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SmPt2In2 – a new ternary indide with a Pt–In polyanionic framework

  • Nazar Zaremba EMAIL logo , Ihor Muts , Volodymyr Pavlyuk , Viktor Hlukhyy , Rainer Pöttgen , Dariusz Kaczorowski and Vasyl Zaremba
Published/Copyright: June 15, 2021
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 236 Issue 5-7

Abstract

Single crystals of a new samarium platinum indide have been synthesized in a high-frequency furnace under flowing argon atmosphere. The crystal structure of SmPt2In2 was determined from single-crystal X-ray data (R1 = 0.0416 for 1049 F values and 63 variables). It belongs to the CePt2In2 structure type with the following crystallographic parameters: P21/m, mP20, Z = 4, a = 10.0561(8), b = 4.4214(2), c = 10.1946(8) Å, β = 116.492(5)°, V = 405.68(5) Å3. Physical properties were studied and the crystal chemical discussion is supported by electronic structure calculations.

Keywords: crystal structure; electronic structure calculations; indium; intermetallics; physical properties; rare-earth
Corresponding author: Nazar Zaremba, Department of Chemistry, Technische Universität München, Lichtenbergstrasse 4, 85747Garching, Germany; and Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya street 6, 79005Lviv, Ukraine, E-mail:

Funding source: Deutscher Akademischer Austauschdienst

Award Identifier / Grant number: 91619802

Funding source: National Science Centre, Poland

Award Identifier / Grant number: 2017/25/B/ST8/02179

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the Deutscher Akademischer Austauschdienst (Nr 91619802) and partially by the National Science Centre, Poland (nr 2017/25/B/ST8/02179).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-05-07
Accepted: 2021-05-27
Published Online: 2021-06-15
Published in Print: 2021-06-25

© 2021 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/zkri-2021-2028
Keywords for this article
crystal structure; electronic structure calculations; indium; intermetallics; physical properties; rare-earth

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Inorganic Crystal Structures (Original Papers)
  4. ErNi2.23Al2.77 and YbNi2.31Al2.69 – i3 superstructures of the CaCu5 type
  5. New compound Sm2Ru3Sn5 with a structure derived from Ru3Sn7
  6. Site preference and atomic ordering in the ternary Rh5Ga2As: first-principles calculations
  7. SmPt2In2 – a new ternary indide with a Pt–In polyanionic framework
  8. The order/disorder phase transition of hypophosphorous acid H3PO2
  9. KCu(SeO4)Cl(H2O)2, a first copper chloride selenate
  10. The germanides APtGe2 (A = Ca, Sr, Eu)
  11. Organic and Metalorganic Crystal Structures (Original Paper)
  12. Crystal structure analysis and supramolecular association in ethyl N-[amino(iminio)methyl]carbamate dichloride hemi-hydrate
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