Potential of binary mixtures of sodium lauryl sulfoacetate (SLSA) and alkyl polyglucoside (APG10) as oil degreaser
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Sakaria N. Dina
Sakaria N. Dina is a lecturer at Chemical and Food Technology Department at Polytechnic Tun Syed Nasir Syed Ismail, Malaysia. She is graduated from Universiti Teknologi Mara (UiTM) and currently a postgraduate student for a Master degree in Chemical Engineering at Universiti Teknologi Malaysia (UTM). Current research interests are the environmentally friendly biodegreaser which is also the research project of the master study.
Zainal Abidin M. H. Shah is a lecturer at the Chemical and Food Technology Department at Polytechnic Tun Syed Nasir Syed Ismail, Malaysia. He is currently pursuing a master degree in Chemical Engineering at Universiti Teknologi Malaysia (UTM). He is graduated from Universiti Putra Malaysia (UPM). Cuurent reseach project is the application of biosurfactant in bioremediation.
Azman N. Raudhah is a research assistant at the University Teknologi Malaysia (UTM) Malaysia and currently pursuing her studies for a Ph.D programme in Bioprocess Engineering at University Teknologi Malaysia. She is graduated from Management and Science University (MSU). Her current PhD project is dealing with the production of the bio-degreaser by using agricultural waste as a substrate medium for bioremediation application.
Dr Asli U. Aisah is a senior lecturer at School of Chemical & Energy Engineering, Universiti Teknologi Malaysia, Johor Bahru Johor. She is currently a research fellow of the Innovation Centre of Agritechnology for Advanced Bioprocessing (ICA) in UTM Pagoh Campus. She is holding her Ph.D. in Chemical Engineering from the University of Bath, UK. Her research intersts is situated in the field of chemical reaction engineering as well as biochemical processing, with special interest on kinetics study and reaction mechanisms. Current research is focusing on production of biosurfactant and biodegreaser from agriculture waste for oil remediation application.
Abstract
The industry is challenged to replace toxic chemical-based surfactants with environmentally friendly and biodegradable surfactants. In this study, binary mixtures of sodium lauryl sulfoacetate (SLSA) and an alkyl polyglucoside (APG10) in various proportions were investigated for their effectiveness as degreasing agents. Efficacy was characterised using surface tension measurements, oil dispersion tests, emulsification, pH and cleaning efficacy in removing engine oil from a metal plate. The surface tension results for all solutions showed a critical micelle concentration of 1500 ppm. The dispersion tests (with oil:surfactant ratios of 1:2 and 1:3) showed that the oil was fully dispersed at an oil:surfactant ratio of 1:2 i.e., at a concentration of 2500 ppm SLSA and 2000 ppm of a binary solution with a volume ratio of SLSA:APG10 of 75:25. At a ratio of 1:3, the oil was fully dispersed with 2500 ppm of a binary solution with a ratio of SLSA:APG10 of 75:25. Overall, the solution with a volume ratio of SLSA:APG10 of 75:25 was the most favourable. The results also showed that a solution containing only SLSA had good potential as a degreaser, as it achieved a cleaning performance of 90% in removing oil from the metal plate despite low emulsification levels (E24) for both surfactants. In summary, a combination of these two green surfactants can be used effectively as a degreasing agent.
About the authors
Sakaria N. Dina is a lecturer at Chemical and Food Technology Department at Polytechnic Tun Syed Nasir Syed Ismail, Malaysia. She is graduated from Universiti Teknologi Mara (UiTM) and currently a postgraduate student for a Master degree in Chemical Engineering at Universiti Teknologi Malaysia (UTM). Current research interests are the environmentally friendly biodegreaser which is also the research project of the master study.
Zainal Abidin M. H. Shah is a lecturer at the Chemical and Food Technology Department at Polytechnic Tun Syed Nasir Syed Ismail, Malaysia. He is currently pursuing a master degree in Chemical Engineering at Universiti Teknologi Malaysia (UTM). He is graduated from Universiti Putra Malaysia (UPM). Cuurent reseach project is the application of biosurfactant in bioremediation.
