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Applications of cationic bamboo fibers for the effective reinforcements of secondary fibers

  • Tianhao Huang , Yunxia Wang , Yi Hou EMAIL logo and Xiangxing Liu
Published/Copyright: August 14, 2025
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Abstract

Bamboo, with its long fibers, fast growth, high abundance, and short harvesting cycle, is a promising alternative to traditional wood pulp, particularly in reinforcing secondary fibers during paper recycling. In this study, different from direct addition with poor combination concerning the negative charge in recycled pulp fibers, bamboo fibers were firstly modified with 3-chloro-2-hydroxypropyltrimethylammonium chloride (CHPTAC) to get cationic bamboo fibers, the characterizations by FTIR and N contents (maximum 1.05 %) classified that the hydroxyl groups in bamboo fibers were etherified effectively with greater zeta potentials (maximum −13.2 mV) in mixed pulps. The cationic modification of bamboo fibers resulted in a significant increase in the tensile and burst index of the secondary pulp, by 49.75 % and 61.54 % with only 10 %addition, respectively, as compared to the unmodified bamboo fibers, which was contributed to the mutual attraction between positively charged modified bamboo fibers and negatively charged secondary fibers, besides the original hydrogen bonding inside fibers, which leads to the enhancements for secondary fibers strength. These findings provide valuable insights into the effective applications of bamboo fibers for reinforcing recycled paper and offer promising solutions for the sustainable development of the paper industry.


Corresponding author: Yi Hou, State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, China, E-mail:

Funding source: State Key Project of Research and Development Plan of Guangdong Province

Award Identifier / Grant number: 2022B0202020002

Funding source: Nine Dragons Paper

Award Identifier / Grant number: 2106030200502

Acknowledgments

This work is partially supported by High Performance Computing Platform of South China University of Technology.

  1. Research ethics: Not applicable.

  2. Informed consent: Informed consent was obtained from all individuals included in this study, or their legal guardians or wards.

  3. Author contributions: The author has accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: To improve language.

  5. Conflict of interest: All other authors state no conflict of interest.

  6. Research funding: The authors are appreciative of the support of the Key Project of Research and Development Plan of Guangdong Province (2022B0202020002) and Nine Dragons Paper (based on the contract of 2106030200502).

  7. Data availability: The raw data can be obtained on request from the corresponding author.

References

Abubakr, S., Scott, G.M., and Klungness, J.H. (1995). Fiber fractionation as a method of improving handsheet properties after repeated recycling. Tappi J. 78: 123–126.Search in Google Scholar

Etale, A., Nhlane, D.S., Mosai, A.K., Mhlongo, J., Khan, A., Rumbold, K., and Nuapia, Y.B. (2021). Synthesis and application of cationised cellulose for removal of Cr(VI) from acid mine-drainage contaminated water. AAS Open Res. 4: 4, https://doi.org/10.12688/aasopenres.13182.1.Search in Google Scholar PubMed PubMed Central

Ghasemian, A., Ghaffari, M., and Ashori, A. (2012). Strength-enhancing effect of cationic starch on mixed recycled and virgin pulps. Carbohydr. Polym. 87: 1269–1274, https://doi.org/10.1016/j.carbpol.2011.09.010.Search in Google Scholar

Granja, P.L., Barbosa, M.A., Pouységu, L., de Jeso, B., Rouais, F., and Baquey, C. (2001). Cellulose phosphates as biomaterials. Mineralization of chemically modified regenerated cellulose hydrogels. J. Mater. Sci. 36: 2163–2172.10.1023/A:1017587815583Search in Google Scholar

Hemmati, F., Jafari, S.M., Kashaninejad, M., and Barani Motlagh, M. (2018). Synthesis and characterization of cellulose nanocrystals derived from walnut shell agricultural residues. Int. J. Biol. Macromol. 120: 1216–1224, https://doi.org/10.1016/j.ijbiomac.2018.09.012.Search in Google Scholar PubMed

Huang, J., Zhang, L., Zhou, Y., Huang, M., and Sha, Y. (2016). Study on the suitability of bamboo fiber for manufacturing insulating presspaper. IEEE Trans. Dielectr. Electr. Insul. 23: 3641–3651, https://doi.org/10.1109/tdei.2016.005679.Search in Google Scholar

Sheikhi, P., Asadpour, G., Zabihzadeh, S.M., and Amoee, N. (2013). An optimum mixture of virgin bagasse pulp and recycled pulp (OCC) for manufacturing fluting paper. BioResources 8: 5871–5883, https://doi.org/10.15376/biores.8.4.5871-5883.Search in Google Scholar

Villar, J.C., Revilla, E., Gómez, N., Carbajo, J.M., and Simón, J.L. (2009). Improving the use of kenaf for kraft pulping by using mixtures of bast and core fibers. Ind. Crops Prod. 29: 301–307, https://doi.org/10.1016/j.indcrop.2008.06.002.Search in Google Scholar

Wang, Y., Hou, Y., Lei, L., Zhang, Y., and Hu, S. (2024). Reinforcements of cationic polyvinyl alcohol with low dosage for secondary fibre. Polym-Plast. Tech. Mat. 63: 2171–2180, https://doi.org/10.1080/25740881.2024.2368868.Search in Google Scholar

Wang, Y. (2024). Development of enzyme-based biotechnology for removing stickies and regaining fibers quality in paper recycling. Dissertations 4073.10.1002/9781394214297.ch35Search in Google Scholar

Zhang, H., He, Z., and Ni, Y. (2011). Improvement of high-yield pulp properties by using a small amount of bleached wheat straw pulp. Bioresour. Technol. 102: 2829–2833, https://doi.org/10.1016/j.biortech.2010.10.053.Search in Google Scholar PubMed

Zulkefli, S., Abdulmalek, E., and Rahman, M.B. (2017). Pretreatment of oil palm trunk in deep eutectic solvent and optimization of enzymatic hydrolysis of pretreated oil palm trunk. Renewable Energy 107: 36–41.10.1016/j.renene.2017.01.037Search in Google Scholar

Received: 2024-12-12
Accepted: 2025-07-07
Published Online: 2025-08-14

© 2025 Walter de Gruyter GmbH, Berlin/Boston

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