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New Developments in Biodegradable Starch-based Nanocomposites

  • J.-M. Raquez , Y. Nabar , R. Narayan und P. Dubois
Veröffentlicht/Copyright: 6. April 2013
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Abstract

This contribution outlines the new developments in thermoplastic starch-based (nano)composites useful for more specific applications compatible with our environment, partially based on our ongoing research over the past few years. Accordingly, melt-intercalating starch macromomolecules into layered silicates (e.g., natural clays) has proved to be an efficient way for preparation of thermoplastic starch-layered silicate nanocomposites with interesting thermo-mechanical properties, as well as improved solvent-resistance. Cellulosic (nano)whiskers were also added as another environmentally benign (nano)filler in starch-based compositions. The design of such thermoplastic starch-based (nano)composites with enhanced properties relies upon the control over the phase behavior and morphology of the nanofiller within the matrix by more defined interfacial compatibility as well as by fine tuning of processing parameters. A special emphasis was also given to the introduction of layered silicates (nano)filler in biodegradable melt-blends made of hydrophilic thermoplastic starch and hydrophobic biodegradable polyesters as a valuable way to increase the compatibility between the two polymeric partners.


Mail address: Philippe Dubois, Center of Innovation and Research in Materials & Polymers (CIRMAP), Laboratory of Polymer and Composite Materials, University of Mons-Hainaut/Materia Nova, Place du Parc 20, B-7000 Mons, Belgium. E-mail:

References

Alexandre, M., Dubois, Ph., “Polymer Layered Silicate Nanocomposites”, Mater. Sci. Eng. R., 28, 163 (2000)10.1016/S0927-796X(00)00012-7Suche in Google Scholar

Anglès, N., Dufresne, A., “Plasticized Starch/Tunicin Nanocomposites. 1. Structural Analysis”, Macromolecules, 33, 83448353 (2000)10.1021/ma0008701Suche in Google Scholar

Anglès, N., Dufresne, A., “Plasticized Starch/Tunicin Nanocomposites Materials. 2. Mechanical Behavior”, Macromolecules, 34, 2921 (2001)10.1021/ma001555hSuche in Google Scholar

Avela, M., et al., “Biodegradable Starch/Clay Nanocomposites for Food Packaging Applications”, Food Chem.93, 467 (2005)10.1016/j.foodchem.2004.10.024Suche in Google Scholar

Bastioli, C., et al., US Patent 5288765 (1994)Suche in Google Scholar

Bastioli, C., et al., US Patent 5360830 (1994)Suche in Google Scholar

Bastioli, C., et al., US Patent 5736586 (1998)Suche in Google Scholar

Bastioli, C., et al., US Patent 5801207 (1998)Suche in Google Scholar

Battista, O. A., et al., “Level-off Degree of Polymerization: Relation to Polyphase Structure of Cellulose Fibers”, Ind. Eng. Chem., 48, 333 (1956)10.1021/ie50554a046Suche in Google Scholar

Chandra, R., Rustgi, R., “Biodegradable Polymers”, Prog. Polym. Sci., 23, 1273 (1998)10.1016/S0079-6700(97)00039-7Suche in Google Scholar

Chen, B., Evans, J. R. G., “Thermoplastic Starch-clay Nanocomposites and their Characteristics”, Carbohydr. Polym., 61, 455 (2005)10.1016/j.carbpol.2005.06.020Suche in Google Scholar

ChenM., et al., “Novel Thermoplastic Starch-clay Nanocomposite Foams”, Nanotechnology16, 2334 (2005)10.1088/0957-4484/16/10/056Suche in Google Scholar PubMed

de Graaf, R., et al., “Material Properties and Glass Transition Temperatures of Different Thermoplastic Starches after Extrusion Processing”, Starch/Stärke, 55, 80 (2003)10.1002/star.200390020Suche in Google Scholar

Dean, K., et al., “Preparation and Characterization of Melt-extruded Thermoplastic Starch/Clay Nanocomposites”, Compos. Sci. Technol., 67, 413 (2007)10.1016/j.compscitech.2006.09.003Suche in Google Scholar

Dubois, P., Narayan, R., “Biodegradable Compositions by Reactive Processing of Aliphatic Polyester/Polysaccharide Blends”, Macromol. Symp., 198, 233 (2003)10.1002/masy.200350820Suche in Google Scholar

Dufresne, A., Samain, E., “Preparation and Characterization of a Poly(β-Hydroxyoctanoate) Latex Produced by Pseudomonas Oleovorans”, Macromolecules, 31, 6426 (1998)10.1021/ma980508aSuche in Google Scholar

Goettler, L. A., et al., “Layered Silicate Reinforced Polymer Nanocomposites: Development and Applications”, Polymer Review, 47, 291 (2007)10.1080/15583720701271328Suche in Google Scholar

Gross, R., “Biodegradable Polymers for the Environment”, Science, 297, 803 (2002)10.1126/science.297.5582.803Suche in Google Scholar PubMed

Huang, M. F., et al., “Studies on the Properties of Montmorillonite-reinforced Thermoplastic Starch Composites”, Polymer, 45, 7017 (2004)10.1016/j.polymer.2004.07.068Suche in Google Scholar