Azman N. Raudhah is a research assistant at the University Teknologi Malaysia (UTM) Malaysia and currently pursuing her studies for a Ph.D programme in Bioprocess Engineering at University Teknologi Malaysia. She is graduated from Management and Science University (MSU). Her current PhD project is dealing with the production of the bio-degreaser by using agricultural waste as a substrate medium for bioremediation application.
Dr Asli U. Aisah is a senior lecturer at School of Chemical & Energy Engineering, Universiti Teknologi Malaysia, Johor Bahru Johor. She is currently a research fellow of the Innovation Centre of Agritechnology for Advanced Bioprocessing (ICA) in UTM Pagoh Campus. She is holding her Ph.D. in Chemical Engineering from the University of Bath, UK. Her research intersts is situated in the field of chemical reaction engineering as well as biochemical processing, with special interest on kinetics study and reaction mechanisms. Current research is focusing on production of biosurfactant and biodegreaser from agriculture waste for oil remediation application.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: The authors acknowledge that this work was sponsored by a Universiti Teknologi Malaysia Fundamental Research (UTMFR) grant (Q.J130000.2509.21H54).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Odokuma, L. Ultimate biodegradability potential of trichloroethylene (TCE) used as degreaser in marine, brackish and fresh water. IOSR J. Environ. Sci. Toxicol. Food Technol. 2015, 9, 2319–2399; https://doi.org/10.9790/2402-09728089.Suche in Google Scholar
2. MicroCare Europe, B. V. B. A. Eco-friendly cleaning of metal parts. IST International Surf. Technol. 2020, 13, 32–33; https://doi.org/10.1007/s35724-020-0121-3.Suche in Google Scholar
3. Rocha e Silva, N. M. P., Almeida, F. C. G., Rocha e Silva, F. C. P., Luna, J. M., Sarubbo, L. A. Formulation of a biodegradable detergent for cleaning oily residues generated during industrial processes. J. Surfactants Deterg. 2020, 23, 1111–1123; https://doi.org/10.1002/jsde.12440.Suche in Google Scholar
4. A. Bhadani, Kafle, A., Ogura, T., Akamatsu, M., Sakai, K., Sakai, H., Abe, M. Phase behavior of ester based anionic surfactants: sodium alkyl sulfoacetates. Ind. Eng. Chem. Res. 2019, 58, 6235–6242; https://doi.org/10.1021/acs.iecr.9b00286.Suche in Google Scholar
5. Pal, N., Saxena, N., Laxmi, K. V. D., Mandal, A. Interfacial behaviour, wettability alteration and emulsification characteristics of a novel surfactant: implications for enhanced oil recovery. Chem. Eng. Sci. 2018, 187, 200–212; https://doi.org/10.1016/j.ces.2018.04.062.Suche in Google Scholar
6. Rakowska, J., Radwan, K., Porycka, B., Prochaska, K. Experimental study on surface activity of surfactants on their ability to cleaning oil contaminations. J. Clean. Prod. 2017, 144, 437–447; https://doi.org/10.1016/j.jclepro.2016.12.158.Suche in Google Scholar
7. Cheng, K. C., Khoo, Z. S., Lo, N. W., Tan, W. J., Chemmangattuvalappil, N. G. Design and performance optimisation of detergent product containing binary mixture of anionic-nonionic surfactants. Heliyon 2020, 6, e03861; https://doi.org/10.1016/j.heliyon.2020.e03861.Suche in Google Scholar PubMed PubMed Central
8. Monroe, K. R., Hill, E. A., Carter, K. D.Jr. Surfactant parameter effects on cleaning efficiency. In The Alliance for Responsible CFC Policy, Washington DC, 1993; pp. 405–414.Suche in Google Scholar
9. Geetha, D., Tyagi, R. Alkyl poly glucosides (APGs) surfactants and their properties: a review. Tenside, Surfactants, Deterg. 2012, 49, 417–427; https://doi.org/10.3139/113.110212.Suche in Google Scholar
10. Li, G., Chen, L., Ruan, Y., Guo, Q., Liao, X., Zhang, B. Alkyl polyglycoside: a green and efficient surfactant for enhancing heavy oil recovery at high-temperature and high-salinity condition. J. Pet. Explor. Prod. Technol. 2019, 9, 2671–2680; https://doi.org/10.1007/s13202-019-0658-1.Suche in Google Scholar
