Startseite Influence of surfactant concentration on structural properties and corrosion behaviour of electrodeposited Ni–SiO2 nanocomposite coatings
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Influence of surfactant concentration on structural properties and corrosion behaviour of electrodeposited Ni–SiO2 nanocomposite coatings

  • Louiza Guerguer ORCID logo EMAIL logo , Ahmed Hamdi , Aicha Ziouche , Djamel Benbertal , Mohammed Abdelkader Belalem und Abderrahim Benmoussat
Veröffentlicht/Copyright: 16. Februar 2023
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Abstract

In this study, Ni–SiO2 nanocomposite coatings were deposited on the surface of X70 steel by performing direct current electrodeposition. The effect of different concentrations of cetyltrimethylammonium bromide surfactant (0.3, 0.5, 1, and 2 g L−1) on particle distribution and corrosion behaviour of the coatings was analysed. The structural properties of the obtained coatings were evaluated by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy analysis, X-ray diffraction, and atomic force microscopy. The corrosion behaviour of the coatings was tested by potentiodynamic polarisation and electrochemical impedance spectroscopy. The results showed that the electrodeposited coatings obtained from the electroplating bath with 1 g L−1 of surfactant modified the surface morphology of the Ni–SiO2 nanocomposite coating and presented a finer and more uniform microstructure. The results of the phase structure analysis showed that the addition of the surfactant in the electrodeposition process changed the preferred orientations for the coatings from (111) to (220) and (200) planes. The anti-corrosion performance of the resulting coating produced in the presence of 1 g L−1 of surfactant was significantly higher than the anti-corrosion performance of the other coatings and showed a lower corrosion rate.


Corresponding author: Louiza Guerguer, Materials and Energies Research Laboratory, Sersouf, Department of Material Sciences, Institution of Sciences and Technology, University of Tamanrasset, BP 10034, Tamanrasset, Algeria, E-mail:

Acknowledgements

The authors would like to thank the ALFAPIPE Company of Ghardaia-Algeria for providing the steel samples and their chemical composition. We would also like to thank the Dr. Mohamed Cherif M’Ziane for his assistance in (SEM/EDS Mapping) measurements, where the microstructural analysis was accomplished in the Laboratory of Energy Processes and Nanotechnology (LEPN) at the University of Blida1-Algeria.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-06-21
Accepted: 2022-08-16
Published Online: 2023-02-16
Published in Print: 2023-03-28

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Heruntergeladen am 16.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijmr-2021-8429/pdf
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