ArF laser photolytic deposition and thermal modification of an ultrafine chlorohydrocarbon
-
Josef Pola
,
Anna Galíková
Abstract
MW ArF laser irradiation of gaseous cis-dichloroethene results in fast decomposition of this compound and in deposition of solid ultrafine Cl- and H-containing carbonaceous powder which is of interest due to its sub-microscopic structure and possible reactive modification of the C-Cl bonds. The product was characterized by electron microscopy, and FTIR and Raman spectra and it was revealed that HCl, H2, and C/H fragments are lost and graphitic features are adopted upon heating to 700°C.
[1] Berry, M. J. (1974). Chloroethylene photochemical lasers: Vibrational energy content of the HCl molecular elimination products. The Journal of Chemical Physics, 61, 3114–3143. DOI: 10.1063/1.1682468. http://dx.doi.org/10.1063/1.168246810.1063/1.1682468Suche in Google Scholar
[2] Bykovchenko, V. G., Érmanson, L. V., & Chernyshev, E. A. (1965). Investigation of the kinetice of the interaction of chlorosilanes with chlorobenzene in the gas phase. Russian Chemical Bulletin, 14, 1919–1922. DOI: 10.1007/BF00845882. http://dx.doi.org/10.1007/BF0084588210.1007/BF00845882Suche in Google Scholar
[3] Chandra, M., Senapati, D., Tak, M., & Das, P. K. (2006). Photodissociation of isomeric dichloroethylenes in the ultraviolet: Effect of the second chlorine atom substitution on the dynamics. Chemical Physics Letters, 430, 32–35. DOI: 10.1016/j.cplett.2006.08.128. http://dx.doi.org/10.1016/j.cplett.2006.08.12810.1016/j.cplett.2006.08.128Suche in Google Scholar
[4] Choi, M., Altman, I. S., Kim, Y.-J., Pikhitsa, P. V., Lee, S., Park, G.-S., Jeong, T., & Yoo, J.-B. (2004). Formation of shell-shaped carbon nanoparticles above a critical laser power in irradiated acetylene. Advanced Materials, 16, 1721–1725. DOI: 10.1002/adma.200400179. http://dx.doi.org/10.1002/adma.20040017910.1002/adma.200400179Suche in Google Scholar
[5] Dillon, R. O., Woollam, J. A., & Katkanant, V. (1984). Use of Raman scattering to investigate disorder and crystalline formation in as-deposited and annealed carbon films. Physical Review B, 29, 3482–3489. DOI: 10.1103/PhysRevB.29.3482. http://dx.doi.org/10.1103/PhysRevB.29.348210.1103/PhysRevB.29.3482Suche in Google Scholar
[6] Dischler, B., & Bayer, E. (1990). Properties of amorphous hydrogenated carbon films from ArF laser-induced C2H2 photolysis. Journal of Applied Physics, 68, 1237–1241. DOI: 10.1063/1.346724. http://dx.doi.org/10.1063/1.34672410.1063/1.346724Suche in Google Scholar
[7] Ehbrecht, M., Faerber, M., Rohmund, F., Smirnov, V. V., Stellmakh, O., & Huisken, F. (1993). CO2-laser-driven production of carbon clusters and fullerenes from the gas phase. Chemical Physics Letters, 214, 34–38. DOI: 10.1016/0009-2614(93)85451-S. http://dx.doi.org/10.1016/0009-2614(93)85451-S10.1016/0009-2614(93)85451-SSuche in Google Scholar
[8] Galíková, A., & Pola, J. (2008). Highly sensitive TGA diagnosis of thermal behaviour of laser-deposited materials. Thermochimica Acta, 473, 54–60. DOI: 10.1016/j.tca.2008.04.014. http://dx.doi.org/10.1016/j.tca.2008.04.01410.1016/j.tca.2008.04.014Suche in Google Scholar
[9] Galvez, A., Herlin-Boime, N., Reynaud, C., Clinard, C., & Rouzaud, J.-N. (2002). Carbon nanoparticles from laser pyrolysis. Carbon, 40, 2775–2789. DOI: 10.1016/S0008-6223(02)00195-1. http://dx.doi.org/10.1016/S0008-6223(02)00195-110.1016/S0008-6223(02)00195-1Suche in Google Scholar
