Startseite Fabrication of Porous 3-D Structure from Poly(L-lactide)-based Nanocomposite Foam via Enzymatic Degradation
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Fabrication of Porous 3-D Structure from Poly(L-lactide)-based Nanocomposite Foam via Enzymatic Degradation

  • M. Bitou und M. Okamoto
Veröffentlicht/Copyright: 6. April 2013
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Abstract

In order to prepare a porous three-dimensional (3-D) structure in biodegradable polyester materials we have conducted the enzymatic degradation of a poly(L-lactide) (PLLA)-based nano-composite foam, having a nanocellular structure, using proteinase-K as a degrading agent at 37°C. The surface and cross sectional morphologies of the foam recovered after enzymatic hydrolysis for different intervals were investigated by using a scanning electron microscope. The nanocellular material took up a large amount of water, which led to the swelling of the foam due to the large surface area inside the nanocelluar structure, and facilitated the enzymatic degradation of the PLLA matrix as compared with the bulk (pre-foamed) sample. Consequently, we have successfully prepared a porous 3-D structure as a remaining scaffold in the core part of the nano-composite foam, reflecting the spherulites of the crystallized PLLA.


Mail address: Masami Okamoto, Advanced Polymeric Nanostructured Materials Engineering, Graduate School of Engineering Toyota Technological Institute, 2-12-1 Hisakata, Tempaku, Nagoya 4688511, Japan. E-mail:

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Received: 2007-5-14
Accepted: 2007-9-4
Published Online: 2013-04-06
Published in Print: 2007-12-01

© 2007, Carl Hanser Verlag, Munich

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Special Issue on Biobased Polymers
  5. Invited Papers
  6. Crystallization and Mechanical Propertiesof Poly (D, L) Lactide-based Blown Films
  7. Rheological Behavior and Modeling of Thermal Degradation of Poly(∊-Caprolactone) and Poly(L-Lactide)
  8. Rheological Evaluation and Observations of Extrusion Instabilities of Biodegradable Polyesters
  9. Biaxial Orientation of Polylactide/Thermoplastic Starch Blends
  10. Effects of Starch Types on Mechanical Properties of Poly(lactic acid)/Starch Composites
  11. Solid and Microcellular Polylactide-Carbon Nanotube Nanocomposites
  12. Tapioca Starch-poly (lactic acid)-based Nanocomposite Foams as Affected by Type of Nanoclay
  13. Injection Molded Solid and Microcellular Polylactide Compounded with Recycled Paper Shopping Bag Fibers
  14. Fabrication of Porous 3-D Structure from Poly(L-lactide)-based Nanocomposite Foam via Enzymatic Degradation
  15. The Linear Viscoelastic Behavior of a Series of 3-Hydroxybutyrate-based Copolymers
  16. New Developments in Biodegradable Starch-based Nanocomposites
  17. Viscous Properties of Thermoplastic Starches from Different Botanical Origin
  18. Thermoplastic Foams from Zein and Gelatin
  19. Improvement of the Mechanical Properties of Soy Protein Isolate Based Plastics through Formulation and Processing
  20. Biocomposites Based on Bacterial Cellulose and Apple and Radish Pulp
  21. Preparation and Properties of Metallocene-catalyzed PE/Starch Nanocomposites: Role of Nanocompatibilizer
  22. Evaluation of Properties and Biodeterioration Potential of Polyethylene and Aliphatic Polyester Blends
  23. PPS News
  24. PPP News
  25. Seikei-Kakou Abstracts
  26. Seikei-Kakou Abstracts
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