New Developments in Biodegradable Starch-based Nanocomposites
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J.-M. Raquez
Abstract
This contribution outlines the new developments in thermoplastic starch-based (nano)composites useful for more specific applications compatible with our environment, partially based on our ongoing research over the past few years. Accordingly, melt-intercalating starch macromomolecules into layered silicates (e.g., natural clays) has proved to be an efficient way for preparation of thermoplastic starch-layered silicate nanocomposites with interesting thermo-mechanical properties, as well as improved solvent-resistance. Cellulosic (nano)whiskers were also added as another environmentally benign (nano)filler in starch-based compositions. The design of such thermoplastic starch-based (nano)composites with enhanced properties relies upon the control over the phase behavior and morphology of the nanofiller within the matrix by more defined interfacial compatibility as well as by fine tuning of processing parameters. A special emphasis was also given to the introduction of layered silicates (nano)filler in biodegradable melt-blends made of hydrophilic thermoplastic starch and hydrophobic biodegradable polyesters as a valuable way to increase the compatibility between the two polymeric partners.
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© 2007, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Special Issue on Biobased Polymers
- Invited Papers
- Crystallization and Mechanical Propertiesof Poly (D, L) Lactide-based Blown Films
- Rheological Behavior and Modeling of Thermal Degradation of Poly(∊-Caprolactone) and Poly(L-Lactide)
- Rheological Evaluation and Observations of Extrusion Instabilities of Biodegradable Polyesters
- Biaxial Orientation of Polylactide/Thermoplastic Starch Blends
- Effects of Starch Types on Mechanical Properties of Poly(lactic acid)/Starch Composites
- Solid and Microcellular Polylactide-Carbon Nanotube Nanocomposites
- Tapioca Starch-poly (lactic acid)-based Nanocomposite Foams as Affected by Type of Nanoclay
- Injection Molded Solid and Microcellular Polylactide Compounded with Recycled Paper Shopping Bag Fibers
- Fabrication of Porous 3-D Structure from Poly(L-lactide)-based Nanocomposite Foam via Enzymatic Degradation
- The Linear Viscoelastic Behavior of a Series of 3-Hydroxybutyrate-based Copolymers
- New Developments in Biodegradable Starch-based Nanocomposites
- Viscous Properties of Thermoplastic Starches from Different Botanical Origin
- Thermoplastic Foams from Zein and Gelatin
- Improvement of the Mechanical Properties of Soy Protein Isolate Based Plastics through Formulation and Processing
- Biocomposites Based on Bacterial Cellulose and Apple and Radish Pulp
- Preparation and Properties of Metallocene-catalyzed PE/Starch Nanocomposites: Role of Nanocompatibilizer
- Evaluation of Properties and Biodeterioration Potential of Polyethylene and Aliphatic Polyester Blends
- PPS News
- PPP News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Special Issue on Biobased Polymers
- Invited Papers
- Crystallization and Mechanical Propertiesof Poly (D, L) Lactide-based Blown Films
- Rheological Behavior and Modeling of Thermal Degradation of Poly(∊-Caprolactone) and Poly(L-Lactide)
- Rheological Evaluation and Observations of Extrusion Instabilities of Biodegradable Polyesters
- Biaxial Orientation of Polylactide/Thermoplastic Starch Blends
- Effects of Starch Types on Mechanical Properties of Poly(lactic acid)/Starch Composites
- Solid and Microcellular Polylactide-Carbon Nanotube Nanocomposites
- Tapioca Starch-poly (lactic acid)-based Nanocomposite Foams as Affected by Type of Nanoclay
- Injection Molded Solid and Microcellular Polylactide Compounded with Recycled Paper Shopping Bag Fibers
- Fabrication of Porous 3-D Structure from Poly(L-lactide)-based Nanocomposite Foam via Enzymatic Degradation
- The Linear Viscoelastic Behavior of a Series of 3-Hydroxybutyrate-based Copolymers
- New Developments in Biodegradable Starch-based Nanocomposites
- Viscous Properties of Thermoplastic Starches from Different Botanical Origin
- Thermoplastic Foams from Zein and Gelatin
- Improvement of the Mechanical Properties of Soy Protein Isolate Based Plastics through Formulation and Processing
- Biocomposites Based on Bacterial Cellulose and Apple and Radish Pulp
- Preparation and Properties of Metallocene-catalyzed PE/Starch Nanocomposites: Role of Nanocompatibilizer
- Evaluation of Properties and Biodeterioration Potential of Polyethylene and Aliphatic Polyester Blends
- PPS News
- PPP News
- Seikei-Kakou Abstracts
- Seikei-Kakou Abstracts