[10] He, G., Yang, Y., Huang, Y., Hashimoto, S., & Gordon, R. J. (1995). Ultraviolet elimination of H2 from chloroethylenes. The Journal of Chemical Physics, 103, 5488–5498. DOI: 10.1063/1.470533. http://dx.doi.org/10.1063/1.47053310.1063/1.470533Suche in Google Scholar
[11] Hua, L., Zhang, X., Lee, W.-B., Chao, M.-H., Zhang, B., & Lin, K.-C. (2010). Photodissociation of cis-, trans-, and 1,1-dichloroethylene in the ultraviolet range: Characterization of Cl(2PJ) elimination. The Journal of Physical Chemistry A, 114, 37–44. DOI: 10.1021/jp907030e. http://dx.doi.org/10.1021/jp907030e10.1021/jp907030eSuche in Google Scholar
[12] Komuro, K., Ishizaki, K., & Suzuki, H. (2002). Cross-coupling reaction of chlorobenzene with triethoxysilane by palladium catalyst. Nippon Kagakkai Koen Yokoshu, 81, 1464. Suche in Google Scholar
[13] Kitahama, K. (1988). Reinvestigation of the carbon films prepared by ArF excimer laser-induced chemical vapor deposition. Applied Physics Letters, 53, 1812–1814. DOI: 10.1063/1.99788. http://dx.doi.org/10.1063/1.9978810.1063/1.99788Suche in Google Scholar
[14] Lindstam, M., Boman, M., & Piglmayer, K. (2001). Room temperature deposition of hydrogenated amorphous carbon films from laser-assisted photolytic chemical vapor deposition at 248 nm. Thin Solid Films, 394, 114–124. DOI: 10.1016/S0040-6090(01)01193-2. http://dx.doi.org/10.1016/S0040-6090(01)01193-210.1016/S0040-6090(01)01193-2Suche in Google Scholar
[15] Mochida, I., Tsunawaki, T., Sotowa, C., Korai, Y., & Higuchi, K. (1996). Coke produced in the commercial pyrolysis of ethylene dichloride into vinyl chloride. Industrial & Engineering Chemistry Research, 35, 3803–3807. DOI: 10.1021/ie9600248. http://dx.doi.org/10.1021/ie960024810.1021/ie9600248Suche in Google Scholar
[16] Morjan, I., Voicu, I., Dumitrache, F., Sandu, I., Soare, I., Alexandrescu, R., Vasile, E., Pasuk, I., Brydson, R. M. D., Daniels, H., & Rand, B. (2003). Carbon nanopowders from the continuous-wave CO2 laser-induced pyrolysis of ethylene. Carbon, 41, 2913–2921. DOI: 10.1016/S0008-6223(03)00381-6. http://dx.doi.org/10.1016/S0008-6223(03)00381-610.1016/S0008-6223(03)00381-6Suche in Google Scholar
[17] Okamoto, M., Asano, T., & Suzuki, E. (2001). Phenyldichlorogermane synthesis by the reaction of chlorobenzene and the dichlorogermylene intermediate formed from elemental germanium and tetrachlorogermane. Organometallics, 20, 5583–5585. DOI: 10.1021/om010761q. http://dx.doi.org/10.1021/om010761q10.1021/om010761qSuche in Google Scholar
[18] Pola, J., Bakardjieva, S., Maryško, M., Vorlíček, V., Šubrt, J., Bastl, Z., Galíková, A., & Ouchi, A. (2007). Laser-induced conversion of silica into nanosized carbon-polyoxocarbosilane composites. The Journal of Physical Chemistry C, 111, 16818–16826. DOI: 10.1021/jp074243q. http://dx.doi.org/10.1021/jp074243q10.1021/jp074243qSuche in Google Scholar
[19] Pola, J., Galíková, A., Bastl, Z., Vorlíček, V., Šubrt, J., Bakardjieva, S., & Ouchi, A. (2008a). UV laser photolysis of 1,3-butadiyne and formation of a polyoxocarbosilane-doped nanosized carbon. Journal of Photochemistry and Photobiology A: Chemistry, 194, 200–205. DOI: 10.1016/j.jphotochem.2007.08.006. http://dx.doi.org/10.1016/j.jphotochem.2007.08.00610.1016/j.jphotochem.2007.08.006Suche in Google Scholar
