Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements
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Dominika Jendrzejczyk-Handzlik
Abstract
The thermodynamic properties of liquid Ag – Sn – In alloys were determined using solid oxide galvanic cells with zirconia electrolyte. The following galvanic cells were employed:
Re + kanthal, Agx – Iny – Sn(1−x−y),(In2O3)s.s//ZrO2 + (Y2O3)//NiO, Ni, Pt(I)
in the temperature range from 973 to 1273 K, and in the range of indium mole fraction from 0.3 to 0.8.
This limitation was imposed by the side reaction between tin in the liquid alloy and solid In2O3. It was also found that the liquid is in equilibrium with the solid solution of oxides. Calorimetric measurements of the heat of mixing were also carried out at constant temperature 1003 K and along one isopleth with XAg/XSn = 1/1.
The thermodynamic properties of the liquid phase were described by the Redlich – Kister – Muggianu formula and the phase relations in the ternary system were calculated. The results of calculations were compared with the experimental data which are available from different literature sources.
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© 2008, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Basic
- A model to calculate the viscosity of silicate melts
- A model to calculate the viscosity of silicate melts
- A note on the application of the phase rule
- Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements
- Unconstrained solidification and characterisation of near-eutectic Al–Cu–Ag alloys
- Tensile properties of L12 intermetallic foils fabricated by cold rolling
- Microstructural control of FeB-inoculated mottled low-alloy white iron by a design of experiments approach
- Applied
- Dislocation structure and crystallite size distribution in lath martensite determined by X-ray diffraction peak profile analysis
- Effect of minor addition of Pb upon interfacial reactions and mechanical properties at Sn-3.0Ag-0.5Cu/Cu and Sn-58Bi/Cu solder joints
- Elastic properties of braided ceramic matrix composites
- The influence of microstructural characteristics and contaminants on the mechanical properties and fracture topography of low cost Ti6Al4V alloy
- Microstructure and room temperature mechanical properties of Hf and Sn-doped Nb-20Ti-5Cr-3Al-18Si alloy
- The effect of alloying elements on constrained carbon equilibrium due to a quench and partition process
- Hardfacing behavior of Cr–Ni stainless steel with Co-based super alloys
- Development of SMD 32.768 kHz tuning fork-type crystals
- Notification
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Basic
- A model to calculate the viscosity of silicate melts
- A model to calculate the viscosity of silicate melts
- A note on the application of the phase rule
- Thermodynamic properties of liquid silver–indium–tin alloys determined from emf measurements
- Unconstrained solidification and characterisation of near-eutectic Al–Cu–Ag alloys
- Tensile properties of L12 intermetallic foils fabricated by cold rolling
- Microstructural control of FeB-inoculated mottled low-alloy white iron by a design of experiments approach
- Applied
- Dislocation structure and crystallite size distribution in lath martensite determined by X-ray diffraction peak profile analysis
- Effect of minor addition of Pb upon interfacial reactions and mechanical properties at Sn-3.0Ag-0.5Cu/Cu and Sn-58Bi/Cu solder joints
- Elastic properties of braided ceramic matrix composites
- The influence of microstructural characteristics and contaminants on the mechanical properties and fracture topography of low cost Ti6Al4V alloy
- Microstructure and room temperature mechanical properties of Hf and Sn-doped Nb-20Ti-5Cr-3Al-18Si alloy
- The effect of alloying elements on constrained carbon equilibrium due to a quench and partition process
- Hardfacing behavior of Cr–Ni stainless steel with Co-based super alloys
- Development of SMD 32.768 kHz tuning fork-type crystals
- Notification
- DGM News
