Natural rubber reinforced with super-hydrophobic multiwalled carbon nanotubes: obvious improved abrasive resistance and enhanced thermal conductivity
Abstract
Polyurethane chain was successfully grafted onto carbon nanotubes, affording polyurethane-functionalized multiwalled carbon nanotubes (P-MWCNTs) with super-hydrophobic property, which shows improved abrasive resistance obviously and enhanced thermal conductivity for natural rubber (NR) vulcanizate. Under the optimized conditions, the akron abrasion loss of NR vulcanizate combined with 5 parts per hundred rubber (5 phr) P-MWCNTs is 0.9 cm3/1.61 km compared to 2.96 cm3/1.61 km of pristine NR vulcanizate. The thermal conductivity of NR vulcanizate combined with 5 phr P-MWCNTs has been improved by 40.3% compared to that of pristine NR vulcanizate. The decreased height of the maximum tan δ peak shows that P-MWCNTs can reduce the heat buildup and damping capability of NR/P-MWCNTs composites. The good dispersion of P-MWCNTs with a continuous network, particularly at high loading (5 phr) in the NR composites, was evidenced from transmission electron microscopy (TEM).
Funding source: Anhui province university outstanding youth talent support program
Award Identifier / Grant number: gxyq2018070
Funding source: Anhui provincial natural science foundation
Award Identifier / Grant number: 1808085ME144
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Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: We thank Anhui Provincial Natural Science Foundation (no. 1808085ME144) and Anhui Province University Outstanding Youth Talent Support Program (no. gxyq2018070).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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© 2022 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Material properties
- Research progress of low dielectric constant polymer materials
- Natural rubber reinforced with super-hydrophobic multiwalled carbon nanotubes: obvious improved abrasive resistance and enhanced thermal conductivity
- Epoxy resin/graphene nanoplatelets composites applied to galvanized steel with outstanding microwave absorber performance
- Enhancement of thermal conductivity in polymer composites by maximizing surface-contact area of polymer-filler interface
- Dynamic characterization of the magnetomechanical properties of off axis anisotropic magnetorheological elastomer
- Investigation of optical and biocompatible properties of polyethylene glycol-aspirin loaded commercial pure titanium for cardiovascular device applications
- Polylactic acid effectively reinforced with reduced graphitic oxide
- Preparation and assembly
- Assembled hybrid films based on sepiolite, phytic acid, polyaspartic acid and Fe3+ for flame-retardant cotton fabric
- Fabrication, characterization, and performance of poly (aryl ether nitrile) flat sheet ultrafiltration membranes with polyvinyl pyrrolidone as additives
- Synthesis of composite membranes from polyacrylonitrile/carbon resorcinol/formaldehyde xerogels: gamma effect study, characterization and ultrafiltration of salted oily wastewater
- Chitosan nanoparticles encapsulated into PLA/gelatin fibers for bFGF delivery
- Engineering and Processing
- Stable photoluminescent electrospun CdSe/CdS quantum dots-doped polyacrylonitrile composite nanofibers
Articles in the same Issue
- Frontmatter
- Material properties
- Research progress of low dielectric constant polymer materials
- Natural rubber reinforced with super-hydrophobic multiwalled carbon nanotubes: obvious improved abrasive resistance and enhanced thermal conductivity
- Epoxy resin/graphene nanoplatelets composites applied to galvanized steel with outstanding microwave absorber performance
- Enhancement of thermal conductivity in polymer composites by maximizing surface-contact area of polymer-filler interface
- Dynamic characterization of the magnetomechanical properties of off axis anisotropic magnetorheological elastomer
- Investigation of optical and biocompatible properties of polyethylene glycol-aspirin loaded commercial pure titanium for cardiovascular device applications
- Polylactic acid effectively reinforced with reduced graphitic oxide
- Preparation and assembly
- Assembled hybrid films based on sepiolite, phytic acid, polyaspartic acid and Fe3+ for flame-retardant cotton fabric
- Fabrication, characterization, and performance of poly (aryl ether nitrile) flat sheet ultrafiltration membranes with polyvinyl pyrrolidone as additives
- Synthesis of composite membranes from polyacrylonitrile/carbon resorcinol/formaldehyde xerogels: gamma effect study, characterization and ultrafiltration of salted oily wastewater
- Chitosan nanoparticles encapsulated into PLA/gelatin fibers for bFGF delivery
- Engineering and Processing
- Stable photoluminescent electrospun CdSe/CdS quantum dots-doped polyacrylonitrile composite nanofibers