Huang, M. F., et al., “High-mechanical Performance MMT-urea and Formamide-plasticized Thermoplastic Cornstarch Biodegradable Nanocomposites”, Carbohydr. Polym., 63, 393 (2006)10.1016/j.carbpol.2005.09.006Suche in Google Scholar

Huang, M. Y., Yu, J., “Structure and Properties of Thermoplastic Corn Starch/Montmorillonite Biodegradable Composites”, J. Appl. Polym. Sci., 99, 170 (2006)10.1002/app.22046Suche in Google Scholar

Ikeo, Y., et al., “Nanoclay Reinforced Biodegradable Plastics of PCL Starch Blends”, Polym. Adv. Technol., 17, 940 (2006)10.1002/pat.816Suche in Google Scholar

Kalambur, S., Rizvi, S., “Starch-based Nanocomposites by Reactive Extrusion Processing”, Polym. Int., 53, 1413 (2004)10.1002/pi.1478Suche in Google Scholar

Kalambur, S., Rizvi, S., “Biodegradable and Functionally Superior Starch-polyester Nanocomposites from Reactive Extrusion”, J. Appl. Polym. Sci., 96, 1072 (2005)10.1002/app.21504Suche in Google Scholar

Kalambur, S., Rizvi, S., “Rheological Behavior of Starch-Polycaprolactone (PCL) Nanocomposite Melts Synthesized by Reactive Extrusion”, Polym. Eng. Sci., 5, 651 (2006)10.1002/pen.20508Suche in Google Scholar

Karlsson, S., Albertsson, A.-C., “Biodegradable Polymers and Environmental Interaction”, Poly. Eng. Sci., 38, 1251 (1998)10.1002/pen.10294Suche in Google Scholar

Lohse, D. J., Datta, S.: Polymeric Materials Encyclopedia, CRC Press, Boca Raton, FL (1996)Suche in Google Scholar

Ma, X., Yu, J., “The Effects of Plasticizers Containing Amide Groups on the Properties of Thermoplastic Starch”, Starch/Stärke, 56, 545 (2004)10.1002/star.200300256Suche in Google Scholar

Malliger, R. B., et al., “Compatibilization of Starch-polyester Blends Using Reactive Extrusion”, Polym. Eng. Sci., 46, 248 (2006)10.1002/pen.20479Suche in Google Scholar

Mani, R., et al., “Functionalization of Polyesters with Maleic Anhydride by Reactive Extrusion”, J. Polym. Sci., Part A: Polym. Chem., 37, 1693 (1999)10.1002/(SICI)1099-0518(19990601)37:11<1693::AID-POLA15>3.0.CO;2-YSuche in Google Scholar

Marchessault, R. H., et al., “Hydrodynamics Properties of Neutral Suspensions of Cellulose Crystallites as Related to Size and Shape”, J. Colloid Interf. Sci., 16, 327 (1961)10.1016/0095-8522(61)90033-2Suche in Google Scholar

McGhaslan, S., Halley, P., “Preparation and Characterisation of Biodegradable Starch-based Nanocomposite Materials”, Polym. Int.52, 1767 (2003)10.1002/pi.1287Suche in Google Scholar

Mohanty, A. K., et al., “Biofibres, Biodegradable Polymers and Biocomposites: An Overview”, Macromol. Mater. Eng., 276/277, 1 (2000)10.1002/(SICI)1439-2054(20000301)276:1<1::AID-MAME1>3.0.CO;2-WSuche in Google Scholar

Nabar, Y., et al., “Production of Starch Foams by Twin-screw Extrusion: Effect of Maleated Poly(Butylene Adipate-Co-Terephthalate) as a Compatibilizer”, Biomacromolecules, 6, 807 (2005)10.1021/bm0494242Suche in Google Scholar

Nabar, Y., et al., “Physicomechanical and Hydrophobic Properties of Starch Foams Extruded with Different Biodegradable Polymers”, J. Appl. Polym. Sci., 102, 58 (2006)10.1002/app.22127Suche in Google Scholar

Nayak, P. L., “Biodegradable Polymers: Opportunities and Challenges”, J. Macromol. Sci. – Rev. Macromol. Chem. Phys., C39, 481 (1999)10.1081/MC-100101425Suche in Google Scholar

Nesterov, A., Lipatov, Y. S., “Compatibilizing Effect of a Filler in Binary Polymer Mixtures”, Polymer, 40, 1347 (1999)10.1016/S0032-3861(98)00277-8Suche in Google Scholar

Nesterov, A., et al., “Effect of an Interface with Solid on the Component Distribution in Separated Phases of Binary Polymer Mixtures”, Eur. Polym. J., 37, 281 (2001)10.1016/S0014-3057(00)00065-3Suche in Google Scholar

Reddy, C., et al., “Polyhydroxyalkanoates: An Overview”, Biores. Tech., 87, 137 (2003)10.1016/S0960-8524(02)00212-2Suche in Google Scholar

