Response surface methodology optimization and anti-age properties in paper protection of carboxymethyl cellulose grafted with β –cyclodextrin
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Linquan Fang
und
Jun Gao
Abstract
In order to protect the paper, increase the mechanic performance and delay the aging of paper, CMC-β-CD was synthesized by carboxymethyl cellulose as substrate, epichlorohydrin (ECH) as crosslinking agent, sodium hydroxide (NaOH) as catalyst and solvent, and water as medium, β-Cyclodextrin as grafter, through single factor experiment and response surface method, suitable conditions for the synthesis of CMC-β-CD was obtained; The structure of the synthesized CMC-β-CD was characterized by infrared spectroscopy and SEM and the mechanic properties were evaluated. The results showed that when the mass ratio of CMC-β-CD was 7:15, reaction temperature was 40 °C, and pH was 6.0, the optimum synthetic conditions was obtained. And good anti-age properties was also obtained by thermal aging tests. This paper provides some theoretical guidance for the protection of paper cultural relics.
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Research ethics: Not applicable.
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Informed consent: Not applicable.
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Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Use of Large Language Models, AI and Machine Learning Tools: None declared.
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Conflict of interest: All other authors state no conflict of interest.
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Research funding: This work was supported by Undergraduate Training Program for Innovation and Entrepreneurship in 2024, No.2024CXCY327.
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Data availability: The raw data can be obtained on request from the corresponding author.
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