ion, UO22+, leading to eight-coordinated uranium in a distorted hexagonal bipyramidal coordination geometry. Selected bond lengths: U – O(uranyl) 1.764(5) Å, U – O(ligand) 2.364(4) Å, U – N 2.634(5) – 2.702(5) Å. The crystal cohesion is due to normal van der Waals forces. The IR and UV spectra are in accordance with the established geometrical features of the structure.
Articles in the same Issue
- Crystal structure of a cholesterogen – cholesteryl methyl carbonate (CMC)
- An X-ray search for anharmonicity in indium phosphide
- Crystal structure and spectra of bis[p-chloro-benzoyl-di-(2-pyridyl)ketonohydrazono]uranyl
- Crystal structures of isomorphous triaquatris(3-aminobenzoato-O, O)yttrium(III) trihydrate and triaquatris(3-aminobenzoato-0,0)lanthanide(III) trihydrate
- Crystal structure of calcium hydroxide nitrate hydrate and its superstructure in relation to cadmium hydroxide nitrate hydrate
- Structural phase transition in GaMo4Se8 and AlMo4S8 by X-ray powder diffraction
- The crystal structure of Ce4Ru3
- Allowance for Debye scattering in Wilson-plot least-squares procedures
- The (1:1) adducts of (2,4-dichlorophenoxy)acetic acid with 4-aminobenzoic acid and triphenylphosphine oxide *
- Molecular and crystal structure of a terminally-blocked Aib homotetrapeptide *
- Molecular and crystal structure of Nα-benzyloxycarbonyl-l-proline amide *
- Schwingungsspektroskopische Untersuchungen an SiO2-Clathraten
- Liebauite, Ca3Cu5Si9O26: A new silicate mineral with 14er single chain
- The crystal and molecular structure of tramazoline hydrochloride monohydrate, C13H18N3+Cl−·H2O
- Crystal structure of sphagnum acid, C11H10O5
- High resolution X-ray investigations on the supersatellite reflections of Labradorite
- The crystal structure of di(5-amino-3-thione-l,2,4-dithiazole)-tris-thiocyanatobismuthate (III), (C2H2N2S3)2Bi(SCN)3 determined at 100 K
- The structure type of ludwigite
Articles in the same Issue
- Crystal structure of a cholesterogen – cholesteryl methyl carbonate (CMC)
- An X-ray search for anharmonicity in indium phosphide
- Crystal structure and spectra of bis[p-chloro-benzoyl-di-(2-pyridyl)ketonohydrazono]uranyl
- Crystal structures of isomorphous triaquatris(3-aminobenzoato-O, O)yttrium(III) trihydrate and triaquatris(3-aminobenzoato-0,0)lanthanide(III) trihydrate
- Crystal structure of calcium hydroxide nitrate hydrate and its superstructure in relation to cadmium hydroxide nitrate hydrate
- Structural phase transition in GaMo4Se8 and AlMo4S8 by X-ray powder diffraction
- The crystal structure of Ce4Ru3
- Allowance for Debye scattering in Wilson-plot least-squares procedures
- The (1:1) adducts of (2,4-dichlorophenoxy)acetic acid with 4-aminobenzoic acid and triphenylphosphine oxide *
- Molecular and crystal structure of a terminally-blocked Aib homotetrapeptide *
- Molecular and crystal structure of Nα-benzyloxycarbonyl-l-proline amide *
- Schwingungsspektroskopische Untersuchungen an SiO2-Clathraten
- Liebauite, Ca3Cu5Si9O26: A new silicate mineral with 14er single chain
- The crystal and molecular structure of tramazoline hydrochloride monohydrate, C13H18N3+Cl−·H2O
- Crystal structure of sphagnum acid, C11H10O5
- High resolution X-ray investigations on the supersatellite reflections of Labradorite
- The crystal structure of di(5-amino-3-thione-l,2,4-dithiazole)-tris-thiocyanatobismuthate (III), (C2H2N2S3)2Bi(SCN)3 determined at 100 K
- The structure type of ludwigite