Park, H. M., et al., “Preparation and Properties of Biodegradable Thermoplastic Starch/Clay Hybrids”, Macromol. Mater. Eng., 287, 553 (2002)10.1002/1439-2054(20020801)287:8<553::AID-MAME553>3.0.CO;2-3Suche in Google Scholar

Park, H., et al., “Environmentally Friendly Polymer Hybrids”, J. Mater. Sci., 38, 909 (2003)10.1023/A:1022308705231Suche in Google Scholar

Ranby, B. G., “The Colloidal Properties of Cellulose Micelles”, Discussions Faraday Soc., 11, 158 (1951)10.1039/df9511100158Suche in Google Scholar

Raquez, J.-M., et al., “In Situ Compatibilization of Maleated Thermoplastic Starch/Polyester Melt-Blends by Reactive Extrusion”, Polym. Eng. Sci., submitted for publication (2007)10.1002/pen.21136Suche in Google Scholar

Raquez, J.-M., et al., “Maleated Thermoplastic Starch/Polyester-based Nanocomposites by Reactive Extrusion”, Polymer, submitted for publication (2007)Suche in Google Scholar

Ray, S., Bousmina, M., “Biodegradable Polymers and their Layered Silicate Nanocomposites: In Greening the 21st Century Materials World”, Prog. Mat. Sci., 50, 962 (2005)10.1016/j.pmatsci.2005.05.002Suche in Google Scholar

Ruggeri, G., et al., “Some Aspects of Polypropylene Functionalization by Free Radical Reactions”, Eur. Polym. J., 19, 863 (1983)10.1016/0014-3057(83)90039-3Suche in Google Scholar

Samir, M., et al., “Review of Recent Research into Cellulosic Whiskers, their Properties and their Application in Nanocomposite Field”, Biomacromolecules, 6, 612 (2005)10.1021/bm0493685Suche in Google Scholar

Septo, R. F., “The processing of starch as a thermoplastic”, Macromol. Symp., 201, 203 (2003)10.1002/masy.200351123Suche in Google Scholar

Souza, R., Andrade, C., “Investigation of the Gelatinization And Extrusion Processes of Corn Starch”, Adv. Polym. Tech., 21, 17 (2002)10.1002/adv.10007Suche in Google Scholar

Van Soest, J., et al., “The Influence of Starch Molecular Mass on the Properties of Extruded Thermoplastic Starch”, Polymer, 37, 3543 (1996)10.1016/0032-3861(96)00165-6Suche in Google Scholar

Vert, M., et al., (Eds.): Biodegradable Polymers and Plastics, Royal Chemistry Society, Redwood Press: Melksham, Wiltshire (1992)Suche in Google Scholar

Yang, J. H., et al., “Preparation of a Novel Thermoplastic Starch (TPS) Material Using Ethylenebisformamide as the Plasticizer”, Starch/Stärke, 58, 330 (2006)10.1002/star.200500479Suche in Google Scholar

Yu, L., et al., “Polymer Blends and Composites from Renewable Resources”, Prog. Polym. Sci., 31, 576 (2006)10.1016/j.progpolymsci.2006.03.002Suche in Google Scholar

Received: 2007-5-16
Accepted: 2007-9-4
Published Online: 2013-04-06
Published in Print: 2007-12-01

© 2007, Carl Hanser Verlag, Munich

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Special Issue on Biobased Polymers
  5. Invited Papers
  6. Crystallization and Mechanical Propertiesof Poly (D, L) Lactide-based Blown Films
  7. Rheological Behavior and Modeling of Thermal Degradation of Poly(∊-Caprolactone) and Poly(L-Lactide)
  8. Rheological Evaluation and Observations of Extrusion Instabilities of Biodegradable Polyesters
  9. Biaxial Orientation of Polylactide/Thermoplastic Starch Blends
  10. Effects of Starch Types on Mechanical Properties of Poly(lactic acid)/Starch Composites
  11. Solid and Microcellular Polylactide-Carbon Nanotube Nanocomposites
  12. Tapioca Starch-poly (lactic acid)-based Nanocomposite Foams as Affected by Type of Nanoclay
  13. Injection Molded Solid and Microcellular Polylactide Compounded with Recycled Paper Shopping Bag Fibers
  14. Fabrication of Porous 3-D Structure from Poly(L-lactide)-based Nanocomposite Foam via Enzymatic Degradation
  15. The Linear Viscoelastic Behavior of a Series of 3-Hydroxybutyrate-based Copolymers
  16. New Developments in Biodegradable Starch-based Nanocomposites
  17. Viscous Properties of Thermoplastic Starches from Different Botanical Origin
  18. Thermoplastic Foams from Zein and Gelatin
  19. Improvement of the Mechanical Properties of Soy Protein Isolate Based Plastics through Formulation and Processing
  20. Biocomposites Based on Bacterial Cellulose and Apple and Radish Pulp
  21. Preparation and Properties of Metallocene-catalyzed PE/Starch Nanocomposites: Role of Nanocompatibilizer
  22. Evaluation of Properties and Biodeterioration Potential of Polyethylene and Aliphatic Polyester Blends
  23. PPS News
  24. PPP News
  25. Seikei-Kakou Abstracts
  26. Seikei-Kakou Abstracts
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