[20] Pola, J., Ouchi, A., Bakardjieva, S., Vorlíček, V., Maryško, M., Šubrt, J., & Bastl, Z. (2008b). Laser photochemical etching of silica: Nanodomains of crystalline chaoite and silica in amorphous C/Si/O/N phase. Journal of Physical Chemistry C, 112, 13281–13286. DOI: 10.1021/jp803738k. http://dx.doi.org/10.1021/jp803738k10.1021/jp803738kSuche in Google Scholar
[21] Pola, J., Ouchi, A., Saito, K., Ishikawa, K., & Koga, Y. (1996). Efficient chemical vapour deposition of hydrocarbon polymeric films by UV laser induced photolysis of 3-butyn-2-one. Chemical Physics Letters, 262, 279–283. DOI: 10.1016/0009-2614(96)01076-7. http://dx.doi.org/10.1016/0009-2614(96)01076-710.1016/0009-2614(96)01076-7Suche in Google Scholar
[22] Schwan, J., Ulrich, S., Batori, V., Ehrhardt, H., & Silva, S. R. P. (1996). Raman spectroscopy of amorphous carbon films. Journal of Applied Physics, 80, 440–447. DOI: 10.1063/1.362745. http://dx.doi.org/10.1063/1.36274510.1063/1.362745Suche in Google Scholar
[23] Stenberg, G., Piglmayer, K., Boman, M., & Carlsson, J.-O. (1997). Laser assisted chemical vapour deposition of hydrogen containing amorphous carbon at room temperature. Applied Surface Science, 109–110, 549–553. DOI: 10.1016/S0169-4332(96)00911-7. http://dx.doi.org/10.1016/S0169-4332(96)00911-710.1016/S0169-4332(96)00911-7Suche in Google Scholar
[24] Umemoto, M., Seki, K., Shinohara, H., Nagashima, U., Nishi, N., Kinoshita, M., & Shimada, R. (1985). Photofragmentation of mono- and dichloroethylenes: Translational energy measurements of recoiling Cl and HCl fragments. The Journal of Chemical Physics, 83, 1657–1666. DOI: 10.1063/1.449403. http://dx.doi.org/10.1063/1.44940310.1063/1.449403Suche in Google Scholar
[25] Wu, Y.-P. G., & Won, Y.-S. (2003). Thermal decomposition of 1,1-dichloroethene diluted in hydrogen. Journal of Hazardous Materials, 105, 63–81. DOI: 10.1016/j.jhazmat.2003.06.001. http://dx.doi.org/10.1016/j.jhazmat.2003.06.00110.1016/j.jhazmat.2003.06.001Suche in Google Scholar PubMed
© 2010 Institute of Chemistry, Slovak Academy of Sciences
Artikel in diesem Heft
- A deuterium-palladium electrode as a new sensor in non-aqueous solutions: potentiometric titration of weak acids in acetonitrile and benzonitrile
- Chemical variability of Artemisia herba-alba Asso essential oils from East Morocco
- Ag and Cu loaded on TiO2/graphite as a catalyst for Escherichia coli-contaminated water disinfection
- Direct electrochemistry and electrocatalysis of horseradish peroxidase immobilized in hyaluronic acid and single walled carbon nanotubes composite film
- Biological buffered saline solution as solvent in agar-carbomer hydrogel synthesis
- GC/MS analysis of gaseous degradation products formed during extrusion blow molding process of PE films
- Preparation, spectral, thermal, and biological properties of zinc(II) 4-chloro- and 5-chlorosalicylate complexes with methyl 3-pyridylcarbamate and phenazone
- Polyamidoamine dendrimer and dextran conjugates: preparation, characterization, and in vitro and in vivo evaluation
- Morphological characteristics of modified freeze-dried poly(N-isopropylacrylamide) microspheres studied by optical microscopy, SEM, and DLS
- Photophysical properties of novel ferrocenyl quinoline derivatives with red emission in solutions and polymeric matrices
