The aza-Pudovik reaction accelerated in external constant magnetic field
-
Rafał Karpowicz
,
Marta Morawska
Abstract
The aza-Pudovik reaction of N-benzyl aromatic and aliphatic aldimines with dimethyl H-phosphonate was found to be accelerated significantly when carried out in an external magnetic field. Its conversion rates were analyzed and compared with those obtained during the aza-Pudovik reaction carried out under standard conditions. Magnetic acceleration was found to have a similar degree as in that observed in the Kabachnik–Fields reaction. However, the formation of the starting imines was found not to be susceptible to constant magnetic field – no acceleration was observed.
Acknowledgements
The authors wish to express their great thanks to Dr Marcin Jasiński for his friendly assistance.
Supplementary data
Supplementary data associated with this article can be found in the online version of this paper (DOI:10.1515/chempap-2016-0087).
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