11. Lee, S. M., Lee, J. Y., Yu, H. P., Lim, J. C. Synthesis of environment friendly nonionic surfactants from sugar base and characterization of interfacial properties for detergent application. J. Ind. Eng. Chem. 2016, 38, 157–166; https://doi.org/10.1016/j.jiec.2016.04.019.Suche in Google Scholar
12. Tmáková, L., Sekretár, S., Schmidt, Š. Plant-derived surfactants as an alternative to synthetic surfactants: surface and antioxidant activities. Chem. Pap. 2015, 70, 188–196; https://doi.org/10.1515/chempap-2015-0200.Suche in Google Scholar
13. Darne, G. A., Rita de, C. F, Soares da, S., Pedro, P. F., B., Juliana, M. de L., Maria da, G. C. da S., Raquel, D. R., Andrea, F. S. C., Valdemir, A. S., Leonie, A. S. Application of a biosurfactant from candida tropicalis UCP 0996 produced in low-cost substrates for hydrophobic contaminants removal. Chem Eng Trans. 2018, 64, 541–546; https://doi.org/10.3303/CET1864091.Suche in Google Scholar
14. Donald, N. VanEenam. Buckeye International, assignee. Aqueous degreaser emulsion compositions. U.S. Patent 5,419,848, May 30, 1995.Suche in Google Scholar
15. Sathya, P., Lejaniya, A. S., Sathian, C. T., Radha, K. Cleaning and sanitization efficiency of some cleansing agents of natural origin. Pharma Innov. J. 2017, 6, 105–107.10.20546/ijcmas.2017.612.188Suche in Google Scholar
16. Pradhan, A., Bhattacharyya, A. Quest for an eco-friendly alternative surfactant: surface and foam characteristics of natural surfactants. J. Clean. Prod. 2017, 150, 127–134; https://doi.org/10.1016/j.jclepro.2017.03.013.Suche in Google Scholar
17. Sansanwal, P. K. Effect of co-solutes on the physico-chemical properties of surfactant solutions. J. Sci. Ind. Res. 2006, 65, 57–64.Suche in Google Scholar
18. Rudawska, A. Degreasing. In Surface Treatment in Bonding Technology, Academic Press: London, 2019; pp. 63–86.10.1016/B978-0-12-817010-6.00004-7Suche in Google Scholar
© 2023 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Automatic Dishwashing
- How many resources can be saved by changing consumers’ automatic dishwashing behaviour?
- Textile Treatment
- Stain removal performance of moisture-wicking fabric during home laundry
- Physical Chemistry
- Tensiometric and rheological investigations of single and mixed systems consisting of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) in aqueous solutions
- Dilute hydrochloric acid induced switching from antagonism to synergism in the binary mixed systems of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS)
- Study on the properties of amide Gemini surfactants
- Application
- Potential of binary mixtures of sodium lauryl sulfoacetate (SLSA) and alkyl polyglucoside (APG10) as oil degreaser
- The effects of SDS, APG, and DTAB surfactants on the morphology of micro-nano RDX particles prepared in a microfluidic reactor
- Synthesis
- Synthesis and properties of alkyl glyceryl ether sulfonate
- Study on the synthesis and properties of cardanol sulfonate
Artikel in diesem Heft
- Frontmatter
- Automatic Dishwashing
- How many resources can be saved by changing consumers’ automatic dishwashing behaviour?
- Textile Treatment
- Stain removal performance of moisture-wicking fabric during home laundry
- Physical Chemistry
- Tensiometric and rheological investigations of single and mixed systems consisting of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS) in aqueous solutions
- Dilute hydrochloric acid induced switching from antagonism to synergism in the binary mixed systems of cocamidopropyl betaine (CAPB) and sodium dodecyl benzene sulfonate (SDBS)
- Study on the properties of amide Gemini surfactants
- Application
- Potential of binary mixtures of sodium lauryl sulfoacetate (SLSA) and alkyl polyglucoside (APG10) as oil degreaser
- The effects of SDS, APG, and DTAB surfactants on the morphology of micro-nano RDX particles prepared in a microfluidic reactor
- Synthesis
- Synthesis and properties of alkyl glyceryl ether sulfonate
- Study on the synthesis and properties of cardanol sulfonate