- Preparation and characterization of hydrogels based on acryloyl end-capped four-arm star-shaped poly(ethylene glycol)-branched-oligo(l-lactide) via Michael-type addition reaction
- ArF laser photolytic deposition and thermal modification of an ultrafine chlorohydrocarbon
- Asymmetric synthesis of machilin C and its analogue
- Synthesis and study of some new N-substituted imide derivatives as potential antibacterial agents
- Single crystal X-ray structure and optical properties of anthraquinone-based dyes
- Low-density polyethylene in mixtures of hexane and benzene derivates
- Factors influencing aggregation behavior of poly(γ-benzyl l-glutamate)-graft-poly(ethylene glycol) copolymer in mixed solvents
- Chemical evaluation of Fallopia species leaves and antioxidant properties of their non-cellulosic polysaccharides
- Rapid synthesis and bioactivities of 3-(nitromethylene)indolin-2-one analogues
- ZnO nanorods catalyzed N-alkylation of piperidin-4-one, 4(3H)-pyrimidone, and ethyl 6-chloro-1,2-dihydro-2-oxo-4-phenylquinoline-3-carboxylate
Artikel in diesem Heft
- A deuterium-palladium electrode as a new sensor in non-aqueous solutions: potentiometric titration of weak acids in acetonitrile and benzonitrile
- Chemical variability of Artemisia herba-alba Asso essential oils from East Morocco
- Ag and Cu loaded on TiO2/graphite as a catalyst for Escherichia coli-contaminated water disinfection
- Direct electrochemistry and electrocatalysis of horseradish peroxidase immobilized in hyaluronic acid and single walled carbon nanotubes composite film
- Biological buffered saline solution as solvent in agar-carbomer hydrogel synthesis
- GC/MS analysis of gaseous degradation products formed during extrusion blow molding process of PE films
- Preparation, spectral, thermal, and biological properties of zinc(II) 4-chloro- and 5-chlorosalicylate complexes with methyl 3-pyridylcarbamate and phenazone
- Polyamidoamine dendrimer and dextran conjugates: preparation, characterization, and in vitro and in vivo evaluation
- Morphological characteristics of modified freeze-dried poly(N-isopropylacrylamide) microspheres studied by optical microscopy, SEM, and DLS
- Photophysical properties of novel ferrocenyl quinoline derivatives with red emission in solutions and polymeric matrices
- Preparation and characterization of hydrogels based on acryloyl end-capped four-arm star-shaped poly(ethylene glycol)-branched-oligo(l-lactide) via Michael-type addition reaction
- ArF laser photolytic deposition and thermal modification of an ultrafine chlorohydrocarbon
- Asymmetric synthesis of machilin C and its analogue
- Synthesis and study of some new N-substituted imide derivatives as potential antibacterial agents
- Single crystal X-ray structure and optical properties of anthraquinone-based dyes
- Low-density polyethylene in mixtures of hexane and benzene derivates
- Factors influencing aggregation behavior of poly(γ-benzyl l-glutamate)-graft-poly(ethylene glycol) copolymer in mixed solvents
- Chemical evaluation of Fallopia species leaves and antioxidant properties of their non-cellulosic polysaccharides
- Rapid synthesis and bioactivities of 3-(nitromethylene)indolin-2-one analogues
- ZnO nanorods catalyzed N-alkylation of piperidin-4-one, 4(3H)-pyrimidone, and ethyl 6-chloro-1,2-dihydro-2-oxo-4-phenylquinoline-3-carboxylate
