Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
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H. Liu
Abstract
In order to investigate the effect of kaolin coated with liquid macromolecular modifier (LKL) particles on the processability, thermal and mechanical properties of PVC materials, rigid poly(vinyl chloride) (PVC)/kaolin and PVC/kaolin coated with liquid macromolecular modifier (PVC/LKL) composites were both fabricated by melt mixing. The processability, dynamic mechanical behavior, mechanical properties and micro-structure of PVC/kaolin and PVC/LKL composites were studied by using torque rheometer, dynamic mechanical analysis (DMA), universal mechanical testing machine and scanning electron microscope (SEM). The results showed that the LKL particles improved the processability of PVC materials, while restrained the degradation of PVC materials during melt mixing due to the plasticization, toughening effect and compatibilization of the liquid macromolecular modifier (LMM). Moreover, the LMM could promote LKL particles uniformly dispersed in PVC matrix, and enhance the interface adhesion between LKL particles and PVC matrix. The notched impact strength and Tg of the PVC/LKL composites achieved 4.0 kJ/m2 and 95.2 °C, which enhanced 29% and 6 °C with respect to neat PVC materials, respectively.
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© 2015, Carl Hanser Verlag, Munich
Artikel in diesem Heft
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- Tuning of Final Performances of Soybean Oil–Based Polymer Nanocomposites: Effect of Styryl/Oil Functionalized Intercalant of Montmorillonite Reinforcer
- Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
- Numerical Analysis and Evaluation of Process and Geometry Specific Transient Temperature Fields for a New Variation of Gas-Assisted Injection Molding
- Effect of Feeding Strategy on the Properties of PP/Recycled EPDM Blends
- Analysis of a Single Screw Extruder with a Grooved Plasticating Barrel – Part I: The Melting Model
- Melt Elongation Strength and Drawability of LDPE/LLDPE Blends
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Multilayer Coextrusion of Polymer Composites to Develop Organic Capacitors
- Heat Flow Analysis and Efficiency Optimization of Rotational Molding Equipment for Large Plastic Products
- Thermorheology of Polyethylene Wax Modified Sulfur Asphalt
- Thermoplastic Cellulose Stearate and Cellulose Laurate: Melt Rheology, Processing and Application Potential
- Crystallization Kinetics for PP/EPDM/Nano-CaCO3 Composites – The Influence of Nanoparticles Distribution
- The Effect of ZnO Nanoparticle Filler on the Attenuation of ZnO/PCL Nanocomposites Using Microstrip Line at Microwave Frequency
- Synthesis and Properties of Nitrogen Heterocycle-Functionalized Core-Shell Hyperbranched Polyester
- Morphology Tuning of Conducting Polyaniline via Static, Liquid-Liquid Interfacial Polymerization Process and its Application for Optical pH Sensing
- Tuning of Final Performances of Soybean Oil–Based Polymer Nanocomposites: Effect of Styryl/Oil Functionalized Intercalant of Montmorillonite Reinforcer
- Processability, Thermal and Mechanical Properties of Rigid PVC/Kaolin Coated with Liquid Macromolecular Modifier Composites
- Numerical Analysis and Evaluation of Process and Geometry Specific Transient Temperature Fields for a New Variation of Gas-Assisted Injection Molding
- Effect of Feeding Strategy on the Properties of PP/Recycled EPDM Blends
- Analysis of a Single Screw Extruder with a Grooved Plasticating Barrel – Part I: The Melting Model
- Melt Elongation Strength and Drawability of LDPE/LLDPE Blends
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts
