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Doubly modified MWCNTs embedded in polyethersulfone (PES) ultrafiltration membrane and its anti-fouling performance

  • Yadi Zhang ORCID logo , Chengcong Wang , Lijuan Zhang EMAIL logo , Jianghuan Shi , Haikuan Yuan EMAIL logo and Jie Lu
Published/Copyright: June 27, 2022
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Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 42 Issue 9

Abstract

Multiwall carbon nanotubes (MWCNTs) are often used to modify polymer membranes as additives, however, MWCNTs are easy to agglomerate and entangle in polymer matrix due to their own strong van der Waals force. MWCNTs were doubly modified by bonding octadecylamine (ODA) and SiO2 through the respective amidation and esterification reactions to prepare SiO2-MWCNT-ODA nanocomposites. The amino groups on ODA were amidated with the carboxyl groups on MWCNT-COOH. Then the hydroxyl groups on SiO2 were bonded to MWCNT-COOH through esterification to obtain SiO2-MWCNT-ODA nanocomposites. PES/SiO2-MWCNT-ODA composite ultrafiltration (UF) membrane was prepared by non-solvent induced phase separation (NIPS) method. SiO2-MWCNT-ODA nanocomposites and PES/SiO2-MWCNT-ODA membrane were characterized by FTIR, XRD, TGA, and SEM, etc. The results showed that PES/SiO2-MWCNT-ODA membrane had significantly improved permeability, rejection, and antifouling properties for comparison with PES membrane. The pure water flux of PES/Nano.2-0.5 reached 212.5 L m−2 h−1, which was approximately 2.6 times than that of PES membrane, and the rejection of BSA protein for composite membrane was as high as 94.2%. PES/SiO2-MWCNT-ODA composite membrane had excellent antifouling performance and the flux recovery rate (FRR) of PES/Nano.2-0.5 membrane could still maintain at higher value of 84.82% after two cycles in the antifouling test.

Keywords: anti-fouling; MWCNT; polyethersulfone; SiO2-MWCNT-ODA nanocomposites; ultrafiltration membrane
Corresponding authors: Lijuan Zhang and Haikuan Yuan, College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China, E-mail: (L. Zhang), (H. Yuan)

Funding source: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809

Award Identifier / Grant number: 21206146, 22078191, 21978165, 22081340412, 9215602

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was financially supported by the National Natural Science Foundation of China (nos. 21206146, 22078191, 21978165, 22081340412 and 92156020).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-02-16
Accepted: 2022-05-10
Published Online: 2022-06-27
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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  2. Material properties
  3. Effect of nanodiamond particles on the structure, mechanical, and thermal properties of polymer embedded ND/PMMA composites
  4. A comparative investigation on wear characteristics of polymer and biopolymer gears
  5. Unsaturated polyester resin modified with a novel reactive flame retardant: effects on thermal stability and flammability
  6. Recent progress on the morphology and thermal cycle of phase change materials (PCMs)/conductive filler composites: a mini review
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  12. Doubly modified MWCNTs embedded in polyethersulfone (PES) ultrafiltration membrane and its anti-fouling performance
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https://doi.org/10.1515/polyeng-2022-0021
Keywords for this article
anti-fouling; MWCNT; polyethersulfone; SiO2-MWCNT-ODA nanocomposites; ultrafiltration membrane

Articles in the same Issue

  1. Frontmatter
  2. Material properties
  3. Effect of nanodiamond particles on the structure, mechanical, and thermal properties of polymer embedded ND/PMMA composites
  4. A comparative investigation on wear characteristics of polymer and biopolymer gears
  5. Unsaturated polyester resin modified with a novel reactive flame retardant: effects on thermal stability and flammability
  6. Recent progress on the morphology and thermal cycle of phase change materials (PCMs)/conductive filler composites: a mini review
  7. Effect of tiny amount of DMC on thermal, mechanical, optical, and water resistance properties of poly(vinyl alcohol)
  8. Vibration and tribological properties of epoxy-granite composites used as novel foundations for machine elements
  9. Effect of lyocell fiber cross-sectional shape on structure and properties of lyocell/PLA composites
  10. Engineering and processing
  11. Quality prediction and control of thin-walled shell injection molding based on GWO-PSO, ACO-BP, and NSGA-II
  12. Doubly modified MWCNTs embedded in polyethersulfone (PES) ultrafiltration membrane and its anti-fouling performance
  13. Solid-state extrusion of polymers using simple shear deformation
  14. Molding process and properties of polyimide-fiber-fabric-reinforced polyether ether ketone composites
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